Waste SCR Denitration Catalyst Recycles Tungsten Trioxide - Secondary Alkaline Leaching Method

thermal power plant denitration systemWith SCR denitration power being constantly put into the plant large-scale construction projects,  at the same time, the waste catalysts are increasing dramatically; on the other hand, the continuous development of science, high-tech demand for tungsten will be rising. Tungsten is a rare metal, the more we use, the less rest. For fully using the limited tungsten ore, recycling tungsten from waste SCR denitration catalyst has became urgent. There are many reachers both at home and abroad committed to study on this subject, and someone has proposed the secondary alkaline leaching method to recover tungsten trioxide, ammonium metavanadate, molybdenum and other precious metal oxides from waste SCR denitration catalysts. Steps are as following:
 
1. Crushing the waste catalyst into 80 mesh or more;
2. Removing impurities: soaking the powder with excessive water to make arsenic, Hg, alkali metal salts and organic matters dissolved in water, and then carrying out filtration, the wastewater can be recycle after removed impurities through activated carbon;
3. Leaching: adding excessive Na0H solution (concentration of 20~30%) into the powder,  and heating to 80 °C, soaking for 1~2 hours to leach out most tungsten, molybdenum, and vanadium;
4. Recovering vanadium: Adjusting pH value to 1.7-1.8 with NH4Cl, and boiling for 1~2 hours to make vanadium precipitated, thus to recycle pure ammonium metavanadate;
5. Recovering molybdenum and tungsten : Tungsten and molybdenum respectively exist in the form of ammonium tungstate, ammonium molybdate; before adding calcium chloride solution, we supposed to adjust pH value to 4.5~5.0 by hydrochloric acid, then get the calcium tungstate, calcium molybdate, then dissolved by hydrochloric acid to obtain tungstic and molybdic acid;
6. Generating ammonium paratungstate by traditional methods, then calcined to recover tungsten trioxide.

 

Tungsten Carbide Wear Plate — Wear Form(2/2)

Another failure form of tungsten carbide wear plate is solder peeling bore wear. Under the impact of concrete, the surface of the ring alloy plate glasses has cracks, which is due to poor wear resistance of its internal bore, can not fully resist the impact of concrete and wear. Flowing concrete will has relative movement with internal bore of tungsten carbide wear plate, which makes the solid surface and the material properties of the surrounding surface has changed, easily deformed due to uneven force. Therefore, enhanced tungsten carbide wear plate bore is critical and it has enhanced the protection of surface alloy ring and reduces the deformation effect. In order to improve the service life of tungsten carbide wear plate, we can improve the wear resistance of internal bore of wear plate from material and structure.

We have two choices from the material that welding electrode wear and use tungsten carbide directly. By experimental comparison can be drawn with the following electrode wear carbide abrasive wear table:

tungsten carbide wear plate


















From the graph above we can clearly see that the wear resistance of tungsten carbide is 5 times better than the welding electrode so that tungsten carbide as the material for the internal bore is a best choice. For the bore structure of wear plate, in order to avoid high temperatures generated inlaid alloy caused defects, the researchers used a related set of inlaid alloy structure, effectively extends the life of tungsten carbide wear plate.

Tungsten Carbide Wear Plate — Wear Form(1/2)

Generally, the medium of tungsten carbide wear plate is concrete, which is composed of cement, water, fine coarse aggregate and other additives and the hardness index converted to a Rockwell hardness of between about HRC40-50. In the process, the main wear forms can be divided into two types, one is in the process of cutting ring reversal, wear plate and floating cutting ring contacts and has grain wear and erosion; the other is in the process of inhaling or pumping, the internal hole of wear plate has low stress wear and erosion.

After concrete pump working for some time, there is a gap between tungsten carbide wear plate and cutting ring. Theoretically, grinding compounds friction and grinding compounds wear of the sliding contact surfaces are generally the form of typical wear. Both wear plate and cutting ring are tungsten carbide and form a pair of friction, the floating cutting ring swings back and forth on tungsten carbide wear plate quickly. Both of them form grain wear by surface contact constantly.

In addition, there are still ore, quartz sand and some other hard particles, and the concrete also belongs to corrosive medium, which will further exacerbate the grinding compounds wear of tungsten carbide wear plate. At present, with the increasing height of the building, pumping height and pressure is also rising, which for carbide glasses plate and cutting ring put forward higher requirements. As time goes by, it will gradually appear larger gaps or partial abrasion between the cutting ring and the wear plate, and leading to failure of the wear plate finally.

Tungsten Sailing Counterweight

Sailing originated in Holland, and was popular throughout Europe and the United States. Nowadays, with the continuous improvement of the level of social life in China, the people who love sailing are increasing continually. Sailing is not only one of the favorite recreational sports welcomed by people, but also one of the Olympic Games; and the International Sailing Federation (ISF) was founded in 1907 in Paris for maintaining the peace and stability of sailing all over the world. The popular of sailing also gave birth to a lot of sailing clubs, such as the Royal sailing club. The tungsten gold-plated badges for sailing clubs also were sought after by people. Sailing can make you feel exciting and physically and mentally flying, but its safety is the premise to ensure that you can get the best experience in the course of sailing.
 
Whether it is sailing, fishing vessels, cargo vessel or some other use or type of vessel, in order to ensure the stability of sailing on the sea, it usually needs to add counterweight to the hull. The early counterweight is mainly made of iron, lead and stone, sometimes even using seawater as ballast. With the exploitation of new kinds of excellent materials, tungsten alloy material has been recognized by people due to its good performances of high density, good tensile strength and non-toxic environmentally friendly, and has been widely used to make various products, such as counterweights, shielding, which can be well applied in various fields. Tungsten counterweight for sailing is specifically made based on the specifications of sailing. The high density of tungsten alloy makes tungsten sailing counterweight have the excellent counterweight efficiency in a smaller volume; its characteristics of non-toxic and environmental friendly also welcomed by people. Tungsten alloy is the best and ideal material for making sailing counterweight, because it does no pollution to the ocean. Nowadays, most of sailing counterweights are manufactured of tungsten alloy, and along with the development of science and technology, the application of tungsten alloy will also be more and more widely.
tungsten sailing counterweights

 

Rare Earth Doped Tungsten Electrode History

rare earth doped tungsten electrodes

Pure tungsten electrode is the earliest used electrode material. Mainly because tungsten has high melting point, low vapor pressure and other properties. However, pure tungsten work function is too high and at high temperature recrystallization will occur to form equiaxed crystal structure, so that the material becomes brittle and fracture. In order to improving the recrystallization and reducing the work function temperature of the tungsten electrode, after research people developed a series of rare earth doped tungsten electrodes.

Rare earth doped tungsten electrode is based on tungsten doped with some refractory oxide as the active material, lowering the work function of tungsten. Common rare earth doped tungsten electrodes are thorium tungsten electrode, cerium tungsten electrode, lanthanum tungsten electrode and zirconium tungsten electrode. Thorium tungsten electrode was invented in 1913. It has good performance, but radioactive, so long-term use would endanger human health and cause environmental pollution. Comparing with thorium tungsten electrode, cerium tungsten electrode and lanthanum tungsten electrode has a relatively better performance, and no radioactive, having broad application prospects.

Rare earth doped tungsten electrode began at former Soviet Union. The Soviet Union had reports of rare earth doped tungsten electrode before the 1960s. China, in 1973, had successful developed and used cerium tungsten electrode.

The late 1980s, Japanese researchers achieved some progress in new electrode material, developed a series of rare earth tungsten electrodes, including tungsten electrodes doped with single oxide, tungsten electrodes doped with two oxide and tungsten electrodes doped with three oxide. In tungsten electrodes doped with single oxide, lanthanum tungsten electrode overall performance is better, followed by yttrium tungsten electrode and cerium tungsten electrode. In tungsten electrodes doped with two oxides, producing it with following proportioning will have better property, La2O3: CeO2 = 1: 1, La2O3: Y2O3 = 1: 3, CeO2: Y2O3 = 1: 3. Tungsten electrodes doped with there oxides (La2O3: CeO2: Y2O3 = 1: 1: 3) have low work function, and low operating temperatures.

 

Tungsten Electrode and Shielding Gas in TIG Welding

Tungsten electrode has high melting point, high boiling point, high strength, low thermal conductivity and low high temperature volatile and other good property, so it is often as a non-consumable electrode applied in welding field. Pure tungsten electrode has poor electron emission performance doped with rare earth rare earth to improve electrode property. Rare earth doped tungsten electrode has good electron emission performance and long service life. Besides, it is easy to arcing.

During welding, shielding gas is a protective medium of weld region but it is a gaseous medium of arcing. Therefore, physical and chemical property of protection gas will not only affect the protective effect, will also have some impact on the arcing ignition, welding process stability and quality of arcing.

For TIG welding (tungsten inert gas welding), there are three kind of shielding gas, including argon, helium and mixture gas. Among these shielding gas, the most widely used is argon. Argon is an inert gas. It does not react with welding metal and not soluble in the metal as well. Besides, the density of argon is heavier than air, and specific heat capacity and thermal conductivity smaller than air, so it can effective protect the molten metal from air, oxygen, nitrogen, hydrogen and other harmful elements effect. These features make argon showed good performance in welding process. It not only can play a good protective effect, but it can to stabilize the arc.

tungsten electrodes in TIG welding

Helium is also an inert gas. It has good cooling effect, so the arc energy density is large and arc column is small and focused, while the weld joint has good penetration rate. But helium has high ionization potential, big thermal conductivity, so during the welding arc is more difficult and the energy loss is large. In generally, it is used for nuclear reactor cooling rods and large thickness aluminum alloy welding.

Mixture gas includes a certain proportion of two kind of inert gas, including argon-hydrogen mixed gas and argon-helium mixed gas. During the welding process, mixture gas in favor of increasing thermal power of arc, increasing the weld joint penetration rate, improving production efficiency.

 

Tungsten Gold-Plated Coin for Labor Day

May 1st is the national celebrating day for working people every year all over the world; many countries will hold some celebrations. There is a famous saying in China: “Labor glorious!” Yep, since the ancient times, a person usually obtains what he needs by working. They worked through the dynasty one after another, and built one country after another. The magnificent buildings, the modern cities, the funny leisure and entertainments…those are all built by the labors. Commemorating the Labor Day is also to commemorate labors, thank them for their uncomplaining pays and commemorate the extraordinary things created by them.  
 
The meanings of using tungsten gold-plated coin as the commemorative coin of Labor Day is that the tungsten gold-plated coin has high density and component which can imply that the majority of workers occupy great important position on the construction of the motherland. Besides, its good wear resistance and corrosion resistance makes it can be well preserved. Tungsten gold-plated coin for Labor Day is non-toxic and immortal; it is exquisite as gold, but it has high cost-performance than gold. Therefore the tungsten gold-plated coin can be customized different styles, different plating solutions, different patterns as gifts to commend the labors those who pay the hard work year by year in the Labor Day. Tungsten gold-plated coin for Labor Day can also plated with nothing for keeping the original color of clear and texture metal sense of tungsten alloy, which has another beauty. The weight of tungsten gold-plated coin can be customized from 1g to 50g.
tungsten gold-plated coin for Labor Day

 

Tungsten Gold-Plated Coin for Moon Festival

Moon Festival is one of the most important Chinese traditional festivals. Moon Festival means miss, happiness as well as the togetherness. People will have a joyous gathering in this festival, drink wines and watch the moon, feel the cool wind of fall and talk about the trivia happened in hometown in order to transmit the homesickness. But it does not mean that everyone could come together with their family, especially for the redsky; Moon Festival will easily raise their deep homesickness, but they couldn’t go home. How to bear your deep and fine miss? How can transmit your deepest love and emotion to your relatives in the distance? Tungsten gold-plated coin would be the best carrier of your emotion, which can be engraved with your blessing words or meaningful patterns. 
 
Due to the characteristics of good abrasion resistance, corrosion resistance, high cost-performance and high ornamental of tungsten gold-plated coin for Moon Festival, so it can be used as gifts to relatives or friend to show the deep thoughts and wishes. In addition, it can also be kept as a collection. Although the value of tungsten gold-plated coin is lower than gold coin, but it is so that tungsten gold-plated coin can greatly avoid the huge economic loss caused by theft or damage of gold coin. Tungsten gold-plated coin has long lasting preserve time and exquisite appearance as gold, so it can be well used for transmitting your miss and blessing. The shapes, size, patterns of tungsten gold-plated coins can be customized in accordance with the requirements of customs, and its weight can be from 1 g to 50g.
tungsten gold-plated coin for Moon Festival

 

WO3 Enhances SCR Denitration Catalyst Activity and Thermal Stability

Tungsten trioxide can be used in lots of fields, the mainly use is calcined to produce tungsten and tungsten carbide powder, then to produce carbide products, such as cemented carbide cutting tools; at the same time, the tungsten trioxide is also very good shielding material, and using in X-ray shielding and fireproof fabric frequently; in addition, another important use of tungsten trioxide is used as raw material for producing SCR denitration catalyst.

denitration catalyst
 
Catalyst is the core part of the SCR technology; its effective operation determines SCR denitration system efficiency and economy. The mainly active substances of SCR method denitration catalyst are titanium dioxide, vanadium pentoxide, tungsten trioxide, molybdenum trioxide, etc., among them titanium dioxide is the effective carrier. Vanadium oxide can disperse uniformly on the titanium dioxide surface, and anatase titanium dioxide is the highest activity in industry. Vanadium pentoxide being the most important active ingredient in SCR denitration catalyst, the amount of it is different in different catalysts, but the higher vanadium pentoxide content leads to a higher activity of the catalyst.
 
However, due to the extremely high activity of vanadium pentoxide, it will oxidize sulfur dioxide into sulfur trioxide, which will affect SCR denitration catalyst efficiency. Therefore, a high level of vanadium pentoxide is generally not recommended, the many using of denitration catalyst contents 2%~5% of vanadium pentoxide. The introduction of tungsten trioxide plays a major role in enhancing the activity and increasing the thermal stability of the denitration catalyst. That is because tungsten trioxide can limit catalyst being sulfated, the SCR denitration catalyst commonly used containing 5%~10% of tungsten oxide. Molybdenum trioxide takes the main role of improving catalyst activity and preventing catalyst being poisoned by As in the flue gas. But because molybdenum trioxide disadvantages to catalyst forming, and reducing the ratio of honeycomb catalyst end product, so molybdenum trioxide is mainly used in producing flat-catalyst.

 

Waste Cellular SCR Denitration Catalyst Recovers WO3

Cellular SCR denitration catalyst will partly or entirely loss activity after being used for some time, thus cannot to be effective and bring out a lot of waste catalysts. If we don’t recover the noble metals such as titanium, tungsten, and vanadium in the catalysts, it will inevitably result in resources wasted, environmental pollution and costs increased.
 
If we can change waste into treasure, which means recovering the waste catalysts as raw materials for producing catalyst, making these materials circulating, we guess it would be a very good approach. A method that recovering powder containing tungsten trioxide from waste cellular SCR denitration catalyst have been pointed out. The steps are as follows:
 
1. Crushing: Crushing the waste SCR denitration catalyst into 30~50mm pieces by a crusher, and also clearing away the ash by a shaker;
2. Cleaning: Cleaning the catalysts after crushing by an ultrasonic for 1 hour, and then washing by water; 
3. Drying: Drying the catalyst after cleaning in an oven at 100-150°C for 10~15 hours;
4. Grinding: Grinding the dried catalyst into powder with particle size of 5-50um, then the waste SCR denitration catalyst containing tungsten trioxide obtained.
 
The recovered waste SCR denitration catalyst containing tungsten trioxide can be reused as the material for producing fresh catalyst, thus to achieve the goal of recycling. The implementation is: mixing the raw materials titanium dioxide, glass fibers, waste SCR denitration catalyst recycled material, tungsten trioxide, vanadium pentoxide and deionized water, after kneading, extruding, drying and calcining to prepare SCR denitration catalyst.

 

 

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