Cerium-Tungsten Trioxide SCR Denitration Catalyst 2/2

Rare earth element - tungsten trioxide SCR denitration catalyst can be applied to coal-fired power, glass, cement, steel mills plants, heating boiler room and other coal, oil, SCR flue gas denitration process. At the same time, because of this tungsten trioxide SCR catalyst belongs to rare earth system, which has many excellent properties, such as non-toxic, no need to recover, no fear for water, can be regenerated for several times, also it can be made into honeycomb, plate and corrugated and other types. This type of SCR denitration catalyst maybe possible fully replaces the imported VW-Ti system SCR catalyst technology in the near future.

tungsten vanadium rare earth based powder
 
Compares to ordinary V-W-Ti system catalyst, this cerium rare earth element tungsten trioxide denitration catalyst has many advantages:
1. None toxic effects, do not cause harm to humans and the environment;
2. Efficiency with long life
Experiments show that the catalytic ability of rare earth elements is higher than vanadium (V) element, thus brings the titanium dioxide, tungsten trioxide and other components reduced, so that the production costs reduced at the same time. Meanwhile, the increasing content of alumina also bring catalyst stiffness and hardness markedly improved, thus make the catalyst has longer life and better suit for glass furnace, cement, coal boiler other severer operating conditions with high ash content in flue gas;
3.Temperature window broaden, the minimum working temperature of this rare earth cerium-tungsten trioxide SCR denitration catalyst is as low as 260℃, which is 50℃ lower than the average 310℃, making the use scope expanded;
4. Can be regeneration more times, this kind of rare earth element catalyst is able to withstand repeated washing without damaged which means higher regeneration ability, it also greatly reducing the cost and realizing the goal of economic interests.

 

Cerium-Tungsten Trioxide SCR Denitration Catalyst 1/2

CeFrom the precious metal catalyst to today widely used SCR denitration catalyst which is using titanium dioxide as the main catalyst carrier, vanadium pentoxide, tungsten trioxide as main active ingredient, the SCR denitration catalyst has experienced a variety of important technological changes and condensed years of hard work from academics and numbers of plant personnel.
 
However, since the vanadium itself is highly toxic, it’s easy to cause body bronchitis, impaired vision and kidney damage. If the waste catalysts are not recovered, they will do a huge damage to environmental and body, therefore, in the great situation of environmental protection, the user must spend an expensive special costs in the recycling of waste SCR denitration catalyst. Faced with this situation, promoting a new non-toxic catalyst product has become the focus supporting and developing projects for government.
 
Many scholars and manufacturers have made great efforts in this area, also there is a new type of highly efficient, inexpensive SCR denitration catalyst product has been successfully developed. This non-toxic SCR denitration catalyst takes modified rare earth functional ceramics as a carrier, and takes cerium dioxide, tungsten trioxide as the main active ingredients; also it is mixed with a certain amount of zirconium dioxide, glass fibers, and other trace components.
 
Cerium, a silver-gray active metal, its powder is easily spontaneous combustion in the air, can soluble in acid, the highest abundance of rare earth elements. Cerium is easily oxidized at room temperature; therefore, when exposed in the air, it is easy to lose its luster and can even burn by using a knife to rasp in the air. Cerium is mainly as a reducing agent in the catalyst; it can be used as additives in manufacturing cerium salts for manufacturing medicine, leather, special glass, textile and other industries; at the same time, cerium alloy can be used to manufacture jet propulsion components because of its heat-resistant.

 

Composite Carrier Tungsten Trioxide SCR Denitration Catalyst

Denitration practices and researched have shown that the nature of carrier has a great impact on the catalyst’s activity and life. As an important part of the denitration catalyst, the developing carrier is also a problem which is eager to be solved. The catalyst most commonly used in the market today is generally takes titanium dioxide as a carrier, tungsten trioxide, vanadium pentoxide as the main active substance. Some scholars have provided a method that uses modified cordierite powder and titanium dioxide to prepare tungsten trioxide SCR denitration catalyst, thus to improving carrier performance and reducing cost, to get the high thermal stability and wear resistance flue gas denitration  catalyst which is meeting the requirements.

cellular SCR denitration catalyst Chinatungsten
 
Steps as follows:
1. Produce modified cordierite powder: immersing the cordierite powder in sulfuric acid with the temperature of 25~110 °C for 12 hours, and then drying it for 5~12 hours to obtain the modified cordierite powder;
2. Prepare catalyst active solution: dissolve the right amount of oxalic acid in deionized water for mix well, then add ammonium metavanadate, heated to 85 °C and keep the temperature for about 20 minutes;
3. Weigh the modified cordierite powder, titanium tungsten powder into a mixer, stir until uniformly mixed after glass fiber and polyvinyl alcohol added, then add catalyst activity and deionized water which are prepared;
4. Cool and adjust the solution after stirred uniformly, and decayed for 24 hours;
5. Form to honeycomb catalyst as required, and dry for 3.5~5 hours at 85~105 °C;
6. Calcining for 4~8 hours, and then continually calcining at 600 °C for 4~8 hours, to give the desired composite carrier tungsten trioxide SCR denitration catalyst products.

 

Tungsten Alloy Shielding Door For X-Ray Room

tungsten alloy shielding door for X-ray roomTungsten alloy shielding door for X-ray room is used for X-ray room in hospitals. With the unceasing updating and development of various laboratory examinations, the status of X-ray room at the hospital is rising. X-ray room, as the important auxiliary examining room in the hospital, integrates the inspection, diagnosis, treatment with each other to assist clinical departments in diagnosing many diseases and to make the result of diagnosis more obvious. Equipments in X-ray room generally include ordinary X-ray film, X-ray fluoroscopy, gastrointestinal machine, digital X-ray imaging system, direct digital X-ray imaging system, computer tomography X-ray machines, MRI scanners, digital subtraction angiography system, medical linear accelerators, medical diagnostic X-ray machine, which render the diagnosis and treatment of diseases are more convenient, simple and accurate,.

The tasks of X-ray room are to undertake the examination of outpatient, conventional X-ray examination, contrast examination and X-ray computer tomography, magnetic resonance imaging; undertake the radiological examination of health care and rescue and physical examination; carry out  consultation inside and outside the hospital and technical inspection required by superior hospital; full use of existing equipment to develop new technologies, new inspection programs; develop new diagnostic imaging technology and technological innovation of equipment; introduce the most advanced technology at home and abroad to cooperate with the clinical departments in some treatment items, such as cerebral angiography, CT hepatic arteriography, bronchial arteriography.

Since radiation used in the X-ray room is harmful, and can cause leukemia, thyroid cancer, bone tumors and other malignant tumors, and also lead to some changes in human genetic material(like gene mutation and chromosomal aberrations), causing congenital distortion, abortion, stillbirth, infertility and other diseases. Tungsten alloy shielding door for X-ray room is used as a radiation shielding barrier for X-ray room in hospitals, to avoid radiation letting out, then protect people around from radiation damage. Compared with traditional materials (such as lead), tungsten alloy shielding door for X-ray room has higher density, and thus in the same weight and the same shielding performance, the tungsten alloy radiation shielding door for X-ray room is thinner.

 

 

 

CsxWO3 Near-Infrared Absorbing Properties

Csx WO3 nanoparticles in the range of 2050 nm have been successfully synthesized by the supercritical solvothermal approach, where after dissolving WCl6 and CsOH in a mixed solution of water, ethanol and oleic acid, the solution was heated at 300°C. The products were characterized by X-ray diffraction, TEM, HR-TEM, EDS, laser particle size analysis and thermographic measurements. Csx WO3 nanoparticles showed the high transparency in the visible region, excellent shielding performance of the near-infrared light and limited reflectance of light in the range of 2002700 nm, indicating the strong absorption of NIR light on the nanosized Csx WO3 . Csx WO3  nanoparticles also exhibited quick conversion of photo-energy to local heat. 
 
Near-infrared, with the wavelength of 0.75-1.4 µm and the frequency of 214-400THz is defined by the water absorption, and commonly used in fiber optic telecommunication because of low attenuation losses in the SiO2 glass (silica) medium. Image intensifiers are sensitive to this area of the spectrum. Examples include night vision devices such as night vision goggles. Near-infrared spectroscopy (NIRS) is a spectroscopic method that uses the near-infrared region of the electromagnetic spectrum (from about 700 nm to 2500 nm). Typical applications include medical and physiological diagnostics and research including blood sugar, pulse oximetry, functional neuroimaging, sports medicine, elite sports training, ergonomics, rehabilitation, neonatal research, brain computer interface, urology (bladder contraction), and neurology (neurovascular coupling). There are also applications in other areas as well such as pharmaceutical, food and agrochemical quality control, atmospheric chemistry, and combustion research.

SEM of Csx WO3

Tungsten Alloy Shielding For Killing Pests With Irradiation

Killing pests with irradiation is a type of physical pest control technology that uses ionization radiation to interact with pests to induce a series of physical, chemical and biological effects, causing sterility and death of pests. The rays used for killing pests are mainlyγ rays(generated by Co-60 or Cs-137) and high-energy electrons(below 10MeV) as well as X rays(below 5MeV) produced by accelerator. Of which cobalt irradiation has developed fast while the development of electron beam and X-ray irradiation are relatively lagging behind. But with the recent development of accelerator technology, electron beam irradiation shows its unique advantages, and has been paid more and more attention. Due to electromagnetic radiation is harmful to human health, normally using tungsten alloy shielding for killing pests with irradiation to protect staffs from the radiation.

tungsten alloy shielding for killing pests with irradiation

Physical pest control method is also called pest irradiation on quarantine, namely uses a variety of electromagnetic radiation (such as microwave, ultraviolet,γ ray, X-ray, ultrasound, infrared, etc.) to irradiate the eggs, larva, pupa, adult, resulting in a series of physiological changes in the body of peats, leading to metabolic disorder, loss of reproductive capacity, and ultimately death. A certain doses of electromagnetic radiation can cause the death and infertility of insect, and shorten its life, delay its eclosion and development, as well as reduce its hatching. Thus, irradiation insecticidal technology is widely used in food industry, animal husbandry and agriculture, for the quarantine treatment of animals and plants and pest control and sterilization in food processing.

Lead is primally used as a shielding material, but there are some problems exist in the long term use of lead shielding. Lead and its compounds can cause human poisoning by entering into human body through respiratory or digestive tract. While compared with lead, tungsten is non-toxic and non-radioactive, so that it will not harm human health. Moreover, the high density of tungsten alloy also makes it thinner and lighter than lead in the situation of the same weight and shielding performance with lead. 

 

Fluorine-18 Tungsten Radiation Shielding

fluorine-18 tungsten radiation shieldingFluorine-18 tungsten radiation shielding is usually used to shield radiation released when producing and using fluorine-18 and its compounds.Fluorine-18 is a radioisotope of fluorine with half-life of 109.771 minutes that plays an important role in positron source. It decays by positron emission 97% of the time and electron capture 3% of the time. Both forms of decay yield stable oxygen-18. Fluorine-18 is primarily synthesized into fluorodeoxyglucose to use in the radiopharmaceutical industry. It can be used as a tracer in positron emission tomography scan. Use of this tracer to detect the possibility of cancer metastasis is the most frequent type of PET scan in standard medical care.

Fluorodeoxyglucose also can be applied to evaluate the glucose metabolism in the heart, lungs and the brain, and to image tumors in oncology, where a static F-FDG PET scan is performed and the tumor F-FDG uptake is analyzed according to Standardized Uptake Value. FDG-PET can be used for diagnosis, staging, and monitoring treatment of cancers, particularly in Hodgkin's disease, non-Hodgkin's lymphoma, breast cancer, melanoma, colorectal cancer, and lung cancer. It has also been approved for using in diagnosing Alzheimer's disease. Since fluorine-18 is radioactive and toxic, tungsten radiation shielding is usually used to shield radiation released when producing and using fluorine-18 and its compounds.

Fluorine-18 tungsten radiation shielding is made of tungsten alloy with high density. According to the research, the radiation shielding performance of a metal material is closely related to its density .AS the density is higher, the radiation shielding performance is greater. Therefore the radiation shielding performance of fluorine-18 tungsten radiation shielding is great. Fluorine-18 tungsten radiation shielding is a best choice for shielding radiation generated during the preparation and the use of fluorine-18 and its compounds. In addition, tungsten alloy is environmental non-toxic so as not to pollute the environment or endanger human health.

 

Rare Earth Doped Tungsten Electrode Morphology Effect by Rare Earth Doping Quantity

Rare earth doping quantity not only affects rare earth doped tungsten electrode’s welding ability and burning resistance, but also has some impact on electrodes morphology. Using powder metallurgy method to produced tungsten electrodes doped with three rare earth oxides, and according to different rare doping content the electrodes are divided into A electrode and B electrode. The A electrode rare earth ratio is La2O3: CeO2: Y2O3 = 1: 2: 1, and the B electrode rare earth ratio is the ratio of the electrode B is La2O3: CeO2: Y2O3 = 1: 1: 3. Analysis two kinds of rare earth doped tungsten electrodes and ceriated tungsten electrode’s morphology to further understand the impact of rare earth doping amount on rare earth doped tungsten electrode morphology.

Analyzing three kinds of electrode processing states section topography photos found the rare earth oxides in three kinds of electrodes has different shape and distribution. Ceriated tungsten electrode formed a very fine and uniform fibrous CeO2 phase. The A electrode rare earth phase is also fibrous, but uneven, appeared a small amount of fiber breakage. The B electrodes rare earth phase are particles, and the particle and particle link by particle clusters, indicating they are formed by big particles breakage during processing.

After burning test, electrode surface morphology has taken place great changes. Ceriated tungsten electrode tip appeared annular projection, through EDX found them to be cerium oxide, indicating in a large number of cerium oxide enriched to the electrode surface during welding. The A electrode tip has plenty of bulk composite rare earth oxide, and it is composed of smaller particles. The B electrode has special tip morphology. There are many smooth pyramids on matrix surface, which is located in the center of the grain, and a small amount of pyramids has fracture on the top to form some voids. Therefore, the surface of the B electrode is also some small voids, indicating the surface of the B electrode was melted in the welding.

tungsten electrode morphology

 

Rare Earth Doped Tungsten Electrode Performance Effect by Rare Earth Doping Quantity

tungsten electrodes

With the development of welding industry, modern industry has higher requirements on electrode welding property, welding stability and pollution standard. Thoriated tungsten electrodes have good welding properties, but it has radioactive contamination, gradually being replaced by other rare earth tungsten electrodes, such as ceriated tungsten electrodes and lanthanated tungsten electrodes. Rare earth oxides having low work function and excellent thermal electron emission property so rare earth doped tungsten electrode has good welding stability and welding ability. However, at AC TIG welding (tungsten argon-arc welding), there are some shortages including poor arcing property, short life and other issues. Tungsten electrode doped with three rare earth oxides is produced for improving these shortages. In general, tungsten electrode doped with three rare earth oxides has better arcing property and welding stability than tungsten electrode doped with two rare earth oxides. In the tungsten electrode doped with three rare earth oxides, different rare earth doping quantity has a certain influence on rare earth doped tungsten electrode welding  performance.

Using powder metallurgy method to produce two different rare earth content tungsten electrodes doped with three rare earth oxides, and the electrodes will be divided into A electrode and B electrode. A electrode rare earth oxide ratio is La2O3: CeO2: Y2O3 = 1: 2: 1, B electrode rare earth oxide ratio is La2O3: CeO2: Y2O3 = 1: 1: 3. Comparing these two electrodes with ceriated tungsten electrodes, we will more comprehensive understanding he use performance of electrodes.

These three electrodes were placed on the TIG welding machine, high frequency arcing to test electrode’s welding property and burning loss property, in TIG welding tungsten electrode as a negative electrode, a water-cooled purple copper as the positive electrode. During arc experiments, electrode current is 60A / 120A and arcing duration is 10s / 20min, repeated 10 times in each electrode. From experiment data we knew that B electrode and ceriated tungsten electrodes has better arcing performance and welding performance. A electrode arc performance is general. But burning loss rate of tungsten electrode doped with three rare earth oxides is smaller than ceriated tungsten electrode, so it has better burning resistance property, and B electrode is better than A electrode.

 

New Skills of Hitting on Girls—Tungsten Dart

When seeing the title, your first reaction may be: what is the relationship between new skills of hitting on girls with tungsten dart? Will it replace the tungsten gold ring then use tungsten dart as courtship gifts for winning over your beauty? Or if you have a set of tungsten darts you can incarnate Leonardo Dicaprio minute-by-minute? In fact, you can just have a try.
 
We often see such a scene in some foreign film: the heroes were sitting in the high chairs on the bar and drinking beer, refreshing laughing. There was hanging a dart board in a distant of 8 feet from them, and then one man took off a dart and hit the bull’s-eye of the dart board at the moment of chattering and laughing. The handsome posture, beautiful arc cast by dart, and the dull thud finally made by hitting the bull's-eye… this scene was rather too cool that can not help but repeatedly applauded, and captured countless young girl's heart at the same time. It can be seen that the dart that can create such a “hitting on girl” effect is not the normal dart, or it will fail to hit on girls.
 
Okay, here comes to the gracefully tungsten dart. Tungsten dart has the fashion appearance and metal texture, fine thread and properly hand feelings. When you pick up tungsten dart, it will be with handsome, after casting, the heroic spirit dwells. The characteristics of high density makes tungsten dart can have smaller volume, non-toxic and environmentally friendly characteristics also deeply fit in the life’s theme of creating the green earth. Such tungsten dart is easily manageable, and its centre of gravity is also stable, which makes it easier to locate the locations and scores that you want on the dart board. It can also obtain the perfect performance, and have the big help for you to hit on girls. In view of this, why not ask your favorite out to gym and show your handsome performance with tungsten dart in sunny weekend, and try the new skills of hitting on girls brought by tungsten dart?
tungsten dart

 

 

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