Working Condition Affects Tungsten Trioxide SCR Denitration Catalyst 1/2

The properties of tungsten trioxide SCR denitration catalyst will cause a direct effect on the whole denitration system, the different working conditions cause the different catalyst design; therefore, the scientific and reasonable choice of a catalyst form, amount and type is becoming the key of designing SCR denitration system. In this paper, we propose how the five kinds of working conditions affect tungsten trioxide SCR denitration catalyst.

SCR denitration catalyst
 
1. High content of calcium
CaO will cause catalyst poisoning, it performance as that when the content of CaO is very high in the fly ash, or the flue gas has a high sulfur trioxide content, large amounts of calcium sulfate will easy to produce in the catalyst surface, they adhere to each other thus to form a bridge, and cause shielding of catalyst surface, thereby reducing catalyst activity.
 
2. High ash
Currently, the mainstream types of catalyst have been used are honeycomb, plate and corrugated plate. Among them, the plate exhibits more favorable advantage in a high fly ash condition; and corrugated plate shares a relatively low market, which is less than 5%. Generally, when the concentration of fly ash in flue gas is among 50~60g/Nmor even higher, choosing the plate which is not easy to plug fouling will bring more safety operation, due to the far greater cross-sectional area it has. However, when in a lower ash concentration, the plate catalyst will inquire 20%~40% more than the honeycomb under the same engineering conditions, thus resulting in initial purchase costs of the catalyst and other auxiliary parts increasing.
 
3. High temperature
The suitable temperature of tungsten trioxide SCR denitration catalyst is generally 300~400°C, however, even in this temperature range, a large amount of catalyst will be required to meet the basic denitration ratio. The amount of catalyst depends on the parameter like NOx concentration, gas flow, and denitration efficiency requirements.

 

Arc Performance Affected By Tungsten Electrode Organizational Structure

tungsten electrods

During the welding process, arc performance not only connects with power supply unit and the environmental conditions, it also depends largely on the tungsten electrode’s arc performance. Good arc performance directly determines the use and application range of tungsten electrodes. The organizational structure of the tungsten electrode has a certain impact on tungsten electrode’s arc performance. In general, the integrity and uniformity of the tungsten electrode structure will directly affect the arc performance. If tungsten electrodes inside has splitting, delamination, micro-cracks, voids, mezzanine or severe non-uniform grain structure, the arc process is instability. So it will occur arc breaking, arc blasting, drift, and the worst case will cause thermal and electric, conductivity decreased, so that electrode’s local will overheating, melting, deformation, reducing the arc performance. In addition, at high temperatures, the electrode structure is closely related to the chemical composition. At High temperature, the doped rare earth oxides is easily migration, evaporation, dilution resulting in recrystallization coarsening to cause cracks.

Organizational structure and chemical composition of the tungsten electrode can affect their physical and mechanical properties, thus affecting its arc performance. Tungsten electrode as an important part in welding tool should have good physical and mechanical properties, such as, high melting point, high boiling point, low vapor pressure, good thermal conductivity and electrical conductivity, high temperature strength and high recrystallization temperature and creep and other good properties. If the physical property and mechanical properties of the tungsten electrode is defective, then it can result in electrode deformation and melting during the welding, leading arc performance deterioration. Different type rare earth tungsten electrodes have different deformation resistance and high temperature resistance. In general, tungsten electrode doped with two rare earth oxides is better than pure tungsten electrode and tungsten electrode doped with three rare earth oxides is better than tungsten electrode doped with two rare earth oxides.

Arc Performance Affected By Tungsten Electrode Chemical Composition

thorium tungsten electrodes

Tungsten electrode arc performance is affected by physical and chemical property, mechanical properties, chemical composition and organizational structure. The following will analyzes the influence of tungsten electrode chemical composition on arc performance in welding process.

Pure tungsten electrode has high electron work function and it is not conducive to high electron stream emission, so the service life and arc performance is poor, which directly affect the welding performance. In order to improve the disadvantages of pure tungsten electrode, with further research, manufacturers developed rare earth tungsten electrode and multiple rare earth tungsten electrodes. According to the current density formula of physics emission mechanism Je = AT2exp (-eφ / kT) shows that, in order to reduce eφ (electronic charge), we can add rare earth oxides or other elements in tungsten electrodes to low eφ’s value. Different types of rare earth tungsten electrodes having a particular Je value, so they arc performance are relatively stable.

Tungsten electrodes chemical composition’s type, content, distribution and high temperature characteristics determine the ignition and stability of the arc. In terms of content, taking single rare earth doped tungsten electrode as example, rare earth oxide content is higher, the better the arc performance of the electrodes. In addition, the uniformity distribution and high temperature evaporation and diffusion behavior of rare earth oxides also affected arc performance to some extent. The main reason for arc performance deterioration is caused by doped rare earth’s evaporation and decomposition. Different type rare earth tungsten electrode under different conditions has difference arc performance, tungsten electrode doped with two rare earth oxides is better than pure tungsten electrode and tungsten electrode doped with three rare earth oxides is better than tungsten electrode doped with two rare earth oxides.

Tungsten electrode during operation, the ends of the electrodes will produce ring mushroom nodules, called "Rim" phenomenon. This is because tungsten electrode surface has more added rare earth oxide content than the central portion, in favor of arc in a short time. When the protective gas is mixed with a small amount of O2 or welding parameters transferred to short-term overload state, it will occurs "Rim" phenomenon. This phenomenon is still under study, some scholars believe that this is due to the tungsten oxide and rare earth oxides evaporation, decomposition, precipitation and segregation at the high temperature to occur dephlegmation and segregation precipitation. In fact, it is the chemical composition of the tungsten electrode changed at high temperatures. "Rim" phenomenon is good for arc in short time, but for a long time will lead to surface additives concentration reduction affected arc electrode performance and increased consumption.

TiC Effect on Tungsten Carbide Button Properties (2/2)

With the increase of the added amount of TiC, its grain refinement, solid solution strengthening effect began to appear, which is beneficial for improving the bending strength of tungsten carbide buttons. And thereafter continue to add TiC, sintered body appeared in the ring structure with non-normal tissue, which is thus the core parts containing lower amounts of solid solution WC and an outer layer containing a high amount of WC solid solution consisting of the ring with will make the structure appear flexural strength decreased more obviously. The variation of fracture toughness is similar to the bending strength.

From the point of view fracture surface, tungsten carbide button after fracture section added TiC is smoother and the distribution is more uniform. And by observing the hard phase of WC and Co binder phase section can be found in WC grains tend to diversify, it also shows that the fracture of the alloy phase is broken along the border and the bonded phase WC grains and binder phase, rarely WC grains through the break, and it is related to the dispersion of fine-grained solid solution with TiC phase of strengthening.

Furthermore, there are some pores in the section, especially the surface of alloy without adding TiC. In the process of solid phase sintering, because of rigid WC skeleton hinder shrinkage during cooling of briquettes contraction and solidification Co generated carbide makes it impossible to completely fill the screen, resulting in the formation of pores shrink tube; on the other hand, uneven distribution and the gas generated during sintering forming agent is one of the reasons. In addition, TiC also has an influence on the routes of cracks expanding. It will have containing and pinning effect on the movements of WC grain boundaries. And owing to a great difference of elastic modulus and coefficient of thermal expansion, the residual stress of TiC and the matrix in the process of sinter cooling, which resulting in cracks in the offset process of moving forward, extending the cracks propagation path.

TiC Effect on Tungsten Carbide Button Properties (1/2)

TiC has higher melting point, boiling point, hardness and excellent chemical stability so that it can be widely used in tungsten carbide materials. In order to analyze the effect of TiC on tungsten carbide button, we study from the hardness, the density, the bending strength, fracture toughness and other mechanical properties. The experiment shows that with the increase of the addition amount of TiC, relative density of tungsten carbide button is rising. This is due to tungsten carbide button without TiC has some internal pores or defects by the raw material and the problems in the overall process, its relative density is lower; on one hand, TiC added refine the micro-structure of tungsten carbide button, on the other hand, ne-grained TiC particles uniformly distributed in the gap between the WC particles were packed efficiently so that the distribution of the alloy grain structure more uniform and reasonable, and thus increased densification of tungsten carbide buttons.

Viewed from the hardness, TiC has better hardness than WC, so with fine grains having a dispersion strengthening effect of TiC added, the hardness of the material also increased. However, when TiC is increased to a certain amount, the hardness of the tooth carbide ball longer because TiC added increasing amounts of rises, inside the material has been basically compact at this time. For the bending strength, with the increase of TiC addition amount of the bending strength of tooth carbide ball was dropped after the first rise and then fall. This is due to the TiC added after sintering temperature is lower than the carbonization temperature, dissolved in WC TiC slow imbalance occurs alloy, WC in solid solution reduced the amount of binder phase of Co carbide wettability deteriorated.

tungsten carbide buttons

 

Proper Preservation Methods of Tungsten Gold Plated Coin

Tungsten gold plated coin, is a kind of commemorative coin that manufactured with tungsten alloy as raw material, and therefore it is often referred to as tungsten gold coin, or tungsten gold commemorative coin. It has high appreciation value and collection value, and because of the unique high-density corrosion resistance, abrasion resistance, non-toxic and environmentally friendly characteristics of tungsten alloy, tungsten gold plated coin has the longer-term preservation of gold coins. The worth of tungsten gold plated coin is less than gold, but both feel almost similar, and equally beautiful. In order to plate gold in the surface of tungsten gold plated coin for obtaining the same exquisite appearance as gold coin, it can also be plated with silver, platinum, rose gold and so on, which can have different and unique beauty. It is because of all these advantages, tungsten gold plated coin can be engraved with all kinds of different patterns to convey different meanings and feelings by people. Although tungsten gold plated coin has good wear resistance and corrosion resistance, but in normal life, we also need to pay attention to its preservation methods to extend the life of its collection, and long maintain its aesthetics. The proper preservation methods of tungsten gold plated coin can be summarized as follows:
 
1. Avoid contact with chemicals. Shower gel, shampoo and women used cosmetics in ordinary life contain many chemicals, so we should avoid storing tungsten gold plated coin with them so as to prevent tungsten gold plated coin’s gold plating layer reacts with chemicals, thereby destroy its appearance.
 
2. Avoid direct play with hands. Although tungsten gold-plated coin has high wear and corrosion resistant, but since the surface layer is gold-plated, so in order to avoid the problems caused by sweat, we should wear gloves or other items can isolate our hands and tungsten gold plated coin.
 
3. You can buy dedicated circular transparent box of commemorative coin, it will not affect the watch play; and can also play a protective role.
 
4. If you do not watch and play tungsten gold plated coin in a long-term, it should be kept under seal. Should you are in areas where is too wet, you can put some desiccant to reduce humidity before sealing. But note that the desiccant should not be in directly contact with tungsten gold plated coin.
 
5. The tungsten gold plated coins should be stored separately, to avoid the damage of the gold layers caused by friction between them.
tungsten gold plated coin

 

BSTN Composite Ceramics with Perovskite and Tungsten Bronze Phases

Special compositions of Ba0.7Sr0.3·(1-y)TiO3·yNb2O5 were designed for preparing the BSTN system by the traditional ceramic method. The composite ceramics in which the two phases of the perovskite (BST) and the tungsten bronze (SBN) coexist were successfully prepared by this composition controlled in the excessiveness of some components. XRD and LCR were used to measure the structure and dielectric constants of the composite ceramics. It is found that, in the perovskite (BST) structured system of BSTN ceramics, the second phase SBN starts to appear when the excessive content of Nb2O5 is up to about 6mol%. Similarly, in the tungsten bronze (SBN) structured system, the second phase of BST can also begin to form while the excessive content of (BaO+SrO) is up to about 11mol%. 
 
However, both the perovskite and the tungsten bronze phases formed in a system exhibit the different minorities of Nb2O5 and TiO2 solved respectively with changing the excessiveness. Especially in the case of the two phases being equivalent to each other in BSTN composite ceramics, Nb2O5 is hardly to be solved into the perovskite phase due to shortage of Nb2O5 and excessiveness of TiO2 in composition. However, a few of TiO2 is easily to be solved in the tungsten bronze phase due to excessiveness of TiO2.There is a dual characteristic shown by the perovskite phase and the tungsten bronze phase in temperature dependence curve of dielectric constant in the BSTN. The Curie temperature of the tungsten bronze phase decreases with the increase in solubility of TiO2 in the phase structure. Conversely, the Curie temperature increases with increasing perovskite phase due to the primary effect of the tungsten bronze phase being restricted by a lot of perovskite. The lowest transition temperature between ferroelectric and paraelectric phases in the BSTN is at about 200℃ and it is 90℃ lower than that of the SBN without TiO2 solved in the present work.

tungsten bronze

Tungsten Alloy Radiation Shielding For GPS

tungsten alloy radiation shielding for GPS Tungsten alloy radiation shielding for GPS is used for shielding the electromagnetic radiation generated in the using of GPS. The Global Positioning System, referred to as GPS, is a space-based navigation system that provides location and time information in all kinds of weather conditions, anywhere on or near the Earth where there is an unobstructed line of sight to four or more GPS satellites. The system consists of three major segments, which are the space segment, a control segment and a user segment. The space segment is made up of 24 satellites. The control segment is composed of a master control station, a ground antennas and monitor stations. The user segment is GPS signal receiver.GPS has the characteristics of high precision, all weather, short observation time and easy operation.

Global Positioning System is a satellite navigation system designed to provide instantaneous three-dimensional position information almost anywhere on the globe at any time, and in any weather. With the continuous improvement of GPS, it has been widely used in all fields, and gradually deep into people's daily life. Such as it can be used in the patrol vehicle management to monitor the location information of vehicles for the inspection of the tasks accomplished, and to automatically complete the vehicles dispatch by analyzing the distance  from all vehicles to event point and the current state of vehicles. In the car navigation and traffic management, GPS can be used for navigation by aircraft, ships, vehicles and pedestrians; in a navigator, the GPS can achieve the function of map query, route planning, self-navigation and other. GPS systems can also be used in military, fire fighting, logistics and other fields.

GPS is mainly to receive satellite signals through electromagnetic waves. The electromagnetic radiation has radiation characteristic that can cause harm to the body's central nervous system, immune function, cardiovascular system, reproductive system, vision system. Therefore, it should be accompanied by the use of certain radiation protection measures (such as using tungsten alloy radiation shielding for GPS) to protect the human body when using GPS. Tungsten alloy radiation shielding for GPS has good radiation shielding ability, and can shield electromagnetic radiation to avoid human suffering from radiation damage in the long-term electromagnetic radiation environment.

 

Tungsten Alloy Radiation Shielding For DSA System

Tungsten alloy radiation shielding for DSA system is a tungsten alloy shielding used for digital subtraction angiography system. DSA system, also known as digital subtraction angiography system, is a new x-ray imaging system to clearly visualize blood vessels in a bony or dense soft tissue environment by computer. Images are produced using contrast medium by subtracting a ‘pre-contrast image’ or the mask from later images, once the contrast medium has been introduced into a structure. Compared to the conventional angiography system, images obtained by digital subtraction angiography system are more clearly and intuitively, even some fine vascular structures can be displayed.

tungsten alloy radiation shielding for DSA systemDigital subtraction angiography system is suitable for the examination of heart and great vessels. It clearly shows the structural abnormality of heart anatomy, coronary, aortic coarctation, aortic dissection, aortic aneurysm, developmental anomaly of aorta, etc; and also clearly shows the cervical segment and intracranial arteries for diagnosing intracranial aneurysms, cervical artery stenosis or occlusion, vascular anomaly, arterial occlusion and for observation of intracranial tumor‘s feeding artery. In addition, digital subtraction angiography system can be used to check large blood vessels, abdominal aorta and its branches. At the same time, digital subtraction angiography system can also be used for the interventional treatment in all parts of the body lesions, such as interventional embolotherapy in treatment of liver cancer, cerebral aneurysms, cerebral arteriovenous malformation,and percutaneous balloon mitral valvuloplasty, percutaneous puncture biopsy.

Since digital subtraction angiography system is an X-ray angiography system basing upon image subtracting. And X rays can inhibit, destroy or even kill biologic cells, causing different degrees of changes in physiological, pathological and biochemical aspects of organism. Therefore, it is need to use a tungsten alloy radiation shielding to shield and absorb X rays when using the digital subtraction angiography system. Tungsten alloy radiation shielding for DSA system has excellent radiation shielding performance to shield radiation and avoid it damaging human body.

 

Tungsten Alloy Shielding For Radioactive Tracer Technique

tungsten alloy shielding for radioactive tracer techniqueTungsten alloy shielding can be used to shield the radiation released from the radioactive tracer technique. Radioactive tracer technique is used to track the passage of a sample of substance through a system. The substance is "labeled" by including radioisotopes in its chemical composition. When these decay, their presence can be determined by detecting the radiation emitted by them. Then the movement condition and change rule of the substance can be distinguished. Radioactive tracer technique has the characteristics of high sensitivity, high quantitative accuracy, simple method, accurate localization and conforming to the physiological conditions, etc.

Radioactive tracer technique has been widely used in industrial production, agriculture and animal husbandry, health care, life sciences, and other fields. In agriculture and animal husbandry, it can be used to study the fertilizer absorption rule of crops and discovery the life cycles, migratory habit, mating behavior and foraging behavior of insects, parasites, fishes and animals; in medicine, it is mainly used for the diagnosis of the disease; in industrial production, it provides the possibility of using a variety of high-efficiency testing methods and automatic control methods for the production process, solving many technical and theoretical issues, such as determining the diffusion rates of certain elements within the metal sheet; in the life sciences, it can dynamically observe the physiological and biochemical processes within the cell or in vivo at molecular level, understanding the material basis of life activities. Check the chemical reaction process of research of environmental pollution radioisotope tracer technique can also be used. Radioactive tracer technique can be also used for the detection of environmental pollution and research of a chemical reaction process.

Radioactive tracer technique has found an increasingly wide utilization in our life. But due to the rays released form it will cause harm to human body, the use of tungsten alloy radiation shielding in the radioactive tracer technique is necessary. Generally, tungsten alloy shielding is made up of tungsten heavy alloy which has high density and great shielding effectiveness. Thus tungsten alloy shielding can shield the radiation to protect the staff from radiation damage.

 

 

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