The Classifications of EB Tungsten Filament

All EB (electron beam) tungsten filaments are made of tungsten which is also known as wolfram. The EB tungsten filament has a good discharge performance and an excellent anti-sag performance. The two characteristic can ensure that the filament is not deformed during working. The following classifications are the main types of EB tungsten filament.

Classification

Specification

Picture

Mosquito Coil: the shape of the EB tungsten filament is similar to the mosquito coil, therefore, it can be named as Mosquito Coil. And the Mosquito Coil can be divided into the following specifications.

0.55mm

electron gun filaemnt 0.55

0.65mm

electron gun filament 0.65

0.80mm

electron gun filament 0.8

Pull-type: Pull-type is also known as the cavity type of Mosquito Coil.

0.80mm

electron gun filaemnt 0.8

Classification

Specification

Picture

U-shaped: this kind of  EB tungsten filament is similar to the shape of the letter U.

0.80mm

electron gun filaemnt U 0.8.

U-shaped with folding legs: the feet of the EB tungsten filament has a curved.

0.80mm

electron gun filaemnt Uz 0.8.

Half Moon: the shape of this type is the shape of a half moon.

0.80mm

electron gun filaemnt half moon 0.8.

Straight shape

0.80mm

electron gun filaemnt straight 0.8.

 

Low-NOx Combustion Unit Uses Tungsten Trioxide SCR Denitration Catalyst

The two major mechanisms of NOx formation in low-NOx combustion unit are while reducing combustion temperature, the concentration of oxygen in the fire zone also be reduced, in order to suppress the formation of nitrogen oxides in the furnace. The concentration of NOx emissions can be reduced by 30% to 60% by using low-NOx combustion furnace technology. Nowadays, the widely used low-NOx combustion technology is mainly through low-nitrogen furnace transformation, for achieving the goals of low-oxygen, hierarchical partitioning combustion in the furnace, thus to achieve the reduction of NOx emission.

flue gas denitration equipment
 
Due to the limitations of the furnace low NOx combustion technology, the NOx emissions can’t meet environmental requirements, so denitration process should be carried out in order to further reduce NOx emissions. Dry, semi-dry and wet method ate the prevailing flue gas denitration processes. Wherein, dry SCR denitration process is of high commercial value and being widely used with its nice properties, such as simple structure, easy operation, high reliability, high denitration efficiency, relatively low initial Investment.
 
SCR device consists of denitration reaction preparation system and the composition of the reactor body, reducing NOx into nitrogen and water vapor by injecting into denitration reaction agents--NH3 into the reactor. SCR denitration catalysts are generally taking titanium dioxide as a carrier, vanadium pentoxide and tungsten trioxide as the main active ingredients, its activation temperature is generally between 300~400 ℃. Tungsten trioxide plays the role of anti-curing, anti-poisoning in the catalyst, thus to enhance the activity of the catalyst. SCR denitration reactor can be divided into high and low dust categories according to installation location of precipitator. However, due to low dust device needs to install a steam heater and flue gas heat exchanger (GGH), which makes the system complex, investment increased, so the generally chosen is the high dust process.

 

CaO Effects Designing WO3 Denitration Catalyst

denitration catalystCalcium oxide (CaO), the so-called quicklime, is an inorganic compound powder with white, hygroscopic and corrosive. The plaster (Calcium sulfate) in thermal power plant is generated by sulfur dioxide reacting with desulfurization and then oxidized, and then discharged with the flue gas exhaust system. When it comes into being that calcium sulfate contacts with tungsten trioxide SCR denitration catalyst, large number of calcium sulfate will be deposited on the surface of the catalyst, which can cause the catalyst surface shielding, and then the catalyst activity decreased.
 
By the time the content of calcium oxide in the flue gas is less than 5%, little effect has occurred on catalyst design. However, when the content of calcium oxide is more than 5%, its effect on the catalyst design generates becomes very large. With the calcium oxide content increasing, the amount of tungsten trioxide SCR denitration catalyst turns to linearly increasing trend, especially when the calcium oxide content is about 30%, the consumed catalyst required will increase about 25% compared with low calcium conditions. In this condition, catalyst activity and aging speed can’t overestimate when design catalyst; in order to ensure the chemical catalyst lifetime (24,000 hours), we need to leave enough adequate catalyst, thus will result in a larger number of design volume and costs increased.
 
Therefore, in the high calcium conditions, the blind pursuit of a minimum amount of tungsten trioxide SCR denitration catalyst will result in a short life of the catalyst, reduction denitration efficiency decreased and other adverse consequences. Besides, if we ignore the impact of calcium on the running of catalyst, reduce design margins unprincipled, overestimated the catalyst activity, the risk of high operating costs will present although it bring cost savings to some extent. It is worth mentioning that, the presence of tungsten trioxide can effectively inhibit the sintering of the catalyst particles, delaying the degree of sintering, therefore, tungsten trioxide SCR denitration catalyst is particularly suitable for high calcium conditions.

 

Tungsten Bronze (TB) Crystal Structure

The tungsten bronze (TB) crystal material, due to good optical effects, electrical properties and blastic phase boundary and so on, has been widely used in the technical field of laser frequency doubling, optical modulator, optical information processing, superconducting, humidity sensors, fuel cells and other solids. Molecular design of TB crystal material is to design on the atomic level, explore and synthetic crystalline material of the target structure based on the understanding of its structure. In recent years, this area has made a lot of new results, which becomes an effective means of research and development and improved performance of this type of crystal material.
 
Tetragonal tungsten bronze (TTB) crystal is relative common of tungsten bronze type crystals, (many rhombic TB structure is a superstructure of TTB structure), which is widely used. So the commonly known TB crystal mainly refers to the TTB crystals. the structure projection of C-axis shown in FIG. B-O octahedra corner-top connection formed pentagonal, square and triangular pores. They are called A1, A2 and C positions. The thick solid line drawn is a unit cell, wherein: the number of void ratio down to A1: A2: C = 4: 2: 4, ie there are10 positions of A totally; and 10 positions of B and 30 of O2 -.
 
B position can be divided into two B1 position (cell edges midpoint) and eight B2 position (cell interior) based on symmetric types. C axis translation period equals to the height of a B-O octahedron . In the structure: coordination number of A2 and O2- may be 9,10,11,15, ligand effect of A2, C, B and O2- respectively are 12,9 and 6.
 
Therefore, the formula of TB structure is (A1) 1 (A 2) 2C4 (B1) 2 (B2) 8O30. When six A1, A2 positions are not filled with cation and C position is completely empty, it is called not filled structure; when six A1, A2 positions are all filled with cation and C position is completely empty, it is called full structure; When six A1, A2 positions and C position are all filled with cation, it is called completely filled structure.

TB structure

 

Tungsten Carbide Ball for Universal Joint (2/2)

Tungsten carbide ball is composed of hard phase WC and binder phase Co. It has higher hardness, strength, excellent wear resistance and chemical stability, which is the ideal material for universal joint. In the arc type universal joint, the active fork ball and do some carbide groove driven fork mounted four synthetic carbide ball raceway can accommodate four carbide balls. Besides, there is a spherical ball mounted in the center of the groove as centering ball. Straight groove raceway-type universal joint in the two fork ball with carbide straight grooves, straight grooves and each axis is inclined relative to the center line and the same tilt angle and symmetrical to each other. Built in the raceway between the two fork ball has four tungsten carbide balls.

Velocity joint cage can be divided into stationary and scalability ball basket universal joints according to the movement of the universal joint axial direction. Viewed from the structure, fixed cage universal joints are composed of spline, star sets, curved groove. Star spherical shell fitted jacket and synthesized six races, each mounted in each race a carbide ball and keep cage carbide ball inside in the same plane. It powered by a drive shaft through a spherical shell and tungsten carbide ball. The structural feature of scalability ball basket universal joints is the inner wall of the cylindrical shell of the star and the external cylindrical sleeve made straight slot, built-in two raceways fitted together after the formation of cemented carbide ball. Star set bore splined for connection with the input shaft, which allows relative movement of the tubular sleeve in the axial direction. Overall, due to high hardness, high strength, wear and corrosive resistance, tungsten carbide ball has a broad application prospect in universal joints.

Tungsten Carbide Ball for Universal Joint (1/2)

Universal joint like joint on human limbs, it is a kind of component that change the angle and achieve power transmission, which is also called universal connect. Universal joint can be usually seen in driving system gear in cars or some mechanical equipment, whose main role is to change the position of the shaft line direction. On the front-engine rear-wheel drive vehicles, the universal joint transmission device is installed between the transmission output shaft and the drive axle final drive input shaft; while the front-engine front-wheel drive vehicle is omitted, drive shaft, universal joint mounted between the drive and is also responsible for steering the front axle and the wheel axle.

According to elastic twist direction, it can be specifically divided into rigid and flexible universal joint. Flexible universal joint assembly is mainly composed of elastic rubber-like, temporarily go into details here. We discuss the most common rigid joints in constant velocity joints here. As the name implies constant input shaft and output shaft universal joint is connected is always equal to the instantaneous angular velocity of the transfer direction of movement section, which can be subdivided into fork-ball constant velocity joints and constant velocity joints ball basket. Fork-ball constant velocity joint consists of two fork ball with raceway and ball composition. It is unavoidable that the groove and ball will endure friction, impact and other interactions during the process, especially will probably be contacted with some corrosive liquid, which put higher requirements for the materials.

Tungsten Carbide Ball for Universal Joint

 

Tungsten Electrode Production Technology - Hydrogen Reduction

Rare earth tungsten electrode greatly improved pure tungsten electrode welding performance and greatly broadened in welding, plasma welding, cutting, painting and other areas application. The production techniques failed to break greatly constricts rare earth tungsten electrode industrialization production. Therefore, to study tungsten electrode production technology has a certain significant on tungsten electrodes volume production and application field expansion. The production processes of tungsten electrode include raw material doped-pressing-pre-sintered- sintered-swaging process-recrystallization annealing-drawing-straightening-polished and so on.

Using two-step hydrogen reduction method to obtain elemental metal tungsten and uniformly doped rare earth oxide powder, using hydrogen as reducing agent. The main reactions in reduction reaction are rare earth nitrate decomposition, APT decomposition and tungsten oxide reduction. China is the largest tungsten and related products producer, thus reducing furnaces in industrial production have high automation level and can automatic control a plurality of temperature zones’ temperature. During the reduction process, adjusting each temperature zone reduction temperature, generally obtained powder particle size are in line with production requirements. The first reduction general operated in reduction furnace with four pipes, and the second reduction operated in reduction furnace with eleven pipes. The whole reduction process is divided into five temperature zones and the third temperature zone is the highest.

Tungsten powder and rare earth oxide powder’s average particle size and bulk density is quality standard. Bulk density refers to per unit volume freedom filled tungsten powder’s weight, usually showing g/cm3, and it is a simple and fast way to evaluate thickness of the powder. The average particle size is another reference index for particle thickness testing.

tungsten electrodes and hygrogen reducing furnace

Tungsten Electrode Production Technology - Doping Process

Tungsten electrode used in welding, cutting, painting and metallurgical industry is more and more widely. Pure tungsten electrode has higher electron work function, therefore it is difficult to arcing and arcing stability is also poor. Adding rare earth oxides can improve the pure tungsten electrode welding performance to improve the shortages of pure tungsten electrode, thus greatly expand the application areas of the electrodes. The common rare earth tungsten electrodes include thorium tungsten electrodes, cerium tungsten electrode and lanthanum tungsten electrode.

Tungsten electrode usually uses powder metallurgy method to produce. The main processes include doping, mixing, pressing, pre-sintered, sintered to produce blank, then through multistage swaging process recrystallization annealing, drawing straightening, polishing and a series of processes to get the finished products. Tungsten electrode production processes are complex, from the original powder doped to obtain the finished product to be subjected to more than a dozen steps, interlocking and interaction between each step. Therefore control tungsten electrode‘s production process, to develop a reasonable process parameters for obtain high-performance tungsten electrode has great significance.

Doping process is the first step of tungsten electrode production. Whether uniform doped rare earth or not will have direct impact on tungsten electrode performance. Earlier doping method is solid-solid method to doping with tungsten oxide doped and other rare earth oxides, but the effect is not ideal. After continuous improvement on doping method, at the present manufacturers usually use solid-liquid doping method. Solid-liquid doping mainly doped tungsten oxide with rare earth nitrate solution. This solid-liquid doping method greatly improves doping uniformity and improves tungsten electrode’s performance.

Putting a certain proportion of tungsten oxide and rare earth nitrates into the doping pot, when tungsten oxide was thoroughly wetted by the rare earth nitrate solution, to start doped pot impeller, heated with stirring to achieve uniform doping .

tungsten electrodes and doping boiler

 

Ways to Judge the Polluted IG Tungsten Filament

The IG tungsten filament is known as the ion source which is a discipline with a wide range of applications. The IG tungsten filament is indispensable equipment in many basic research areas, such as atomic physics, plasma chemistry, and nuclear physics research. However, to a certain degree, the IG tungsten filament will be polluted because of the prolonged using of the IG tungsten filament. It requires the users have knowledge about the ways to judge whether the IG tungsten filament is polluted or not. Here are several ways can help people make a judgment.

The first method is to make a preliminary judgment of the Repeller.

Minor pollution:

1. Install the number of Repeller into 0.1, the IG tungsten filament cannot achieve the desired sensitivity.2. Auto-tuning would increase voltage of Repeller, or increases voltage of PMT.3. People can notice the obvious change of the reaction of the peak value of voltage if increase the Repeller. The above three conditions are minor pollution

Serious pollution:

1. IG tungsten filament still cannot get the expected sensitivity under a very high value PMT condition.2. The voltage of Repeller must be increased to a very high value so that the IG tungsten filament can achieve the expected sensitivity.

Another way is to make a judgment of the IG tungsten filament. The main way is to look at the filament current, the most obvious signs of the polluted IG tungsten filament is the filament current becomes large, the greater the current, the more serious pollution it exists. Therefore, when using the IG tungsten filament, users should ensure the safety of the vacuum system, the filament must not be opened in a case of leakage, or it would burn out the filament quickly.

 

The Life Time of EB Tungsten Filament

The cathode of EB tungsten filament plays a fundamental role in the life length of EB tungsten filament, and the cathode’s material and temperature are the key factors. Therefore, when selecting the cathode material, a low work function material is the best choice.

There are two main factors to affect the life length of EB tungsten filament.

One is subjective reasons, heating emission requires a high temperature of the filament and the filament evaporation rate is proportional to the temperature index, the higher the temperature, the faster the evaporation rate of the filament. Therefore, under the condition of usage, user should try to ensure that the low temperature of EB tungsten filament, which is important for life length of the filament.

Another is objective reasons: the surface of EB tungsten filament is easy to form a tungsten oxide layer due to the leakage of vacuum, and the evaporation rate of the tungsten oxide is N times higher than that of the elemental tungsten. If there exists oxygen inside the bulb and under high temperature conditions, the reaction between EB tungsten filament and oxygen will blow the filament. As a result of it, the life length of EB tungsten filament will be significantly shortened. In addition, the moisture content of air has a certain influence on life length of the EB tungsten filament. Humidity will greatly reduce the life length of EB tungsten filament.

The life length of EB tungsten filament is limited. And the life length would change because of habits of the user. The EB tungsten filament requires a high vacuum environment and minimizes pollution, so the user should cultivate the habit of maintaining a vacuum system to prevent vacuum from leaking.

In short, although the quality of EB tungsten filament will influence its life length, users’ maintenance is more important, therefore, users should strengthen the management of the EB tungsten filament.

 

 

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