Nuclear Technology And Tungsten Alloy Shielding

Tungsten Alloy ShieldingNuclear technology refers to the modern new and high technology and one of the signs of social modernization which is based on the nuclear reaction, nuclear properties, nuclear effect and nuclear spectroscopy, and with radiation source, nuclear radiation detector, accelerator and reactor as its tools. Nuclear technology is an important method for early diagnosis of certain cancers, coronary heart disease and brain dysfunction. Its sensitivity, selectivity, specificity, interference, penetrating are so high that it is widely used in various fields of national economy as well as medical care, food preservation, agriculture, industry and hydrology aspects. Nuclear technology can be divided into military nuclear technology, nuclear power and civilian nuclear technology, of which civil nuclear technology is the most active, including radiopharmaceuticals, radiation processing technology, nuclear diagnostic technology, nuclear instrumentation, nuclear analytical techniques.

Nuclear technology not only has brought a variety of convenient, but also brought the nuclear radiation. For the question about the long-term effects of nuclear radiation on people, the study of Atomic Energy Commission geneticist James • Nair and his colleagues shows that the probability to have cancer for the people surviving from nuclear radiation is higher than ordinary people. In fact, many survivors suffered from thyroid cancer, lung cancer, breast cancer, leukemia and other cancers, and some people suffered from mental abnormalities after Hiroshima and Nagasaki nuclear explosions suffered. Many examples show that pregnant women subjected to nuclear radiation can lead to fetal malformation, fetal death and other diseases.

Tungsten alloy shielding can effectively shield the nuclear radiation generated in the use of nuclear technology to avoid it causing harm to humans. Since tungsten alloy combines high density, good machinability, good corrosion resistance, high radiation absorption capacity and high intensity, it is the best raw materials for radiation shielding. In the situation of reducing the volume and thickness of shielding, the radiation shielding performance of tungsten alloy shielding is still equivalent to that of lead. In addition, compared to lead and depleted uranium, tungsten alloy is more environmentally friendly.

 

Tungsten Heater for Evaporation Coating

Vacuum evaporation coating has developed rapidly in recent years, glass, plastic, ceramic, metal, and other based material can be coated. Aluminum, copper, silver and their alloys can also be used as the coating material. Most vacuum aluminizing technology use tungsten wire as a heating source (tungsten heater). First of all, the plated workpiece should be clean, load it on a shelf in a sealed room. Accordance to the classification of application, coating machines have been designed into a stationary, rotating and both revolution and rotation and other types. The wolfram heater can be inserted in the position that is close to the plated object, when the degree of vacuum is higher than 5 × 10-4 Torr, the tungsten wire is energized and heated, the molten aluminum will be evaporated into an aluminum atom, and it will condense on the surface of the plated object, forming bright and non-transparent film with 3-5 microinch.

According to statistics, the amount of interpreters which need tungsten heater for vacuum coating is constantly increasing in China. And in order to save the use of silver, China continues to promote the new technology of vacuum aluminizing mirror. And vacuum evaporation coating machine in has been widely used in China. What’s more, the amount of using of tungsten heater is also increasing year by year. United States, Japan, Sweden, Germany and other countries still use wolfram heater, so exports are also on the rise.

Secondly, use value of high quality wolfram heater is twice as much as the poor quality wolfram heater, so improving the quality of wolfram heater has an important influence. In order to reduce the consumption of tungsten, it needs to improve the quality and its reasonable application. If the use of wolfram heater can be stabilized at around 18 times in a week, then the product will be able to meet customer needs.

evaporation coating and tungsten heater

Non-Filled Tungsten Bronze Type Materials

Because of the important application in the field of microwave communications, sensors, transducers, ferroelectric memory information technology, etc.(Ferroelectricity is a property of certain materials that have a spontaneous electric polarization that can be reversed by the application of an external electric field. The term is used in analogy to ferromagnetism, in which a material exhibits a permanent magnetic moment. Ferromagnetism was already known when ferroelectricity was discovered in 1920 in Rochelle salt by Valasek. Thus, the prefix ferro, meaning iron, was used to describe the property despite the fact that most ferroelectric materials do not contain iron.) The non-filled tungsten bronze type material have caught a lot of attention in scientific research workers. Current scientific research mainly focused on the electrical properties of non-filled tungsten bronze materials instead of other functional properties. However, with the development of modern technology, the multi-function demand of device is increasingly high, which requires the development of new material combines two or more functions in order to develop new devices simultaneously achieve multiple functions.
 
Therefore, in materials development and design, it’s necessary to do further research and develop new properties of the materials on the base of maintaining or enhancing the original functions and properties, so that the material will have the wider application. the rare earth ions are generally intrinsic ions of non-filled tungsten bronze materials, by selecting the appropriate rare earth ions activated, the luminescence functional properties of non-filled tungsten bronze materials can be developed, therefore such material is a kind of potential rare earth luminescent materials. However, the potential luminescent properties of non-filled tungsten bronze material have not been concerned. If the materials have both luminescence properties and ability to improve the existing dielectric, ferroelectric properties can be prepared, these materials will have more widely applications in the electronics industry in the future.
 
Na0.67WO3

Tungsten Alloy Medical Radiation Protection Door

Tungsten Alloy Medical Radiation Protection DoorWith the development of medical technology, medical radiation technology is more and more widely used in medical field. It is not only can be used to help doctors diagnose and treat various diseases, but also can be used to sterilize medical instruments. For example, in the medical diagnosis, X-ray can be used to determine the abnormal changes occur in the body organs and tissues. Doctors can study the patients' situation by injecting radioactive isotope into the body and producing the dynamic or stereo images with the help of imaging techniques and computer technology; in disease treatment, gamma rays or X rays emitted by the radioisotope can kill cancer cells, thereby effectively inhibit tumor growth; in the field of radiation sterilization, gamma rays can also be used to sterilize disposable medical supplies, medical equipment and the like. Radiation sterilization is more effective and cheaper than steam sterilization.

Since the radiation is widely used in medical treatment, the radiology department and a variety of medical equipments also appeared in major hospitals. Tungsten alloy medical radiation protection door is used for shielding and absorbing medical ray radiation, to protect the health of patients, their family members and medical workers. Medical radiation (such as X-rays, gamma rays, etc.) can inhibit, destroy and even kill human cells, resulting in the emergence of various changes in human physiology, pathology and biochemical aspects. It can enter the human body to destroy the molecular structure of living cells and disturb the chemical processes in the human body. Medical-ray radiation can also cause radiation sickness.

Tungsten alloy medical radiation protection door is made of tungsten heavy alloy with high density. Since the radiation shielding properties of a metal material increases with its density, so that the tungsten alloy medical radiation protection door has excellent radiation shielding ability, which can effectively shield medical ray radiation. In addition, compared with other radiation protection door materials (such as lead), tungsten alloy radiation protection door is nontoxic, neither endanger human health, nor pollute the environment.

 

Tungsten Alloy Shielding And Protection Of Medical X-Ray

Tungsten Alloy ShieldingX-ray, also known as " Röntgen ray", is a kind of highly penetrating ray discovered by german physicist Wilhelm Röntgen by chance on November 8, 1895. Roentgen used X-ray to shoot a finger bone photo of his wife, which is the first X-ray picture of human skeleton series in human history that shows the outlines of the maniphalanx and the wedding ring on the third finger of his wife. X-ray is immediately put into use in the medical field as soon as being discovered. Since different body tissues and organs have different absorbing abilities of X rays, and the intensity of X rays after penetrating different parts of the body are also different, so it is widely used in radio examination and X ray photography which can clearly observe the degree of fracture, tuberculosis lesions, the size and location of tumor in the body as well as the location of foreign body in vivo. X-rays are also used for digital subtraction angiography, tomography, medical diagnosis, the medical treatment and so on.

With the development of modern medicine, X-ray has gradually become an indispensable part of the medical treatment, diagnosis, drug analysis aspects, but its harm to our health also attracted attention. X-ray can reduce white blood cell in the blood, leading to the human immune function decline. When the human body is irradiated with the X ray, X ray can interact with human cells and tissues to cause ionization material, thereby undermining the proteins, DNA and other macromolecules structure, causing the damage to the cellular structure. X-ray can also cause hair loss, skin burns, eye disorders, leukemia, skin cancer, cataracts and other radioactive diseases. Pregnant women irradiated by X-ray during pregnancy can lead to fetal death, teratogenic, severe mental decline.

Tungsten alloy shielding can be used to shield X-ray to protect humans from radiation damage. Compared with conventional shielding materials (such as lead), tungsten alloy shielding has higher density. Therefore, under the same weight, tungsten alloy shielding is much thinner, and its volume is only the 1/3 of lead shielding, while its radiation absorption capacity is unabated. This is why tungsten alloy is the best raw materials of radiation shielding.

 

Tungsten Gold Commemorative Coin for Classmate Party

Tungsten gold commemorative coin, also called as tungsten alloy gold commemorative coin, is mainly made of tungsten alloy material inner with gold plating on its surface. It has special properties such as high density almost as the real gold, high hardness, good machinability, corrosion resistance and wears resistance, which makes it as the suitable present for classmate party. As we know, every time when we need to say goodbye to each other, the mood will be much complex, and always we prefer some present or gift to express our deep friendship to each other for a memory, such as a photo, a notebook, a bookmark, tungsten gold commemorative coin could be one of the best choice for that case. Time could not be reserved, and only could be done is to cherish and commemorate all the past lifetime. For its hard and durability, it could be preserved till the next time you see each other again, which plays a role as symbol to your perpetual friendship.
 
Tungsten gold commemorative coins, as its name suggests, is existed for commemorating, for carrying the memories and for collecting happiness. It has a unique high-density property of tungsten alloy, which makes it has the same hand feeling as gold commemorative coins. Tungsten gold commemorative coin is not as expensive as gold commemorative coin, but both are equally beautiful. Since tungsten alloy has good machinability, so it can be engraved with beautiful and exquisite patterns and texts on its surface. Its good wear resistance and corrosion resistance can also make it be permanently stored; and its beautiful appearance and unique collection value make it more memorable. In addition, tungsten gold commemorative coins for classmate party can largely avoid economic losses due to the problems of gold commemorative coins’ lost, damage etc. besides, it is light and easy to carry, which also has high cost-effective, so it is an excellent choice as a souvenir for classmate party.
 
tungsten gold commemorative coin for classmate party

 

Tungsten Copper Contact Defects and Solution

Copper infiltration is one of the most common forms of consolidation molding process, which is also an ideal molding process of tungsten-copper alloy melting point and a high melting point metal alloy two-phase psudoalloy composite materials. Compared with conventional mixing sintering, it can effectively eliminate the pores and defects and not need the subsequent processing (forging, re-sintering) can achieve good densification. So it has a broad prospect in electrical contacts fabricating. Tungsten copper contacts have been widely used in high or extra high voltage electrical equipment, circuit breakers, switches. Its fabricating process includes powder mixing, pressing, sintering, infiltrating and solidification, and any defects of each process will directly affect the properties of tungsten copper contacts finally.

Copper enrichment: it is also known as copper pool or copper depression. The reason for this phenomenon is due to induced copper powder large in size has been added in the mixing process. And it is pressed to the strip, the strip leaving melted pores are filled with liquid copper infiltration; the other one is when the mixed powder into a large ball, ball or adding too much copper induction before mixing was pressed into a sheet, and pressing time and pressing a direction parallel.

Tungsten enrichment: W skeleton has certain strength and the interconnected pores or channel system consist of solid grains or grain net. If the sintering temperature is too high or the sintering time is too long, W particle sintering neck increasing the contact area between the particles is also increasing, the formation of isolated pores, making the latter the infiltration process can not effectively penetrate the copper solution, and the obturator is formed. Such contact in the arc process appears the dregs of the phenomenon, affecting the life of the contacts. Adding activated agent and adjusting the proper sintering temperature is the most effective solution.

In addition, viewed from the cross section parallel to the pressing direction, macroscopically visible tungsten-copper material sandwiched between bright copper, microscopically observed throughout the copper belt. The appearance of micro-cracks is due to the higher speed in pressurization, and the gas in the powder is too late to escape, which has elastic after-effect after pressure relief. Secondly because the powder contained in the organic solvent is not completely evaporated, after pressing the gas slowly volatilize lead to micro cracks. The appropriate solution is to slow down the speed of pressure and ensure a longer dwell time.

tungsten copper contacts

 

Tungsten Heater for Vacuum Coating

tungsten heaterA vacuum is a kind of gas state whose pressure is less than atmospheric pressure. Natural vacuum is a kind of vacuum that the air pressure decreases with the increasing of altitude and present in the astrospace. Man-made vacuum is to use of a vacuum pump to draw out the gas from vacuum vessel so that the pressure of container can be lower than atmospheric pressure. Generally, vacuum coating is operating by physical vapor deposition and chemical vapor deposition methods. Normally, it can be divided into vapor deposition, sputtering and ion plating. Vacuum coating often adopts tungsten heater to evaporate aluminum. The life time of the heater is also restricted by many factors, such as the degree of vacuum, current, voltage, temperature, and the amount of aluminum and evaporation time.

It is proved that the amount of insertion of the aluminum mandrel has a decisive role on its life time. On the premise of ensuring the plating thickness and unchanging other conditions, the amount of insertion of the aluminum mandrel should be minimized, the greater the amount of aluminum is inserted, the heater's life will be shorter. Because that there are some residuary aluminum on the tungsten heater after the completion of vapor deposition, and aluminum will react with tungsten, leading to corrosion of tungsten. As a result, with a long-term cumulative, it will greatly shorten the life of the tungsten heater.

In aluminum case of residual aluminum, the life time of tungsten heater is one-third less than those heaters which have no residual aluminum. Therefore, according to statistical data, the amount of the insertion of aluminum should be controlled within 5%~8% of the weight of the heater. Under the premise of ensuring the quality of coating, the fewer amounts of aluminum, the higher the rate of evaporation, and the degree of corrosion of the heater is also lower, therefore, life time of tungsten heater will be longer.

Tungsten Alloy Shielding For Ionization Chamber

Tungsten Alloy Shielding For Ionization ChamberIonization chamber, also known as ion chamber, is the simplest of all gas-filled radiation detectors, and is widely used to detect and measure some kinds of ionizing radiation (including X-rays, gamma rays and beta particles). It consists of different electrodes which have different potential and the dielectric between them. When the ionization chamber is under the irradiation, the rays will interact with gas molecules, and produce ion pair in the dielectric. Then these ion pairs free spread to the surrounding area to form the ionization current under the action of electric field. Since the electric current is proportional to the intensity of ionizing radiation, the intensity of ionizing radiation can be obtained by measuring the electric current. The classification of ionization chamber is extremely complex, it can be divided into treatment α ionization chamber, β ionization chamber or α and β ionization chamber, γ ionization chamber, neutron ionization chamber, electron beam ionization chamber, Bragg peak ionization chamber according to the measuring object; and can be divided into shell ionization chamber, parallel-plate ionization chamber, ionization chamber ventilation according to the shape of the ionization chamber .

Radiation including α-rays, β-rays, neutrons, X-rays and γ-rays can cause the ionization of matter. α-ray, also known as " alpha ray ", refers to the α particle flow released from the radioactive material. Although its penetrate power is weaker than β-ray, its ionization effect is stronger that can greatly damage the human body tissues; the ionization effect of β ray is much weaker than the α-ray, but it can also damage human tissues due to its strong penetrate power; X-rays and γ-rays both have strong penetrate power and can cause harm to humans. When the body is irradiated with the radiation, radiation can restrain, damage or even kill human cells, different degrees of change in human physiology, pathology and biochemical aspects. Ionizing radiation can also cause skin damage, hematopoietic disorders, fertility damage, leukopenia, cancer, fetal death, fetal malformations and other diseases.

Tungsten alloy shielding can be used to shield radiation when using the ionization chamber to detect ionizing radiation. According to the research, the ray absorbing ability of shielding material is closely related to its density, the higher density means better shielding capability. Compared with other traditional materials (such as lead), tungsten alloy has higher density, therefore has better ray absorption capacity and shielding ability. And tungsten alloy shielding will not release toxic substances, will not endanger human health or pollute the environment. 

 

Cesium Tungsten Bronze Ultrafine Powder Preparation

Tungsten trioxide has many applications in everyday life. It is often used in industrial X-ray screen phosphors and fireproof fabric manufacturing tungstate. Because of its rich yellow elements, tungsten oxide is also used as the pigment in ceramics and paints. Tungsten trioxide has been applied in the production of electricity electrochromic windows, smart windows. These windows are glass with the electric switch, and its transmittance and the applied voltage can be changed. A part of the tungsten oxide is used in the production of chemical products, such as paints and coatings, catalysts of the petroleum industry. However, tungsten oxide is an intermediate product. A large amount of tungsten oxide is used in the metal tungsten powder and tungsten carbide powder, and then used in the production of tungsten metal products production, and widely used in the production of tungsten alloy products, such as tungsten copper, tungsten nickel, tungsten nickel-iron, tungsten silver, tungsten rhenium, tungsten thorium, etc., and the tungsten carbide products with the basic material of tungsten has the most widely application in the contemporary industry field. Tungsten trioxide has excellent performance in electrochromic, catalysis, gas sensing and other aspects, its composite oxides, tungsten bronze, generally refers to the metal oxide with deep metallic luster color, and usually metal conductors or metal-semiconductors, the formula of tungsten bronze is AxWO3, but with different types of cations and the number of moles ( different A, x value), the structure and color shades of the compounds will vary. Currently potassium cesium tungsten bronze and tungsten bronzes cesium are relatively common, cesium tungsten bronze is widely used in the preparation of the conductive thin film and insulating agent in glass transparent insulation paint because of its low resistance and excellent transmittance of visible and near-infrared shielding properties.
 
A preparation method of cesium tungsten bronze ultra-fine powder, the steps are as following. (1) Cesium salt and tungsten salt are weighed as the Cs / W molar ratio of 1: (1.5 to 2.8), and introduce chelating agent and alcohol reagent, react at 170 °C for 3h; (2) The mixed solution obtained was put into the pressure bomb and react at 260 ~ 270 °C for 5 ~ 8h; (3) The reaction materials obtained should be washed and centrifuged. the complete crystals cesium tungsten bronze powder will be obtained after being dried in the vacuum at 80 °C.

CsxWO3

 

 

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