GFAAS Determinate Lead Element in Tungsten Trioxide

Graphite furnace atomic absorption spectrometry (GFAAS) is the current method of atomic absorption analysis performed atomization by using a graphite material tube, cup-shaped atomizer. All participated samples in atomic avoiding dilution atomic concentration of gas in the flame, the analytical sensitivity is significantly improved. The method for the determination of trace metals is a better performance than other methods, and it can be used to analyze solid samples and the direct analysis of a small sample, so it is widely used. GFAAS is used in the field of food, medicine, environmental monitoring, health, and other aspects of clinical medicine.Graphite furnace atomic absorption spectrometry

Lead is weak and strong, poisonous, heavy metal. The original color of it is green white in air .its surface is quickly covered with a layer in dark gray oxide. It can be used for construction, lead-acid rechargeable batteries, warheads, artillery shells, welding materials, fishing equipment,, radiation protection materials, trophies and part of the alloy, such as pewter electronic welding used. Lead is a metal element; it can be used as sulfuric acid, corrosion-resistant, anti-gamma ray, batteries and other materials. Type alloys of lead can be used as bearings, cable sheathing and other purposes, but also sports equipment shot.

Weighing 0.5g of tungsten trioxide in a quartz beaker, adding 10ml of ammonia dissolved in the low temperature furnace, adding 10ml 10% tartaric acid after cooling, and shaking the quartz agent, diluting to the mark with distilled water. Experimental results show that using tartaric acid complex tungsten can eliminate entrainment effect of lead tungstate in the mixed solution. Due to the high chloride and lead form gaseous metal chloride, chlorine moiety with the purge gas discharge caused by the loss of the lead, so the impact on the determination of nitrate increases.

 

Slime Processing in Wolframite Dressing

Slimes’ individual processing is characteristic of China Wuxi Concentrator. Wolframite is brittle and easily over crushed. According to statistics, the number of slimes and metal content are generally 11% -14% of the out-cave ore, slimes recovery is about 3% -8% of total recovery, slimes recovery is obviously improved, which is crucial to improve the comprehensive recovery of tungsten and valuable metals and mining economic benefits.
 
Each wolframite concentrator generally has slimes workshop or section. General flows of slimes processing: after desulfurization, recovered tungsten ores by re-election, flotation, magnetic separation or several sorting processes combined according to the properties of slimes materials, while using the associated metal minerals comprehensively.
 
The main flow of slimes recovery process is "desulfurization - centrifugal concentrator - tungsten flotation - magnetic separation" in Jiangxi Tungsten Mine. After the slag and concentrated, protogenic and secondary slimes go flotation desulfurization, centrifugal concentrator and then a rough one and a fine one, centrifuge tungsten concentrate flotation, flotation concentrate by magnetic separation SQC magnetic machine, magnetic concentrates of tungsten concentrates election, magnetic separation tailings tin ore, crude centrifugal concentrator tailings, flotation tailings tungsten into the shaker respectively sweep the election.
 
With this process, tungsten recovery rate of slimes processing goes to 66.94% , tungsten slimes concentrate grade is 65.16%, with an annual output of 82.2t of tungsten metal content, tungsten slimes tailings grade is controlled at 0.12% or less, thus ensuring comprehensive tungsten beneficiation recovery rate above 86%.

 

Tungsten Gold-plated Coins And Gold Coins Differences

The tungsten gold-plated coins are similar to the gold coins with the same look and color, which are only used for the collection, commemorate, symbols even to reflect the personal taste and values. For gold coins, it can be used as souvenir collections, or be investment-oriented coins, which possesses the liquidity and investment value. But for tungsten gold-plated coins, the meaning of its existence or available using purpose is merely as a souvenir collections. Compared the expensive gold coins, if we just use the coins for the purpose of viewing and memorial, then the tungsten gold-plated coins will significantly have the  higher advantage than gold coins.
 
Nowadays, the goods pursuit of consumers has not only just reflected in the cheap price, but also the pursuit of the cost-performance, it is can be commonly explained that the so-called cost-performance means to buy the high quality goods with low price. Tungsten, which has good wear resistance, corrosion resistance and tensile strength, makes its products of tungsten coins undoubtedly have a very high quality. However the production process of gold plating can add the grandeur feelings on the original cold color of tungsten coins, which makes people has a good sense of beauty. Therefore it also has a higher appreciation and collection value, and more affordable, which makes tungsten gold-plated coins are more welcomed by people than gold coins.
 
In short, expect for the different uses of manufacturing materials, tungsten gold-plated coins and gold coins also have a greatly different prices. While both of them have a high ornamental and collection value, but gold coins have the investment value, which is not possessed by tungsten gold-plated coins, but the tungsten gold-plated coins have a higher cost-performance than gold coins, thus having more rooms for tungsten gold-plated coins to develop.
tungsten gold-plated coins

 

Tungsten Gold-plated Coins For Real Estate gifts

The market condition is changing rapidly, and there is no exception for the real estate market. Selecting the best marketing methods, which are most suitable to their own development, to achieve the maximum influence force is the goal, which been dedicated purchased of each industry. For real estate companies, what kinds of real estate gifts can be chose to attract more people's attention, to expand the companies’ reputation so as to increase people's awareness and enthusiasm of real estate buying is very important.
 
Generally, there are many ways for the real estate companies to advertise their buildings, such as traditional media advertising, the new media has also received a lot attentions since it sprung up, but there is one of the most traditional and most plain way of publicity: gifts marketing way. Using the golden and bright tungsten gold-plated coins to attract the customers is undoubtedly a novel and real propaganda way for the real estate businessmen. You can also specifically customize this class of tungsten gold-plated coins for presenting to the participants, that is to merge the building property of the real estate companies into tungsten gold-plated coins with the ways of carving the name of real estate companies, carving the buildings models, etc., so that to make the opening ceremony more unique. Using the tungsten gold-plated coins as real estate building opening gifts can not only achieve the good dissemination purpose of the project and brand value, but also better gathering popularity for the subsequent sale of the real estate.
real estate tungsten gold-plated coin

 

Tungsten Polymers Main Properties

The main properties of tungsten polymer are mainly as follows:

High density of 11.0 g/cc

Enhancing radiation shielding performance

Improve flexibility properties

Easily malleable

Non-toxic

Resistance to corrosion by weather elements

Resistant to corrosion by chemical and organic solvent resistance

Insoluble in water

No harmful effects when handling or processing

 

With the above main properties, tungsten polymer has found many applications in fields and industries, including:

X-ray devices in manufacturing industries and medical X-ray machines

Nuclear and medical industries for radiation shielding

Used in weight and balance applications as a counterweight for applications like motors, ballasts, and more.

Used as a sound proofing material in aviation headphones

Acts as a damper to reduce shock due to vibration in the automotive industry

tungsten polymer

Tungsten Polymers: The Best Replacement To Lead

Lead is a heavy metal and can be poisoning the day to day operations of human organs are inhibited. Despite these health risks, lead is very useful in industries today because of the properties it possesses, such as its malleability and low melting point making it easy to mold and melt, in addition to its low cost which makes it economical for use for industrial purposes.

Recent studies show that the heavy usage and poor disposal of lead products for decades has caused irreversible effects to the environment and as such lead is now ranked as the second most hazardous substance by the United States government. A kind of material without toxic needed badly, tungsten polymers are being introduced as an effective lead alternative in a variety of applications for which lead has traditionally been used. This push for alternatives is due to the threat that leads poses to the environment and to human health.

Therefore, tungsten polymers have become a notable alternative to lead in numerous applications because they can match the physical properties of lead, like high density, while being environmentally benign. This polymer composite is made up of tungsten powder and a plastic base resin, which are compounded together into a thermoplastic material at 11 g/cc, the same density as lead. The base resin systems are made up of; polysulfones (PSU), co-polymides, polyamides (PA), polymethylpentenes (PMP), polyurethanes (TPU), acryloynitrile butadiene styrene (ABS), polyethylenes (PE) and polyetheretherketones (PEEK).

tungsten polymer

Electrophoretic Deposition Tungsten Trioxide Thin Film

WO3 thin film renders color by irradiation with light or by using an appropriate electric field energy that referred to as a photochromic or electrochromic, which has potential applications in smart windows, large area displays and automotive mirrors, etc. Preparations of WO3 thin films are electrophoretic deposition magnetron sputtering, chemical vapor deposition, and sol - gel method.

Electrophoretic depositionElectrophoretic deposition refers to a stable suspension by the action of the electric field, the colloidal particles deposited material called electrophoretic deposition process. E.g., DC voltage is applied to the electrodeposition coating, and charged paint particles move to the cathode, and the cathode surface with an alkaline effect is produced by the formation of insoluble material deposited on the work surface. There are two processes on accordingly electrophoretic deposition comprises, one is electrophoresis, and the second is deposition. Entire electrophoretic deposition process is divided into the following four steps:
(1) Electrolytic: initially, producing hydrogen and hydroxyl ions OH is the reaction at the cathode electrolysis reaction, the reaction resulting in the formation of an overbased cathode surface boundary is layer, when the effect of the cation and the hydroxide becomes water-insoluble substances, it coating film deposition:
(2) Electrophoresis: the cationic resin and H + in the electric field moves to the cathode, and anions to the anode movement;
(3) Electrodeposition: the surface to be coated, a cationic resin and the surface of the cathode basic acting, and not precipitated sediment deposited on the workpiece.
(4)Electro-osmosis: thin film coating on the surface of the solid and translucency with the majority of the pores leaking water that is discharged from the cathode coating thin film in the electric field, which causing the coating dehydration. Tu film is adsorbed on the surface, completing the electrophoresis process.

Dissolving amount of tungsten powder with hydrogen peroxide (H2O2), to prevent bumping solution, H2O2 should be added and dissolved during stirring constantly. After cooling and filtering completely, adding the appropriate amount of concentrated sulfuric acid (CH3CH2OH) and acetic acid in the filter solution (CH3COOH), which can get WO3 sol. Electrophoretic deposition is conducted under greenhouse, and the current density is DC steady flow instrument, preparing WO3 thin films from taking the substrate as an electrode, the current passing through the cathode that can be deposited WO3 thin film, which can obtaining the deposition required thickness, simple operation, a film-forming, high transparency, film uniformity and the substrate with a solid advantage.

 

Sodium Tungstate, Sodium Molybdate and Other Reagents Synergistic Corrosion Inhibition

There’re many methods of controlling equipment corrosion in industrial cooling water system. Adding corrosion inhibitor is not only convenient, cheap, but also has strong applicability. It is one of the important methods. Common corrosion inhibitors are chromate, nitrite. Most are toxic. Sodium tungstate and sodium molybdate are non-toxic, harmless and inorganic corrosion inhibitors. It could be applied in industrial circulation water.
 
HEDPWhen adding sodium molybdate and sodium tungstate alone in the simulated cooling water, with the increase of the concentration of sodium tungstate and sodium molybdate in simulation cooling water, the corrosion rate of carbon steel gradually reduces and the corrosion rate increases. But to achieve better corrosion inhibition effect, the concentration of sodium molybdate and sodium tungstate is required quite high. In order to reduce the amount of sodium molybdate and sodium tungstate, this paper introduces the synergistic corrosion inhibition of sodium molybdate, sodium tungstate and common organic phosphoric acid (HEDP), orthophosphoric acid and Zn2+.
 
Through the experiment, following conclusions can be drawn:
1. In the simulated cooling water, using sodium molybdate, sodium tungstate alone requires higher concentration to have good corrosion inhibition effect on carbon steel.
2. Sodium molybdate, sodium tungstate and HEDP composite can reduce the corrosion rate of carbon steel greatly and the dosage of sodium molybdate and sodium tungstate has greatly reduced. If increasing the concentration of HEDP, corrosion inhibiton effect is more obvious, and ratio of sodium molybdate and HEDP compound sodium tungstate effect is better.
3. If instead of HEDP as part of orthophosphoric acid, then the corrosion inhibition effect is greatly increased. But if orthophosphoric acid and sodium molybdate compound using phosphoric acid concentration is greater than 4 mg/L.
4. Sodium molybdate or sodium tungstate and HEDP, Zn2+ distribution, the corrosion effect is greatly increased, the synergistic effect is obvious, to join only 0.5 mg/L Zn2+ can make corrosion highly efficient, shows good synergistic effect between the three.
5. Sodium molybdate and HEDP, orthophosphoric acid, Zn2+, cathode and anode process of carbon steel have good inhibitory effect. Sodium tungstate and HEDP, orthophosphoric acid, Zn2+, the anode process of carbon steel had good inhibitory effect. The addition of Zn2+ to cathode and anode effect is very obvious. It is a kind of excellent corrosion additives.

 

Sodium Molybdate and Sodium Tungstate Corrosion Inhibition to Carbon Steel

In previous article,the corrosion inhibition of sodium molybdate and sodium tungstate to stainless steel in acid medium has been introduced. This article will introduce the corrosion inhibition of sodium molybdate and sodium tungstate to carbon steel in weak alkaline medium. Carbon steel is unlike stainless steel. It refers to iron carbon alloy of carbon content less than 2.11%. Carbon steel generally contains small amounts of silicon, manganese, sulfur and phosphorus in addition to carbon. Sodium molybdate and sodium tungstate as green new corrosion inhibitors of low toxicity have important meaning of improving the corrosion inhibition effect of carbon steel and reducing the cost.
 
The experiment using polarization curve method and XPS surface analysis to study the corrosion inhibition of sodium molybdate and sodium tungstate to carbon steel in weak alkaline medium. The following conclusions can be drawn:
1. In 0.05mo1/L sodium bicarbonate solution, sodium molybdate and sodium tungstate can reduce critical passive current density of carbon steel and with the increase of its concentration, ∆ ipp also increases. And the anode second peak appears in the polarization curve. The peak value decreases with the increase of sodium tungstate and sodium molybdate concentration. 
2. After adding 3.30mol/L sodium chloride in 0.05mo1/L sodium bicarbonate solution, carbon anode polarization curve no longer has the properties of activation and passivation. This shows that chloride ion has strong destruction effect on the passivation film.
3. In 0.05mo1/L sodium bicarbonate and 3.30mol/L sodium chloride solution, only when the concentration of sodium molybdenum and sodium tungstate is more than a certain value, carbon anode polarization curve can show the properties of activation and passivation. With the increase of sodium molybdenum and sodium tungstate concentration, passivation range is wider.
4. In 0.05mo1/L sodium bicarbonate solution, sodium molybdate and sodium tungstate has depolarization effect to cathode polarization reaction of carbon steel. After adding the chloride ion, they have certain inhibitory effect on cathode.
5. XPS analysis shows that the carbon steel contains Mo (VI) or W (VI), Fe (III), O2-, C and a small amount of Fe (II) in 0.05/L sodium bicarbonate solution containing sodium molybdate and sodium tungstate. And CO32- also enters the passivation film.

Sodium Molybdate and Sodium Tungstate Corrosion Inhibition to Stainless Steel

Sodium molybdate is white diamond crystal. It can be oxidizing roasted by molybdenum concentrate to generate molybdenum oxide. Sodium molybdate solution is generated by liquid alkali leaching. After the suction filter, concentration, cooling, centrifuging and drying, sodium molybdate can be obtained. There are many kinds of applications of sodium molybdate. It’s mainly used in the manufacture of alkaloids, printing ink, chemical fertilizer, molybdenum red pigment, precipitation agent, catalyst and molybdenum salt. It can also be used in the manufacture of flame retardants and pollution-free type metal inhibitor of cooling water system and it’s also used as zinc plating, polishing agent and chemical reagents.
 
Sodium-Molybdate
The corrosion of metal is an extremely serious damage factor in the modern industry and life, which brings huge economic losses and safety hazards to the human society. Using corrosion inhibitor has important economic meaning and environmental meaning. Sodium tungstate and sodium molybdate are non-toxic, harmless and inorganic corrosion inhibitors, which have good corrosion inhibition for the corrosion of the metal. This paper mainly discusses the corrosion inhibition of sodium tungstate and sodium molybdate to stainless steel in acid medium. Through the contrast research, conclusions can be drawn:
 
1. In 1.0 mol/L sulfuric acid solution, sodium molybdate and sodium tungstate make corrosion potential of stainless steel move to positive direction. This shows that they are anode type corrosion inhibitors.
2. In 1.0 mol/L sulfuric acid solution, different concentrations of sodium molybdate and sodium tungstate can reduce critical passive current density of stainless steel. But its mechanism is not the same. Sodium molybdate is the reduction and adsorption on the surface of the electrode, but sodium tungstate reduces critical passive current density of stainless steel by the heteropoly acid deposition.
3. The stainless steel forms the passivation membrane surface in 1.0 mol/L sulfuric acid solution containing sodium molybdate. It’s mainly composed of Cr (III), Mo (VI), Fe (III), Ni (II), O2- and OH. Mo (IV) has not been found on the surface of membrane. Molybdenum mainly exists as Mo (VI) in the inner membrane. 
4. In 1.0 mol/L sulfuric acid solution, sodium molybdate has inhibitory effect to the cathode process and obvious inhibitory effect in low concentration. Sodium tungstate doesn’t have obvious inhibitory effect on cathodic hydrogen evolution.
 

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