WO3 Used in Hydrodesulfurization Catalyst

tungsten oxide desulfurizerThe WO3 hydrodesulfurization catalyst with nanoscale, high dispersion and activity which can be used in the process of distillate hydrodesulfurization, and carried out in a fixed bed reactor, at a reaction temperature of 200-400℃, pressure of 0.2-20MPa, its production steps are as follows:
1. Dissolve the tungsten oxide in the concentrated hydrochloric acid, and carried out electrolysis to generate the hydrochloric acid solution containing with tungsten trioxide;
2. Inlet the hydrogen sulfide gas to get a vulcanization reaction, wherein the gas flow rate is 60~200ml/min, the vulcanizing agents can be in place of ammonium polysulfide, lee sodium sulfide, ammonium sulfide;
3. Taken out oxidation under the condition of oxygen or air at 60~120℃ for 24~56 hours;
4. carried out decompression and distillation to get the mixture, then diluted with hydrochloric acid, filtered and separated by resin column to obtain a core sulfur-containing transition metal atom clusters which are as the following clusters: [M 2 OnS 2 -n] m +, [m 3 OnS 4 -n] m + or [m 4OnS6;-n] m + a, wherein m = W, n = 0~6, m = 0~6;
5. The products obtained in Step 4 are loaded to kinds of carriers by dipping or ion exchange method under the oxygen content of less than 0.1% of an inert atmosphere (helium, argon or nitrogen), then you will get the sulfur catalyst loading type of transition metal atom clusters, which is the needed--tungsten trioxide hydrogen desulfurization catalyst.
 
The prepared catalyst has the following advantages:
1. Raw materials are simple and easy to get with low cost, mild preparation conditions, simple operation;
2. Compared with the traditional metal catalysts, it has the similar composition; at the same time, it also has the better dispersion and smaller particle size, and thus has a higher hydrodesulfurization activity;
3. With a strong resistance to sulfur poisoning which makes it being a very potential liquid fuel hydrodesulfurization catalyst.

 

Doped Tungsten Bronze Niobate Crystal Structure

The photorefractive performance and growth quality of Tungsten bronze (TB) niobate can be effectively improved by doping because of its special crystal structure. For example, potassium and sodium strontium barium niobate crystals doped with copper (Cu: KNSBN) has breakthrough on obtaining large crystal size and performance improvements. Doping modification in crystalline materials research has caught more and more attention. Therefore, studies on the mechanism of doping, the relationship of doping and crystals molecular design and changes of the compositions are necessary.
 
There are five types of structure position (Al, A2, C, Bl, B2)inside the TB niobate crystal structure, which provides favorable conditions for introducing other ions to doping modification. Common dopant ions are: monovalent cations Cu +, divalent cations Mg2 +, Ca2 + and Cu2 + etc., trivalent cation Cr3 +, Fe3 +, etc., tetravalent cations Zr4 +, Ti4 +, etc., and pentavalent cation Ta5 +, V5 + and hexavalent cation W6 +, etc. .
 
Dopant ions in crystal have the following functions. First, to make crystal growth streak reduced and crystal not easy to crack, so that large size crystalline material is easily to grow. Second, to make the crystal has good polarization performance, and the depolarization phenomenon is not easy to appear. In addition, the dopant ions into the crystal also have the following effects on crystal : (a) Changes of lattice constant. (b) Distortion of crystal symmetry. (c) effects on crystals phase transformation. At the same time, the amount of dopant ions into TB niobate crystal will lead to changes in other cations in the crystal more or less. Dopant ions get into the crystal structure of different positions due to its own characteristics and types of cations in crystal and occupying circumstances. So in the synthesis of crystal material, doping can improve the quality of the crystal growth and the performance of the crystal.

tungsten bronze structure

 

Steel Bonded Carbide Description (2/2)

Steel bonded carbide has many advantages, compared with conventional steel, it has higher hardness, wear resistance, hardenability (the ability to obtain the hardened layer depth of quenching); compared with tungsten carbide, it has excellent machinability (such as turning, milling, planing, etc.,), heat treatable and weldable. It also by forging changes its dimensions and internal organizational structure to improve performance, which is generally not available in tungsten carbide. By electrical welding, insert welding, surfacing, vacuum welding, steel bonded carbide can meet a variety of application needs.

Steel bonded carbide also has a smaller proportion of high specific strength, good self-lubricating, high natural frequency and damping characteristics, a significant damping effect. Wherein the circular SiC grains is working with the workpiece surface forms rolling friction, so as to effectively avoid the adhesion of wear and abrasion wear. Combined with the advantages of steel and tungsten carbide, steel bonded carbide has a wide scope of application, which can be used in military materials, marine, aerospace materials, high temperature and corrosion-resistant parts, wear parts of damping, mold material, crushing mining tools, measuring instruments and some fields has special requirements of materials proportion and overall performance.

The machining principle of steel bonded carbide is low cutting rate, accurate control of cutting depth and length, do not add any coolant (except grinding process). If we violet these principles, the surface of steel bonded carbide will be hardened, which hiders the machining process. Material of the tool in the milling process usually uses the high-speed steel and carbide; drilling process should not add coolant to ensure that no oil and drill using medium voltage feed and promptly chip to prevent debris from wear and tear on the drill bit; grinding with high hardness, good self-sharpening diamond grinding wheel 120 #, but should pay attention to the amount of coolant; after quenching, steel bonded carbide will easily crack in the process of electrical machining. In order to prevent the cracks from appearing or extending, it should be extending the annealing time until the stress relief and using quenching or isothermal quenching process.

Steel Bonded Carbide Description (1/2)

From the narrow sense, the carbide we usually refer to is composed of the hard phase tungsten carbide (WC) and the binder phase cobalt (Co); in a broad sense, cemented carbide refers to the materials that refractory metal compound and a binder metal composed by ingredients, pressing alloy molding, sintering and a series of manufactured. Refractory metal carbides generally refers to the periodic table carbide article IV, V, VI family of W, Ti, Ta, V, Hf and other elements, of which the WC, TiC, TaC of the most widely used.

Cemented carbide has higher hardness, strength, red hardness, excellent chemical stability, perfect wear and ablation resistance and many advantages so that it has a broad application prospect, such as cutting tools, geological mining tools, molding, structural parts, wear parts, high temperature high pressure cavity and so on. Steel bonded carbide is one kind of cemented carbide. In addition, cemented carbide can be divided into common tungsten carbide based (WC - Co, WC- TaC - Co, WC – TiC - Co, WC – TiC – TaC - Co, WC- Ti – TaC – NbC - Co), titanium carbide or titanium carbonitride-based (commonly based on TiC or Ti(C,N) and uses Ni – Mo as the binder), chromium carbide based (commonly based on Cr3C2, uses Ni or Ni – W as the binder) and coated carbide (commonly based on tungsten carbide and deposits hard compound of few microns in thickness by CVD or PVD).

Steel bonded carbide a kind of cemented carbide that based on TiC or WC and uses steel as the binder. It is generally prepared using powder metallurgy method, after machining and heat treatment properties between conventional cemented carbide and steel, which is a new engineering material. Furthermore, according to the final structure of the binder phase, steel bonded carbide can be specifically divided into martensite-based, austenite-based and ferrite-based.

steel bonded carbide

 

Tungsten Alloy All-In-One Laser Printer Shielding

Tungsten Alloy All-In-One Laser Printer ShieldingTungsten alloy all-in-one laser printer shielding can be used for shielding the radiation released during using an all-in-one laser printer. All-in-one laser printer, also known as laser plain paper fax machine, is a fax machine that forms an image by the means of utilizing carbon powder to attach on the paper. All fax machines work by scanning the files to be sent and convert them into a series of black and white point information. These point information would be transformed into audio signals and then be transmitted through a traditional phone line. After the recipient's fax machine receiving the signals, it will print them out, so that the recipient will receive a copy of the original document sent. The difference in different categories of fax machines is the printing method. All-in-one laser printer mainly uses a se drum in the machine body to control the opening and closing of laser beam, thereby producing an image with a charge on the drum, then the carbon powder inside the fax machine will be attracted and attached to the paper to form text or image graphics.

With the development and the maturity of all-in-one laser printer technology, its powerful functionality is widely used in modern office applications. Due to its form of file output of laser printing, it will produce certain laser radiation during the printing process. Today, it is accepted that even low-power lasers with only a few milliwatts of output power can be hazardous to human eyesight when the beam hits the eye directly or after reflection from a shiny surface. At wavelengths which the cornea and the lens can focus well, the coherence and low divergence of laser light means that it can be focused by the eye into an extremely small spot on the retina, resulting in localized burning and permanent damage in seconds or even less time. The same with most electrical appliances, fax machine can also generate electromagnetic radiation which has a certain impact on the human body, by causing cardiovascular disease, diabetes, cancer mutation, miscarriage, infertility, birth defects, immune system and nervous system damage and the like. Therefore, the use of tungsten alloy all-in-one laser printer shielding is necessary.

Because tungsten alloy has a high density, such that its radiation shielding capability can reach very high. Therefore, tungsten alloy all-in-one laser printer shielding has a good radiation shielding performance. Placing a tungsten alloy all-in-one laser printer shielding at the periphery of laser machine can effectively shield the radiation generated during the use of fax machine, thereby reducing the radiation damage of office workers. In addition, compared with traditional materials (such as lead), tungsten alloy is non-toxic and will not pollute the environment, so it is an ideal radiation shielding material.

 

Choosing Right Current for Tungsten Electrode for DCEN Welding and AC welding

People usually use tungsten electrode for aluminum GTAW. As we know, tungsten electrode has many types, and each type is given an AWS classification and includes a painted stripe around one end so you can easily identify the type, including pure tungsten (EWP), 2% thoriated (EWTh-2), zirconiated (EWZr-1), ceriated (EWCe-2), lanthanated (EWLa-1), and rare earth(EW-G)tungsten electrode.

Pure tungsten electrode has a lot of shortages, so manufacturers usually add various additions to the tungsten electrode for improving electrode’s performance. First, doped with rare earth makes the tungsten less likely to sag or droop at high temperatures. Second, it makes electrode easier for the tungsten to emit electrons, which gives it a higher current-carrying capacity compared to pure tungsten.

In the past, people usually use 2 percent thoriated electrodes direct current electrode negative (DCEN) welding, but although more recently lanthanated and ceriated electrodes have become more popular for this type of welding. Because 2% thoriated tungsten electrode has radioaction and it will harm people’s health. On the other hand, When people started to weld aluminum by GTAW using alternating current (AC), they found out 2% thoriated electrodes really weren’t well perform for that type of welding. In AC GTAW much more energy of it is taken up by the tungsten than is taken up in DCEN welding. So in the past the electrode choices for AC using were limited to pure tungsten or zirconiated tungsten, which could carry more current than a pure tungsten electrode of the same size. Neither of these electrodes was used with a sharpened tip. Instead, they were allowed to form a round ball on the end. So during AC, people prefer to choose lanthanated and ceriated electrodes.

On the other hand, thoriated tungsten can produce to a very irregular in geometry, which produced a fluttery, irregular arc. So pure and zirconiated electrodes were preferred.

When inverter GTAW machines came on the scene, the balance control can be set much further toward electrode negative (EN), but it still getting good arc cleaning action. Since only a little electrode positive (EP) is used, the tungsten electrode stays much cooler. In fact, the best electrodes for AC inverter GTAW machines are generally ceriated, lanthanated, and rare-earth electrodes, which are all sharpened to a point and it can retain the point very well during use. Thoriated, zirconiated, and pure tungsten electrodes are not often used with AC inverter machines.

tungsten electrodes

Tungsten Electrode Production and Grinding Process

tungsten electrode

Tungsten electrode is an important part in welding field. So produce high quality tungsten electrode can not only improve electrode’s life, but also can improve welding performance. In the production process, manufacturers should well control production parameters, properly grinding and cutting electrode also will influence electrode’s performance. As we knew, improperly produced electrode will leads to arc wander, splitting, shedding, inconsistencies, or expensive mistakes and other problems happening in the welding process. Properly produced, ground and cutting and processing electrodes can improve arc starting and stability.

To produce tungsten electrode manufacturers usually uses powder metallurgic method. The detailed production processes are as follow: doping-mixing-pressing-pre-sintered-sintered- multistage swaging process -recrystallization annealing-drawing straightening and polishing. In the production process, every parameter will influence electrode’s performance, so we should continue to improve production technology for improving its welding performance.

On the other hand, tungsten electrode grinding and cutting is another factor influence electrode’s welding performance. And during grinding and cutting diamond wheels are recommended for all tungsten electrodes. While tungsten is a very hard material, the surface of a diamond wheel is harder, which makes for a smooth grind. Grinding with other types of wheels can create jagged edges, imperfections, or invisible poor surface finishes that contribute to weld inconsistency and defects.

There is electrons flow at a greater density on the surface of the electrode. So during grinding, there are some tips should follow. Firstly, electrodes can not grind or polish by crosswise, because the electrons on the surface will jump across the grinding marks. During the welding, the arc begins before the tip, spreads out, and usually wanders, and then tungsten electrode becomes overheated and wears out more quickly. Secondly, if electrodes longitudinal grinding with the grain, the electrons are led steadily to the extreme tip of the tungsten electrode. The arc starts straight and remains narrow, concentrated, and stable.

Tungsten Bronze and SBN Crystal

Currently the most intensively investigated tungsten bronze niobate is strontium barium niobate (SrxBa1-xNb2O6, SBN) crystal. SBN crystals have solid solution of tetragonal tungsten bronze structure when 0.25≤x≤0.75, of which the space group is P4bm and the point group is 4mm. SBN single unit cell has 10 NbO6 octahedrons, and only five alkaline earth ions filling the 10 voids, wherein Sr2 + and Ba2 + ions occupy portions A1 and A2, position C is empty, which is called non-filled tungsten bronze structure. SBN single crystal are more generally SBN: 61 (x = 0.61) or SBN: 60, this composition crystal is relatively easy to grow and easy to obtain high-quality and large-size crystals. In addition, the Curie point of SBN crystal decreases with increasing x, which decreases down to SBN: 75 of 60 ℃ from SBN: 25 of 200 ℃.
 
The most commonly method to grow SBN is Czochralski method, larger size SBN crystal material can be grew with this method. Crystal of SBN: 61 melting point is about 1510 ℃, the general use of silica-alumina rod frequency heating or resistance heating crystal growing equipment for growing, growing container Pt crucible. In addition the use of technology such as automatic path to maintain the solid - liquid interface of the flat, which helps to get the large size high-quality crystal.
 
Kubota based on the Czochralski method, with the cooling crucible base method to grow larger size crystals of SBN: 61. 1968 Lee reported that SBN crystal growth with decline crucible method, this method can ensure the equal diameter and eliminate crystal growth streak, the growth of the crystals thermal stress is large, but it can be reduced the portion of the thermal in stress crystal growth by annealing. In addition, the growth method of doped SBN crystal and undoped SBN crystals are consistent, but cracking and growth of striped crystal growth are more likely to show up because of doping, and pay attention to adjust the process parameters (pulling rate is low) during the process. Effective electro-optic coefficient of SBN crystals is large, so it is a good electro-optical crystal, and it has a relatively large pyroelectric coefficient, which has been made into the infrared detection element. However, due to the low curie point of SBN commonly used, which greatly limits its wider application in the higher temperature range. The basic physical parameters of the SBN crystals as follows:

SBN parameters

Waste WO3 Denitration Catalyst Regeneration in China

Currently, cellular SCR denitration catalyst is the core of SCR technology, which has the properties like expensive, short life, containing toxic precious metals, its frequent replacement not only cause the operational costs of coal-fired power plants increasing; but also serious threat the environment, as a large number of abandoned or inactivated denitration catalyst unable to be properly handled. Denitration catalyst regeneration can not only alleviate the secondary pollution which it brings; also can greatly reduce the costs of denitration project construction and operation, and thus has a very important significance of research.

appearance of abandoned denitration catalyst
 
During the operation, the catalyst wear out, poisoned such phenomena are inevitably occurred, thus to result in partial or total inactivation. Today, the widely used of denitration catalyst is taking vanadium pentoxide and tungsten trioxide as the main active substances, wherein the vanadium pentoxide has a highly toxic, tungsten is a rare precious metals, therefore, their recovery is very necessary.
 
The process for generating waste tungsten trioxide SCR denitration catalyst is as following: soot blowing high-pressure air, high-pressure water washing, ultrasonic cleaning, acidification washing, active implantation, drying and calcination. Among them, the higher the degree of soot blowing, the shorter time of cleaning or chemical solution treatment is, the smaller the amount of waste water, and thus to help control the costs of catalyst regeneration; high-pressure water washing helps to improve the denitration efficiency; the specific surface area of catalyst after ultrasonic cleaning close to the new catalyst; activity implantation, a critical step to further improve the activity of the catalyst, which is necessary to catalyst regeneration efficiency; drying process is to restore the mechanical activity of the catalyst, and the calcination is the only way to decompose the active ingredient precursors, as well as the one very critical process in the regeneration of tungsten trioxide SCR denitration catalyst.

 

Tungsten Crucible for Rare Earth Smelting

Tungsten Crucible is one of the important deep-processing tungsten products which is now widely used in smelting of rare earth for its excellent corrosion resistance and good anti-wear properties as well as a high temperature strength. The choice of tungsten crucible has an important influence on rare earth metal smelting. Thus, in the preparation of tungsten crucible for rare earth smelting, users should pay more attention to the followings.

The first is for the selection of tungsten powder. Tungsten powder is the main raw material for tungsten crucible, the grain size of tungsten powder plays a crucial role on the quality of the finished tungsten crucible. Inappropriate choice of the grain size of tungsten powder will make tungsten crucible have crack during the pressing. Therefore, the grain size of tungsten powder cannot too coarse. If too coarse, the space in the pressing process will be great which will reduce the density of pressed compact and easily lead to cracking. If the users choose too small grain size, movement of position and the amount of deformation between the tungsten powders will increase at the time of pressing. Due to the flabby of elastic stress, the finished tungsten crucible would have crack finally. Accordingly, the grain size of tungsten powder of tungsten crucible for rare earth would better between 2.5μm and 3.0μm. In addition, the oxygen content of the tungsten powder should be less than 0.1%.

Next is the control of pressure in processing. While pressing tungsten crucible with a strong pressure, tungsten powder will have a serious distortion. On the other hand, the strong pressure would increase the elastic stress, and finally, resulting in tungsten crucible cracking. If the pressure is too weak, tungsten crucible cannot enough reach, and it easy to have crack. In addition, the speed of pressure pool should be slow, if too fast, release of elastic stress of tungsten powder will accelerate which would lead to cracking of the tungsten crucible.

Finally is the notice of sintering process. When sintering pressure compact in the medium frequency induction furnace, the sintering temperature should be controlled between 2200 ℃ and 2250 ℃. And the holding time of 3-5 hours is the best. What’s more, the rising rate of sintering temperature cannot too fast or it would cause deformation of tungsten crucible, it is better to rise 80 ℃ or 100 ℃ for one hour.

Tungsten crucible formed by the above ways for rare earth smelting would have better properties and the best effect which can also greatly reduce industry costs.

tungsten crucible for rare earth

 

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