Tungsten Alloy Radiation Shielding For X-ray Machine

Tungsten Alloy Radiation Shielding For X-ray MachineAn X-ray machine is a device used to generate X-rays. It is made up of a control console which enables the x-ray technician to choose a variety of x-ray techniques suitable for that specific exam, an X-ray generator that creates and produces the desired KV, MA and X-ray tube. The X-ray tube, like any vacuum tube, contains a cathode, which directs a flow of electrons into a vacuum, and an anode, which collects the electrons and is made of tungsten to disperse the heat generated by the collision. When the electrons collide with the target, about 1% of the resulting energy is emitted as X-rays, with the remaining 99% released as heat. Due to the high energy of the electrons that reach relativistic speeds the target is usually made of tungsten even though other materials can be used particularly in XRF applications. The types of X-ray machine include the portable medical X-ray system, the industrial X-ray detection machine and the belt detection X-ray machine. X-ray machines are widely used in hospitals to help doctors diagnose the disease, in industry for non-destructive testing and in railway stations and airports to carry out security checks.

X-ray is a form of electromagnetic radiation. Most X-rays have a wavelength ranging from 0.01 to 10 nanometers, in line with frequencies in the range of 30 petahertz to 30 exahertz and energies in the range of 100 eV to 100 keV. The wavelength of the X-ray is shorter than that of UV ray and typically longer than that of gamma ray. In many languages, X-radiation is referred to with terms meaning Röntgen radiation, who is usually credited as its discoverer, and who had named it X-radiation to signify an unknown type of radiation. X-ray has penetrating effect, ionizing effect and thermal effect. In medicine it is often used for fluoroscopy, in industry for industrial flaw detection. Since the X-ray has a strong penetrating effect, when a living organism is irradiated with X-ray, its living cells can be inhibited, destroyed and even killed, resulting in varying degrees of changes in physiology, pathology and biochemical aspects. In the use of X-ray technology, it also found that X-ray can lead to the patient hair loss, skin burns and can cause vision disorder, leukemia and other ray injury problems on the related personnel.

Tungsten alloy radiation shielding can be used to shield X-ray generated by the X-ray machine. Compared with conventional shielding materials (such as lead), tungsten alloy shielding reflects good value. Since the tungsten alloy has a high density, under the condition of the same thickness, the radiation shielding ability of tungsten alloy is twice than that of lead shielding, and the weight of tungsten alloy shielding is 25 to 50% less than lead. In addition, lead is toxic and tungsten alloy shielding is non-toxic so that it will not harm the human body or pollute the environment.

 

Tungsten Bronze Structure Materials Application in TBC

Thermal barrier coating (TBC) system has been widely applied in the first and second rows of turbine blades and combustion chamber components exposed to the hot gas path of the gas turbine. Typically, the yttria-stabilized zirconia thermal barrier coating is widely applied to the high temperature section, to provide a thermal mechanical shock, high temperature oxidation and hot corrosion damage protection.
 
The initially main purpose of providing TBC is to extend the life of the coating components, but advanced gas turbines makes more and more use of the TBC to improve the efficiency and power output of the gas turbine. A means of improving the efficiency and power output is to reduce the consumption of hot gas path component cooling air, even if those components are capable of operating at higher temperatures. Requirements for higher combustion temperature and reducing cooling flow produced a constant demand for advanced TBC to have higher temperature stability and better insulation in order to achieve long-term efficiency and performance targets of advanced gas turbine.
 
By using the tungsten bronze structure ceramic coating material with a lower overall thermal conductivity to improve insulation of TBC. Usually these structures have excellent thermal, physical and mechanical properties. Combination of big complex cell and strong anisotropy atomic bonds and with high atomic weight, making them an ideal target with lower thermal conductivity. In addition to the thermal - mechanical properties, the new TBC also showed excellent relative stability in the operating temperature range and increasing anti-sintering properties in extreme environments in the turbine section. In addition, they are compatible with traditional or new adhesive layer and super alloys.

TBC

Tungsten Copper Wire Process

The basic process of tungsten copper wires is : Mixing → molding or isostatic pressing → infiltration, sintering tungsten copper rod or tungsten copper block → machining. Except conventional infiltration process, there are some popular processes used more, such as high-temperature liquid phase sintering and activated liquid-phase sintering. The principle of infiltration is that porous tungsten skeleton wetted by copper liquid, under the capillary force the copper liquid flows along the W particle gap, filling the pores of porous tungsten skeleton. So tungsten copper materials have higher density, excellent sintering properties and electrical conductivity; High temperature liquid phase sintering since the sintering temperature is high, a long time, will make a lot of volatile copper phase, so that the sintered tungsten copper material density decrease, the performance will be subject to different degrees of impact, it is difficult to obtain a high density, high conductivity tungsten copper alloy material; activated liquid phase sintering improves the relative density, the hardness and tensile strength of tungsten copper by adding small amounts of trace elements (Ni, Fe, Pd, etc.). But on the contrary, the activated elements will dramatically decrease the electrical and thermal conductivity, which is not suitable for the occasions with high requirements of the conductivity.

The technologies to machine tungsten copper rod or block in wires include drawing processing, rolling processing, roller die drawing techniques and rotary forging technology. Drawing processing take advantage of metal plasticity, when working in the external force so that it is forced through the die, the metal cross-sectional area is compressed to obtain the desired cross-sectional shape and size of the processing method. Preparation of tungsten and copper wire by repeatedly hammering and drawing forming, drawing conducted at room temperature, metal products will produce obvious hardening.

But for tungsten copper with lower Cu content, it has poor plasticity, the drawing rate received extremely limited, which is difficult to draw molding; rolling process is to rely on the friction two rotating rollers and the rolling member rolling pulled into the roll gap, it is compressed to produce plastic deformation process. In addition, the rolling process can also refine the grain, improve the organization, can significantly improve the mechanical properties of the metal alloy, suitable for mass production; Roller die drawing process the billet is drawn in a non-grooved drive, freely rotating rollers consisting of, the sliding friction with the material of the die orifice was changed to rolling friction bearing, the stretching process is more effort not only suitable for drawing round wire, shaped wire may be stretched, but not suitable for low plastic material.

Tungsten Copper Wire Description

Tungsten copper alloy is a kind of psudoalloy, which consists of the hard phase W and the binder phase Cu two immiscible metals, so it only can be fabricated by PM (Powder Metallurgy). Tungsten copper material has both advantages of tungsten and copper, the high density, high melting point, excellent wear resistance and corrosion resistance of W; the excellent electrical and thermal conductivity, good plasticity of Cu; and at a temperature above the melting point of copper alloy of copper liquefied evaporated to absorb a lot of heat, reducing the surface temperature. So tungsten copper material is also known as heat sink materials.

According to the shapes and applications, tungsten copper products can be specifically divided into tungsten copper rod, tungsten copper block, tungsten copper plate, tungsten copper contact, tungsten copper tube, tungsten copper electrode, tungsten copper heat sink, tungsten copper wire and so on. In the early 1960s, tungsten copper wire and tungsten copper electrode has been used in EDM (Electrical Discharge Machining) and resistance welding because of its high density, high strength, excellent electrical and thermal conductivity and arc ablation resistance. So far, with the developments of relevant technologies and further study of researchers, tungsten copper begin to use in plasma electrode material processing, precision machining, spraying, LED and other electrode fields. But since the special PM structure of tungsten copper, it has been greatly limited used in wire. In order to improve the uniformity, mechanical properties and production cost, it needs to looking for new technologies and processes.

Used in EDM electrodes of tungsten copper wires are supposed to meet the following requirements:
1. On the basis of excellent electrical and thermal conductivity, it also has good resistance to spark erosion;
2. Good structure uniformity and density, in order to ensure the stability of the electrical processing and improve the utilization of electrode material;
3. It has lower machining consumption and dose not affects the quality and the overall efficiency;
4. Easy for molding, machining molds and products according to design requirements to provide a correspondingly shaped profile tungsten copper electrode bars or complex shapes.

tungsten copper wire

 

Tungsten Trioxide Contained Vehicle Denitration Catalyst without Vanadium

The main pollutants in vehicle emissions are hydrocarbons, nitrogen oxides, carbon monoxide and particulate and so on. SCR is the known way with best denitration effect, while the core technology of it is SCR denitration catalyst. Earlier, the denitration catalyst is mainly based on automobile platinum, gold and other precious metal, and later began to use non-precious metal oxide as the main active ingredient. Selective catalytic reduction using ammonia or compound which can decompose into ammonia is the public known way for removing nitrogen oxides from the exhaust gases of lean burn internal combustion engine, which contains active ingredients like titanium dioxide, tungsten trioxide, vanadium pentoxide.
automobile exhaust gas denitration apparatus
However, when SCR catalyst containing vanadium used for cleaning motor vehicle exhaust, it may lead to toxic vanadium compound going into the air because of the volatility of vanadium under high temperature, thus to cause environmental pollution and personal injury. So, the listed capacity of the car catalyst containing vanadium is low. Therefore, for a long time, researchers and vendors are ongoing committed to provide no vanadium SCR denitration catalyst.
 
Rare earth with the reputation of industrial "vitamins" and "gold" has become an extremely important strategic resource consistent with the metal tungsten. Research indicated that the incorporation of rare earth oxide catalyst can effectively replace the vanadium based catalyst, which exhibits excellent performance. Studies have indicated that some catalyst doping into cerium-zirconium mixed oxide, and also the sulfur, molybdenum, tungsten (in form of tungsten trioxide) compound; in which the ingredients are: 0.02~3% of cerium-zirconium mixed oxide, 5~15%, 0.5~3% of tungsten trioxide (or molybdenum trioxide). This kind of SCR catalyst uses a ceramic flow-through monolith honeycomb wall flow type filter or a ceramic matrix, is particularly suitable for lean burn internal combustion engine exhaust gases to remove nitrogen oxides with the properties of highly activity and anti-aging.

 

Titanium Based Tungsten Trioxide Denitration Catalyst

different types of SCR catalystsTitanium is a silvery-white transition metal, which is considered as a rare metal, with the properties of light-weight, high-strength, metallic luster, moisture chlorine corrosion; its most common compound is titanium dioxide, which is often used as the carrier of denitration catalyst. The typical plate denitration catalyst is based on stainless steel and coated with a catalyst paste (ingredients: titanium dioxide, vanadium pentoxide, tungsten trioxide and molybdenum trioxide, etc.).
 
Because of tungsten, molybdenum, vanadium and other metals and their compounds are usually expensive, for seeking a higher cost-effective, the researchers decided to start with the substrate of plate tungsten trioxide denitration catalyst to improve its property. Experiment has shown that metal titanium or its alloy can meet their demands. Compared to stainless steel, the titanium has a higher strength / weight ratio because of its light-weight, high-strength; when used as the catalyst substrate, it can cut off 1/2 of the weight with the remaining high strength, and loading the same amount of active substance while significantly reducing the weight of the SCR denitration system. Furthermore, since titanium also purchases according to the unit weight, which is to say the cost of the titanium substrate is approximately equal to that of the stainless steel substrate.
 
In addition, titanium based of tungsten trioxide plate denitration catalyst due to the choice of titanium plate with through-hole which makes the whole SCR system able of rapid heating and cooling, and quickly response to the changing conditions. Insiders know the most efficient temperature range of NOx removal reaction is very high and narrow; however, the titanium substrate can exactly effectively overcome this disadvantage. Also, if the catalyst is cracking or chipping, the exposed titanium will be oxidized to titanium dioxide by the oxygen in the high temperature of exhaust gas, which also contributes to the catalytic denitrification.

 

Testing Standards of Carbon Sulfur Analyzer and Tungsten Granule——Test Conditions and Test Methods

Except the technical requirements, testing standards of carbon sulfur analyzer and tungsten granule also include - test conditions, test methods, management of the results of treatment, re-testing period. The relative standard deviation of carbon is lower than 1.0%, sulfur should be lower than 4.0%, the analysis time should less than one minute, the weighing stability of less than 0.002 grams. Environment conditions for testing should meet the standards. The ambient temperature should be controlled between 15 ℃ to 30 ℃, relative humidity must be less than 80%. If it is measured against the amount of 0.0010% to 0.0100% of the carbon and sulfur, the relative humidity should be less than 60%. Power supply is (220 ± 4.4) V, (50 ± 1) Hz, and it should be ensured that the detection environment has no strong vibration, no strong electric, no active gases and without any impede of magnetic fields.

The main test equipments and materials for detection should be in accordance with national standards. Using the approved the steel components by the state metrological administrative department to analyze national primary, secondary reference material. Uncertainty of the determination of carbon and sulfur less than one-third of error of indication, weighing with 1g standard weights. According to visual indication and touch to detect the appearance of instrument. The instrument is required to be preheated on the basis of instructions before detecting. Select carbon content within the range from 0.100%  1.000%, and choose sulfur content within the range from the 0.010% to 0.100%, weighing 0.5 g of sample every time, repeated detecting for 7 times, calculating the standard deviation and relative standard deviation in according with the standard formula calculation method . Weighing with 1 g standard weight, continuously weighing for six times, the difference between the maximum and the minimum is called weighing stability. After the test is completed, certificate of qualification can be sent, if unqualified, pointing out that the failed project. Test cycle usually two years. While moving, repairing or doubting on the measurement results, users can test the instrument.

If the carbon sulfur analyzer used by the company are not included in the mandatory verification of measuring instruments catalog, on the other hand, these instrument are not applied in trade settlement, safety, health, environmental monitoring, there is no need to test it compulsively.

carbon sulfur analyzer and tungsten granule

 

Cubic Hydrogen Tungsten Bronze Crystal Structure

The structure of D0.53WO3 has been determined by a room temperature powder neutron diffraction study. The unit cell is body centered cubic (Im3) and contains 8 formula weights (a = 7.562 ± 0.002 Å). The average cell content was refined by a least squares method based on peak intensities. The tungsten atoms lie on the special sites of the perovskite structure and are surrounded by nearly regular octahedrons of oxygen atoms with the latter displaced from the normal perovskite positions along 〈110〉. The deuterium atoms constitute statistically distributed -OD bonds which are directed towards the nearest oxygen atom of a neighboring octahedron. The analogous hydrogen compound(cubic hydrogen tungsten bronze) is best described as a nonstoichiometric oxide hydroxide WO3−x(OH)x based on a distorted ReO3 structure. The crystal structure is closely related to that of In(OH)3 and Sc(OH)3.
 
In order to understand the slow stages of the catalytic reduction of WO3 to hydrogen tungsten bronzes HxWO3, the mobility of hydrogen in the latter has been studied by NMR spectroscopy between −50 and −195 °C. Values of the spin-lattice relaxation time T1 plotted vs. the inverse temperature show a minimum indicating one main relaxation process, namely that due to diffusion. The corresponding calculated diffusion coefficient of H in HxWO3 is very high. Thus transport of H in HxWO3 cannot be the rate determining step in the catalytic reduction of WO3 Rather, that step is suggested to be the penetration of the reducing species below the surface of WO3 into the lattice.

tungsten bronze structure

 

Glass Furnace Flue Gas SCR Denitrification Catalyst Uses Tungsten Trioxide

glass furnace denitration systemThere are many sources of nitrogen oxides, in which glass furnace flue gas is the main one. The mass of nitrogen oxides in the glass furnace flue gas emissions is up to 14 million tons per year. Furthermore, with the advance of modernization, the consumption of housing and car growing; plus the new growth point of solar glass industry, all these resulting in increasing demand for glass, glass industry continues to develop, thus nitrogen oxide emissions rise.
 
Glass furnace is the indispensable melting Equipment of the glass manufacturing industry. Many processes of glass production including the furnace, the flame and oxygen-enriched furnace, ect., however their production processes require high temperature environment. A large number of nitrates, sulfate, silicate and other compounds used as the glass raw materials, so large amounts of nitrogen oxides, sulfur oxides and dust will generate in high-temperature production process. So the denitrification, desulfurization project is necessary.
 
Ammonia-selective catalytic reduction (SCR) is accepted as the most widely applied, mature, effective of flue gas denitrification technology. It can also apply to the glass furnace flue gas denitration project. The core of SCR denitration process is the denitration catalyst, which usually takes titanium dioxide as the carrier, vanadium pentoxide and tungsten trioxide (or molybdenum trioxide) as the main active ingredients, and with other additives.
 
Tungsten trioxide SCR denitration catalyst used in glass furnace flue gas denitrification mainly consists of two processes: acid-base catalysis and redox. Starting from ammonia absorbed, and then generates "activated" ammonia on the catalyst surface by oxidation and reduction; then the "activation" ammonia will react with vapor or NO which slightly adsorbed to produce non-toxic of nitrogen and water vapor, then discharged into the air, thus complete the cycle of catalytic denitrification.

 

Tungsten Trioxide Waste Plate Denitration Catalyst Recycles Metal Oxide

plate denitration catalystThe main treatment methods of waste denitration catalyst currently are landfill, burning and recycling, the first two methods have huge potential dangers on the environment. In addition, due to full implementation of emission reduction, the waste catalyst generated increasingly; the treatment ways of landfill and incineration will not only occupy a lot of land, but also bring a secondary pollution to the environment. The way of recycling includes used as boiler slag recycling vulcanizing agent and raw materials recovery, thus to apply for the production of new catalyst, the raw materials of steel plants; wherein, heavy metal with toxic and its relatively components must be separated. The way of basic recycling titanium, vanadium and tungsten from tungsten trioxide waste plate denitration catalyst is as follows:
 
1. Carry out the pretreatment by purging the catalyst with dry compressed air for 1h;
2. Peel off the paste of waste catalyst from the stencil and place it in a ball milling for 10 hours to obtain the recycling materials;
3. Recycling titanium dioxide: the certain concentration of sodium carbonate solution and recycling catalyst material are reacted to obtain sodium titanate solution containing other metal elements;
4. Add sulfuric acid and stir for 5 hours, then obtain the titanium dioxide after filtered, washed with water, dried and calcined;
5. Add HCl into the resulting filtrate of sodium titanate centrifuged to adjust the pH to 8.0~9.0, then add quantitative magnesium chloride, dissolve by stirring to get a white precipitate, and then get magnesium silicate by separating and drying the precipitate;
6. Add ammonium chloride into the filtrate after magnesium precipitated; stir to dissolve to obtain a vanadate precipitate, then calcined to obtain the vanadium pentoxide;
7. Add HCl of 5%~10% by volume ratio into the filtrate after vanadium precipitated to adjust pH to 4.5~5.0, then add calcium chloride solution, filtered and washed to obtain calcium tungstate.
 
The adding of Na, Cl elements in the recovery process of basic hydrometallurgical does not bring out the secondary pollution harmful pollutants, and the recovered titanium dioxide is of high purity which can be directly used for coating or catalyst producing.

 

 

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