SCR Denitration Catalyst Recovers Tungsten Trioxide

low temp ultra SCR catalyst Currently, working life of SCR denitration catalyst is generally 3~5 years, the commonly treatment ways of the deactivated catalyst are regenerating or landfill. Landfill will not only result in the occupation of land resources, but also a tremendous waste of resources. According to statistics, by 2018, it will produce annually 38,000 tons of waste SCR denitration catalyst, which contains 1520 tons of tungsten trioxide. Because tungsten is a rare metal and the very high price of tungsten trioxide, if the waste SCR catalyst can’t get reasonable treatment and the valuable resources can’t be recovered, the great waste of resources will cause.
 
Simple method for recovering tungsten trioxide from SCR denitration catalyst is as following:
1. Crushing the tungsten trioxide contained waste SCR denitration catalyst into dry powder, and calcining under a high temperature;
2. Add the waste SCR denitration catalyst and ammonia in a sealed reactor and heated to 60~180°C;
3. Stand until the liquid-solid layers stratified after fully dissolved (for 5~15 hours), then collect the upper layer of serum;
4. The lower layer of solid residue and ammonia are added into the reactor, heating and collect the supernatant upper layer of serum;
5. Repeat steps 3 and 4 at least once;
6. Collect the upper layer of serum of tungsten trioxide component and evaporate to dryness and water is sufficiently dried, to obtain a solid;
7. Calcining the solid obtained in the step 6 under the high-temperature (conditions: 500~800°C, roasting time for 1~5 hours) to generate tungsten trioxide, thus completing the process of waste SCR denitration catalyst recycling tungsten trioxide.
 
Using this method, the recovery rate of tungsten trioxide can ensure up to 95%, and with high purity (98.5%), which can be directly re-used for the production of SCR denitration catalyst; in addition, the waste of resource is reduced which brings the positive implications of both economic and environmental protection.

 

WO3 Desulfurization Catalyst Used for Preparing Superior Grade White Oil

desulfurization catalystWhite oil, alias paraffin oils, mineral oils, is the highly refined colorless oily liquid with odorless, and has excellent chemical and light stability. It is widely used in industries such as cosmetics, food, pharmaceutical, plastics, chemical fiber, machinery and light industry.
Hydrogenation method to prepare white oil often bases on the material of hydrocracking tail oil, and dewaxed by solvent or catalytic, and then generated by high-pressure hydrogenation nickel catalyst saturating; with the advantages of no pollution, high yield, wide source of raw materials, full product range, etc., it gets rapidly development and universal application.
 
The specific process of hydrogenation process for producing high quality white oils include: under the suitable conditions, oil feedstock and hydrogen successively go through the reaction zone which contains three catalysts, the first reaction zone packed with a hydrotreating function catalyst, the second reaction zone loaded with the pour function catalyst, and the third reactor zone packed with a hydrogenation saturation function catalyst. The packing volume ratio of catalysts in three reaction zones can be 0.2~0.6:0.2~0.6. Reaction conditions: temperature 220~360 ℃; hydrogen partial pressure of 2.0~16.0MPa; the liquid hourly space velocity is 0.2~3.0 hours; the ratio of hydrogen and oil is 120~1000.
 
The three catalysts are:
1. Pre-hydrogenation refining catalyst, the aluminum oxide as carrier adding with other refractory oxide, the main components: cobalt oxide or nickel oxide, 15 ~ 40wt% of tungsten trioxide or molybdenum oxide;
2. The high activity of hydrodewaxing catalyst, which contains 3~25% of tungsten trioxide, 2-10% of molybdenum trioxide, 1-10% of nickel oxide, 1-8% of zinc oxide, 1-10% of tin oxide;
3. The high activity hydrofinishing catalyst, which the content of cobalt oxide or nickel oxide is 2~10wt%; content of tungsten trioxide is 15 ~ 40wt%.

 

Lanthanated Tungsten Electrode Metal Injection Molding

tungsten electrode cubes

The Metal Injection Molding (MIM) of insoluble metal is mainly used for manufacturing parts with complex and small size. The metal which produced by MIM isn’t has particularly high temperature strength and fatigue performance, but it can save a high of insoluble metal machining costs to achieve a nearly net shape. Traditional tungsten electrodes were produced by sintered tungsten bar and after machining to obtain pure or rare earth tungsten electrodes. Tungsten has highest melting point in insoluble metal, so machining is difficult and the cost is high, so using MIM to produce tungsten electrodes used in lighting equipment are more and more attention and favor in manufacturers. Compared with traditional method, tungsten electrode manufactured by MIM not only has complex shape which can use in different lighting equipment, but also has good performance. Pure tungsten and doped tungsten (AKS-W) is a common anode material, and thoriated tungsten, barium tungsten, and lanthanated tungsten electrode is often used as a cathode material.

Lanthanum tungsten electrodes (W-La2O3) manufactures by MIM, and the production processes are as following:
1. The La (NO3) 3 • 6H2O was dissolved in alcohol and then mixed with tungsten powder (0.1um), in which La2O3 addition is 1.5%.
2. Place the mixture into a mixing ball mill for 24h, and then to employ drying and screening process. The milling medium is alcohol, grinding body is tungsten rod.
3. The sieved powder is baking and reduction at 600 ℃, so that La (NO3) 3 will decompose into La2O3.
4. Using paraffin-polymer binder to produce MIM feed. Determine the critical powder load in feed by torque rheometer. Since 1um tungsten powder produced feed has good flow, so the loading is used 55% of the volume fraction. Besides, the compounding temperature is 158 ℃, and roller speed is 60r / min.
5. Then after injection, degreasing and sintered will obtain lanthanated tungsten electrode.

Monkey Tungsten Gold Plated Bar

Monkey tungsten gold plated bar, also called Monkey tungsten alloy gold plated bar, which implies the characters of smart and active. Zodiac Monkey ranks 9th in the twelve zodiacs, when it comes to the year of Monkey, a great number of commemorative activities will be held among the banks or business companies for expressing their appreciation to their clients. 
 
Monkey tungsten gold plated is actually made of tungsten alloy material inner, and gold plating about 0.3 micrometer on its surface usually. It has a bright color almost the same as the real gold from its appearance, so it is cost-effective for them to save cost for their promotion. Besides, when babies was born in the year of Monkey, if there should be a gift of Monkey tungsten gold plated bar could be presented, then the blessing of health and longevity will be express apparently. Owning to its special properties of wear resistance and corrosion resistance, Monkey tungsten gold plated bar becomes the most suitable choice for commemoration, collection and present to each other. Unit weight, engraving, images, gold plating could be customized.
 
Monkey tungsten gold plated bar

Goat Tungsten Gold Plated Bar

Zodiac Goat ranks the eighth in the twelve zodiacs, which is a lucky symbol, so Goat tungsten gold plated bar is usually utilized as commemoration or gift for the relatives or friends, which to express their blessings of health and safety for their life. Goat has docile characteristic, so Goat in China is also a symbol of good mascot. People, who are Goat, generally have the gentle, kind-hearted characters, and are full of compassionate. When the Year of the Goat is coming, Chinese people will put up with decals, paper cutting, which are engraved or painted with goats for blessing and greeting.
 
Unit weight could be controlled raging from 28.35 g to 10KG (1 OZ to 35.27 OZ); also the gold plating could be customized such as 18K, 24K. Engraving could be providing as per special drawing design with different engraving content requirements such as the name, birthday, blessing words, etc. Besides as the collection for families to commemorate the year of Goat, it could also be applied for many business activities to symbolize the long-term cooperation relationship between each part. We are open to any special drawing design related to Goat tungsten gold plated bar. Although Goat tungsten gold plated bar does not have the same hedging value as real gold bar, but it is similar to real gold, which also has the high appreciation value and can be easy carried. Besides, it can greatly avoid the economy loss caused by real gold damage or lost. Thus, using Goat tungsten gold plated bar as gift, collection or souvenir to your friends or relatives could be an ideal thing.
 
Goat tungsten gold plated bar

Eltra Carbon Sulfur Analyzer and Tungsten Granule

Eltra brand was estabilished in 1980 in German, mainly focusing on research and development of elemental analyzer. It has been extended to the oxygen nitrogen hydrogen analyzer from the beginning of carbon sulfur analyzer, which is wild about research and manufacturing of analyzer. Nowadays, Eltra has become the leader on the area of elemental analyzer, which is mainly applied in steel, mining, automotive, aviation, coal, building materials, and universities and research institutes. This brand developed a resistance furnace carbon sulfur analyzer with Siemens in 1981, which was first sold in Germany in 1984. In 1988, Eltra researched and developed induction furnace carbon sulfur analyzer, expanding the international market and improving the instruments and technology for many years.

Eltra carbon sulfur analyzer can detect the content of iron, copper, alloys, ores, cement, ceramics, carbon compounds, minerals, sand, glass and other solid materials quickly and accurately. Carbon sulfur analyzer of this brand mainly consists of 16-bit microprocessor, a separate induction furnace and four Infrared detecting pools which are used to detect high and low carbon and sulfur respectively. In the detection process, this instrument can automatically switch the low range and high range of detection. The CS-800 carbon sulfur analyzer of Eltra usually adopt tungsten granule as its flux, and it has a high sensitivity, good performance, wide measurement range, and accurate analysis results, etc. There is a more special characteristic, when the detection analysis, the instrument can display its working status real time to ensure the analysis can be done simply and reliably. In addition, detection time of this type of carbon sulfur analyzer is only 40-50 seconds, which costs less time to finish the determination, and it generally use magnesium perchlorate and alkali asbestos as chemical reagent.

ELTRA is one of the world's leading manufacturers of elemental analyzers for rapid and accurate analysis of solid materials. The carbon / sulfur analyzer CS-800 is equipped with up to four independent infrared (IR) cells which allow for precise simultaneous analysis of high and low carbon and sulfur concentrations in one measurement. The sensitivity of the cells can be customized individually by selecting the length of the IR path to ensure the optimum measuring properties for each application.

tungsten granule

Labfit Carbon Sulfur Analyzer and Tungsten Granule

Labfit brand was established in 1992, which is an Australian-owned manufacturer of commercial grade laboratory equipment in the soil testing and carbon sulphur analysis industry. Labfit carbon sulfur analyzer is a famous Australian brand, which has many excellent technical staff that has rich experiences with solid theoretical foundation in Australia, won the trust and praise of majority of users. It possesses advanced analysis, testing, testing equipment, the main application areas include petroleum, coal, materials, universities, chemical, metallurgy, environmental protection, food and agriculture and others.

Its CS1232 infrared carbon sulfur analyzer enjoys a great popularity in the world. The type of Labfit carbon sulfur analyzer uses the latest solid-state infrared absorption detection technology with high measurement accuracy. The application of vertical furnace, make the temperature can be controlled at the set value of 1%, which can reduce the chances of rupturing of a ceramic tube. Its user interface is intuitive and easy to be understood. When the analysis of the measurement, the measuring system will automatically select the appropriate sulfur measurement unit by using the 48-bit sample injector.

Width of CS1232 infrared carbon sulfur analyzer is 76 cm, its depth is 66 cm with a height of 93 cm. It weighs about 90 kg. The detection method is using a solid-state infrared absorption. Vertical resistance furnace, using a cylindrical silicon carbide to heat elements, in order to ensure uniform temperature distribution. Use two magnesium perchlorates as drying tower, and adopt a glass wool as a filter. The carrier gas is 99.5% of pure oxygen, pneumatic gas is dry and clean compressed air, the flow of oxygen should be controlled at 3l per minute. Double purification system is used to prevent gas from entering inside the combustion tube, avoiding unnecessary industrial accidents. Using a non-porous ceramic crucible, tungsten granule is the main flux. Analyzed data including time / date, name of samples, description, number of samples, weight of samples, dial number, analyzing data, analyzing curve, analyzing time, and other standard values. However, the analysis would take long time to finish the determination, which requires 60-180 seconds. It is easy to operate air filter dust collectors and centrifugal sampling tube whose material is very strong, and it can withstand daily use. It is portable equipment with a simple appearance, with a simple keyboard to input flow calibration value.

tungsten granule

Annealing Effect on Tungsten Bronze Niobate Structure

Tungsten bronze structure dielectric material is the important dielectric system only following perovskite, with complex crystal structure and rich ferroelectric phase transition and dielectric relaxation characteristics, which is potential multiferroic material and it has unique properties of excellent ferroelectric, piezoelectric, pyroelectric and nonlinear optics, etc., has gained more and more attention. In recent years, some researchers try to introduce Fe, Co, Ni and other magnetic ions to tungsten bronze niobate ferroelectrics, and found some multiferroic materials have both ferroelectricity and ferromagnetism at room temperature.
 
However, these ceramic materials require high temperature sintering, the sintering process on the one hand easily leads to changes in iron valence and the generation of oxygen vacancies; on the other hand, high-temperature sintering ion distribution is relatively disordered, and the subsequent cooling rate is usually faster, making the high temperature disordered state maintain a low temperature. As we all know, the annealing process is an important means to control the metal material structure and properties. Similarly annealing also has many applications in the ceramic material, such as Xia reported that the impact of annealing on lead-based relaxor ferroelectric properties, it’s found that peak dielectric constant and piezoelectric properties improved after annealing lead-based relaxor ferroelectrics significantly. There are more and more studies of ceramics annealing process in recent years.
 
Because of the complex structure of the tungsten bronze, tungsten bronzes ceramics typically contain a variety of ions in the A, B bit, and it may contain different valence ions (such as iron or titanium), the sintering temperature is likely to cause changes in ion valence and generate oxygen vacancies and affects the distribution of ions. The content of oxygen vacancies and the degree of ions ordered the distribution have great impacts on its corresponding ion tungsten bronze structure, dielectric properties, ferroelectric properties. Tungsten bronze structure is relatively complex, the annealing treatment will help to improve that the tungsten bronze niobate large ions occupy large clearance position and small ions occupy a small gap position. At the same time, under different atmosphere, annealing can also effectively control the concentration of oxygen vacancies niobate. At present, there are a lot of tungsten bronze ceramic studies, but there is little about annealing effect on the tungsten bronze ceramics structure and properties. Thus, firstly prepared iron-tungsten bronze niobate Ba4Nd2Fe2Nb8O30 by solid-phase method, then annealed ceramic in oxygen and nitrogen after being sintered, study about annealing treatment effects on its structure, dielectric properties, ferroelectric properties.
 
Tungsten Bronze structure

Tungsten Alloy Gamma Ray Shielding

Tungsten Alloy Gamma Ray ShieldingGamma ray, also denoted as the lower-case Greek letter γ, is extremely high-frequency electromagnetic radiation that consists of high-energy photons. It is produced from a process called gamma decay in which an atomic nucleus decays from a high energy state to a lower energy state. Gamma rays typically have frequencies above 10 exahertz, and thus have energies above 100 keV and wavelengths less than 10 picometers, which is less than the diameter of an atom. However, this is not a strict definition, but rather only a rule-of-thumb description for natural processes. Electromagnetic radiation from radioactive decay of atomic nuclei is referred to as "gamma rays" no matter its energy, so that there is no lower limit to gamma energy derived from radioactive decay. This radiation commonly has energy of a few hundred keV, and almost always less than 10 MeV.

Gamma-ray has wavelengths shorter than X-ray, so it has more strong penetrating power than X-ray. In addition, the high-energy gamma ray is an ionizing radiation, which can cause harm to humans. When the body is subjected to 200 to 600rem doses of γ-ray radiation, hematopoietic organs of the body (such as bone marrow) will be damaged, and the rays can cause the loss of white blood cells, bleeding, hair loss, and the probability of death within two months ranges from 0 to 80%; when the radiation doses are in the scope of the 600-1000rem, the probability of death within two months ranges from 80-100%; when the scope of radiation doses changes to 1000-1500rem, the human gastrointestinal system will be destroyed, accompanying some symptoms such as diarrhea, fever, endocrine disorders, and the probability of dying within two weeks almost 100%; when the radiation doses up to 5,000rem or more, can cause central nervous system damage, spasm, tremor, disorders, narcolepsy, and the probability of death within two days is 100%.

Tungsten alloy gamma ray shielding has strong ability of gamma-ray linear attenuation, so it is an ideal γ-ray shielding material. Compared with conventional shielding materials, tungsten alloy shielding reflects good value. Lead was early used as shielding material, but in the use process discovered, its radiation shielding performance is not high enough, and it can also cause serious pollution to the environment. While under the conditions of the same thickness, the radiation shielding capability of tungsten alloy shielding is twice than the lead shielding.  Moreover, tungsten alloy shielding does not produce harmful substances, so do not worry that it will cause harm to human health.

 

Tungsten Alloy Application in " the Palm of Death" --- Grenade

We saw a lot of sophisticated weapons and a number of top military equipments in the parade of Chinese People's War against Japanese Aggression and the World Anti-Fascist victory 70th anniversary in the Tiananmen Square from TV. But in the past China, or any other countries during the war, the weapons could have ability to be used in war are all very simple, but people can always create "surprise" under a difficult circumstance. Grenade is such a surprise. It is one of the common military weapons, which has excellent blasting and lethality, and was firstly used and invented by the Chinese people. It is one of the main weapons of the infantry troops for close combat. Grenade has small size so that can be easily carried. It can be well used for attack and defense, and plays an important role in the last period of relatively simple weapons.
 
Then what aspect can tungsten alloy apply in such “the palm of death"? Actually, the main application of tungsten alloy in grenade is to act as prefabricated fragment for lifting explosion lethality of grenade. Tungsten alloy prefabricated fragment has been widely used in the warhead of various types of weapons, grenade is one of them. Tungsten alloy prefabricated fragment is commonly existed in the form of ball and small blocks, then being attached to the inner surface or the outer surface of a variety of grenades. It would form a more centralized fragment lethality area with the exploration power, so as to hit the enemy and their weapons and equipments. Compared to iron prefabricated fragment, tungsten alloy prefabricated fragment would be more advantage, because tungsten alloy is with high corrosion resistance, wear resistance, and it’s very heavy, so that would be more lethal, which can also greatly prevent the drops of serviceability of grenade caused by iron rusting.
 
British DM61A1 fragmentation grenades and DM78A1 with tungsten alloy prefabricated fragment
 

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