Tungsten Oxide Ceramics EDS Spectroscopy

Tungsten oxide picture

The leakage current of the tungsten oxide ceramic varistor under the action of the applied voltage is a decreasing process with time. This shows that the grain boundary barrier model of tungsten oxide varistors is different from conventional varistors such as zinc oxide.

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UV Light Affects the Gas Sensitive Properties of Tungsten Oxide

Tungsten oxide picture

Researchers have found that ultraviolet and visible light can provide energy for the surface chemical reaction of tungsten oxide gas-sensitive materials, thereby accelerating the rate of chemical reactions, thereby improving its gas-sensing properties. The study found that ultraviolet light affects the gas-sensitive properties of tungsten oxide gas mainly through two aspects:

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Sintering Densification of Tungsten Carbide

three stages of densification image
Sintering densification of tungsten carbide is the most prominent change in the sintering process. There are many kinds of statements about the mechanism of densification. Views include diffusion control, flow control, physical and chemical reaction process control, etc. At present, the mainstream view regards the whole densification process as a complex process of the three stages of diffusion - flow - rearrangement.

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Influence Factors of Sintering Densification

pore of tungsten carbide image
The sintering process of tungsten carbide is divided into pre-sintering (deforming agent), solid phase sintering, liquid phase sintering, cooling and so on. During the sintering, the volume of the block will shrink, and the pores decrease greatly, which is so called the sintering densification. Liquid phase flow and particle rearrangement during the stage of liquid sintering do contribute a lot to densification. The liquid-solid wetting angle and the content of cobalt are two of the most important influence factors.

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Influence Factors of η Phase

WC-Co tungsten carbide SEM image
As for WC-Co tungsten carbide, the nucleation and growth of its η phase is restricted by the composition and quantity of the alloy's γ phase. Therefore, the increase of carbon content and cobalt alloy amount and the WC grain refinement lead to the increase of η phase concentration distribution and size coarsening. The increase of sintering temperature and cooling rate will reduce the number and size of η phase.

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γ Phase of WC-Co Tungsten Carbide

WC-Co tungsten carbide SEM image
WC-Co tungsten carbide is the most widely used type of tungsten carbide. In industry, it is usually alloyed by powder metallurgy sintering such as low-pressure sintering. In the liquid process of phase sintering, WC is partially dissolved in cobalt, forming a Co-W-C solid solution based on Co. The solid solution phase is γ phase. The existence of γ phase makes the grain of WC rearranged and regrown, which is beneficial to the homogenization of grain.

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Composition Change of WC-Co Tungsten Carbide

WC-Co pseudo binary phase diagram
WC-Co tungsten carbide is widely used because of its mature technology. In sintering, its components will change as the temperature changes. It is necessary to make a thorough understanding of the composition changes in the holding and cooling stage which will have a great influence on tungsten carbide. Generally, the WC-Co pseudo binary phase diagram is needed, as shown in the following figure.

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Tungsten Oxide Ceramics Varistor Performance

Tungsten oxide picture

In 1994, it was first discovered that doped tungsten oxide varistors have varistor properties. Due to the lower varistor voltage, the varistor characteristics of tungsten oxide attract attention. Later, the effects of alumina and other dopants on the pressure sensitive properties were reported. However, the varistor characteristics of tungsten oxide varistor ceramics are extremely unstable, such as poor reproducibility of electrical behavior and negative resistance behavior, and the nonlinear coefficient is much smaller than that of zinc oxide. Therefore, there are few reports on tungsten oxide varistor ceramics in foreign countries, but there are many reports on the use of tungsten oxide varistors in gas sensors.

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Tungsten Oxide Ceramic Grain Growth

Tungsten oxide picture

Because of the larger radius of oxygen atoms, poor mobility. Therefore, in the sintering process of oxide ceramics, the transmission rate of oxygen atoms determines the sintering performance of tungsten oxide ceramics.

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Tungsten Oxide Ceramic Voltammogram

Tungsten oxide picture

The graph below shows the volt-ampere characteristics of tungsten oxide ceramics sintered at different holding temperatures. The electrical non-linear behavior of varistors typically occurs at current densities in the region of 1-10 mA. From the figure we can see that at 1050 ℃ 1100 ℃ and insulation for two hours of tungsten oxide ceramics, in the current density of 1-10mA region has a non-linear volt-ampere curve. That is, the pressure sensitive characteristics are exhibited.

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