Tungsten Copper Sheet Properties

Tungsten copper sheet properties refer to phase analysis, micro-structure observation and other properties detection. The phase analysis can be specifically divided into DTA (Differential Thermal Analysis), XRD phase analysis (X-ray Diffraction), component test and so on. DTA uses differential thermal analyzer, the principle is to compare by not undergo any chemical reactions and physical changes at a certain temperature stable substance as a reference with an equal amount of measured (tungsten copper sheet) in the same environment under constant variable temperature conditions. Any physical and chemical changes on the measured and it is located in the same environment as compared to the standard temperature will be a temporary increase or decrease. The XRD phase analysis uses copper K radiation target, adjust current, voltage, and scanning rate, the measured characteristic X lines of tungsten copper sheet specimen major constituent phases.

For tungsten copper material, component test usually uses dilute nitric acid - hydrofluoric acid solution, which due to W will precipitate in nitric acid medium in the form of acid and separated from the Cu. Next ammonium hydroxide precipitate was dissolved tungstate, ammonium tungstate determination of tungsten burning gravimetric method; then inductively coupled plasma atomic emission spectrometry filtrate the residual tungsten, both of which add up to the total amount of tungsten. The process of micro-structure of tungsten copper sheet detecting is Sandpaper milling → Washing → Polishing (Al2O3) → Washing → Alcohol Cleaning → Drying → Detecting Sample.

The performance tests include density test, hardness test (Vickers hardness HV), resistivity (electrical conductivity) test, thermal conductivity test, coefficient of thermal expansion test and so on. Density test uses a classic method of drainage method of Archimedes; micro hardness is measured by the length of indentation of diamond indenter pressed into the surface of the sample; the resistivity usually uses bridge method; Thermal conductivity is the first on the surface of tungsten copper sheet sample sprayed on the surface of the toner in order to prevent the reflection of incident light, then at a certain temperature using the flash method thermal analyzer heating element xenon lamp emits a pulse beat in the sample surface, warmed by the infrared detector measures the situation was thermal diffusivity.

Tungsten Copper Sheet Process

Due to tungsten copper material is composed of two kinds of metals with a great difference in melting point, which copper evaporates and takes off part of heat for equipments working well at high temperature. Especially in some electronic components with high power and easily heated, tungsten copper as heat sink has wide applications. However, with the rapid development of electronic science and technology, electronic components have become smaller and more precise, which places a greater demand on tungsten copper sheet and heat sine materials. Conventional process of tungsten copper sheet has some defects in thickness and density, so it is difficult to meet the requirements of the properties of heat sink materials. In order to fabricate tungsten copper sheet with uniform thickness and high density, the researchers study on three levels, which include continuous liquid phase sintering, cold rolling and re-sintering.

In the process of continuous liquid phase sintering, the preparation of raw material is also crucial. It should be noticed that the content of elements and granularity, the additives, the stirring time, the granulation process, drying temperature, forming pressure, blank density detection and many parameters controlling. Continuous liquid phase is conducted in molybdenum wire furnace under the protection of hydrogen. It puts tungsten copper sheet in the high temperature zone and holds a period of time, and then push to end cooled rapidly cooled to obtain the sintered sample. Afterwards, The sintered samples in the two-roll cold rolling mill and cold rolling deformation measurements, observed by optical microscopy that is rolling a longitudinal section (parallel to the rolling direction), the evolution of the cross-section (perpendicular to the rolling direction) of the microstructure. Finally, re-sinter tungsten copper sheet after cold rolling in the molybdenum wire furnace under the protection of hydrogen, and temperature should be controlled 1300℃ (above the melting point of Cu), in the high temperature zone without holding time in case of grain growth.

tungsten copper sheet

 

Reaction Time Effect on CsxWO3 Powder Absorbance

The figure is the diffuse reflectance spectroscopy of cesium tungsten bronze (CsxWO3) powder synthesis in different hydrothermal reaction time. The figure shows, with the extension of reaction time, the absorbance of CsxWO3 gradually increases in at visible and near-infrared short-wave region; the absorbance lowest point appears at a wavelength of 450 nm, with high absorbance in the UV and short wave near infrared region, it showed good performance on UV absorption and short-wave near-infrared absorption properties. High absorption in the direction of the UV edge is because of CsxWO3 intrinsic absorption, which is mainly determined by the band gap of CsxWO3; and absorption in the visible and short wave near infrared may be related to free carrier absorption in CsxWO3 system. In general, the higher the concentration of free carriers, the more obvious the free carrier absorption. It’s reported in the literature that CsxWO3 is a low resistivity material, there are more free carriers in the system, and thus there is a strong free carrier absorption and free carrier absorption coefficient has following relationship to the free carrier concentration and the wavelength of light absorbed:
equation 1
 
N is the refractive index of medium, e0 is the vacuum permittivity, the carrier effective mass, m is the magnetic permeability, μ is the wavelength of the incident light, n is the free carrier concentration. Free carrier absorption coefficient α and the square of the wavelength and irradiation free carrier concentration n is proportional, so at wavelengths of greater than 450 nm, the CsxWO3 absorbance increase with increasing wavelength, it shows strong absorption properties in the near infrared shortwave. The increasing hydrothermal reaction time contributes to a thorough reaction and the formation of complete crystals, and in the mean while, may increase the content of the cesium ions into the tungsten bronze, which improved carrier concentration of CsxWO3 system, so its absorbance in the visible and short wave near infrared region gradually increases with the reaction time.

Diffuse absorption spectra

WO3 Desulfurization Catalyst Environmental Effects

Living in this extremely developed era in technology and industry, power plants, automobiles are fully around us. Thermal power plants cause very serious air pollution, besides, by the terms of chemical plants and factories, their exhaust emissions also make the air quality even worse. Determined to rectify the environment is not just a government thing, but more of the people's environmental awareness.

desulfurization catalyst
 
For example, the exhaust of car causes more serious environmental pollution along with civilian price. The ordinary people cannot control the oil quality upgrade, but can install SCR catalyst in the car exhaust pipe, thus to reduce urban pollution. Earlier developed precious metal catalyst is too expensive to be accepted by general public; fortunately, we have developed a non-noble metal catalysts and catalyst-frequency combustion through continuous research, such as tungsten trioxide SCR desulfurization catalyst, which maximize purifies sulfur dioxide and other harmful emissions.
 
In ten years from 1990~2011, thermal power generation capacity in China raised from 0.5 trillion kW•h to 2.7 trillion kW•h, which takes 82% of the average total electricity generation. By the time thermal power plants bring such a large amount of electricity, it also cause caused a huge burden to environment, so, it is imperative in managing thermal power plant flue exhaust. For incineration plants, non-precious metal catalysts are the first choice because of their huge consumption. These desulfurization catalysts are use titanium dioxides as framework materials, and the vanadium pentoxide as the main active ingredients. Tungsten trioxide as an active ingredient has been added to the desulfurization catalyst, since it has the property of anti-vulcanization and anti-poison, thereby to enhance the activity of the catalysts.

 

Lanthanum Tungsten Electrode Analysis

lanthanum tungsten electrodes

Lanthanum tungsten electrode is mainly produced by powder metallurgy method. It is added 1%, 1.5% or 2% lanthanum oxide to tungsten powder, after doping, reduction, vertical melt, swaging and stretching to obtain lanthanum tungsten electrode. Lanthanum tungsten electrodes have good welding performance, long service life, and no radioactive contamination, so it is considered the best substitute for thorium tungsten electrode and it is widely used in tungsten inert gas welding (TIG welding), plasma welding and cutting field. By comparison electrical property found, lanthanum tungsten electrode’s electrical property is superior to cerium tungsten electrode and thoriated tungsten electrode. Lanthanum oxide, having low mobility and evaporation rate, can form a good lap dovetail organization, so lanthanum tungsten electrode has good high temperature creep performance.

After swaging process, La2O3 particle is evenly distributed over the tungsten grain and boundaries. If not properly control billet processing, it is prone to delamination or peeling. On the other hand, if feeding too fast in swaging process can also cause delamination or peeling.

After electrical property analysis understand the La and Ce distribution in lanthanum tungsten electrode and cerium tungsten electrode. At DC 200A, for 20min, the electrode tip working at high temperature 2600 ~ 3000 ℃, La2O3 and Ce2O3 from the center migrate to the surface and to the tip. Their average content decreased gradually from the edge to the center portion and there has almost no La2O3 andCe2O3. Ce2O3 has faster migration and evaporation rate.

After electrical property test observed electrode’s microstructure found that the electrode grains grow along axial direction. The grains aspect ratio of cerium tungsten electrodes and lanthanum tungsten electrode is respectively (3: 1 to 15: 1), (3: 1 to 7: 1). In lanthanum tungsten electrode there are a large number of bubbles and a small amount of La2O3 particle. Besides, grain boundaries are dovetail lap organizations which can impede grain boundary sliding laterally, so it has better thermal shock, creep performance. Lanthanum tungsten electrode electrical property is better than other electrodes.

 

 

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