Cobalt Interlayed TiN-coated Tungsten Carbide Cutting Tool’s Performance Ⅱ
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- Category: Tungsten Information
- Published on Thursday, 10 September 2015 09:25
- Written by zhihua
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Atomic Layer Deposition of Tungsten Using Sequential Surface Chemistry with A Sacrificial Stripping Reaction
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- Category: Tungsten Information
- Published on Wednesday, 09 September 2015 17:55
- Written by xinyi
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Tungsten (W) films were grown with atomic layer control using a novel sequence of self-limiting surface reactions. The tungsten film growth was achieved by dividing the binary reaction WF6+Si2H6→W+2SiHF3+2H2 into two separate half-reactions. Alternating exposures to WF6 and Si2H6 in an ABAB… sequence produced tungsten deposition at temperatures between 425 and 600 K. The Si2H6 reactant served only a sacrificial role to strip fluorine from tungsten without incorporating into the film. FTIR spectroscopic investigations demonstrated that the WF6 and Si2H6 half-reactions were complete and self-limiting at T>400 K. In situ spectroscopic ellipsometry measurements determined a tungsten growth rate of 2.5 Å/AB cycle with WF6 and Si2H6 reactant exposures sufficient for complete half-reactions. The surface topography of the deposited tungsten films was flat indicating smooth film growth. The tungsten films were either amorphous or composed of very small crystalline grains and contained no measurable silicon or fluorine. These results represent the first demonstration of atomic layer deposition of smooth single-element metal films using sequential surface chemistry.
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Tungsten Carbide Ball Grades
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- Category: Tungsten Information
- Published on Wednesday, 09 September 2015 17:48
- Written by xiaobin
- Hits: 305
Some main tungsten carbide ball grades table
Grades |
WC contents(%) |
Co contents(%) |
Hardness(HRA) |
Density(g/cm3) |
TRS (N/cm2) |
YG6 |
94 |
6 |
89.5 |
14.5-14.9 |
1380 |
YG6X |
94 |
6 |
91 |
14.6-15.0 |
1500 |
YG8 |
92 |
8 |
89.5 |
14.5-14.9 |
1600 |
YG10 |
90 |
10 |
89.5 |
14.3-14.7 |
2200 |
YG15 |
85 |
15 |
87 |
13.9-14.2 |
2100 |
The table shows that the hardness will decrease by the increasing Co content, while its toughness and bending strength is enhancing. In addition, fine grain has higher density and hardness than coarse grain and other properties are also improving after sintering.
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Tungsten Carbide Ball Process
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- Category: Tungsten Information
- Published on Wednesday, 09 September 2015 17:50
- Written by xiaobin
- Hits: 294
Tungsten carbide ball has high hardness and usually above 87 HRA, which is double than normal steel ball so that the process is also difficult. The main problem is that the low surface energy of tungsten carbide ball, grinding media and abrasive adhesion is poor. Therefore, it has a huge influence on the efficiency and the accuracy or the surface roughness of tungsten carbide ball. Secondly, the rotation of tungsten carbide ball in the grinding plate is poor, which affects the machining accuracy carbide ball to some extent, especially spherical error.
At present, the most of equipments are based on steel ball process, which needs us to improve the equipment and grinding structure, choose proper grinding compounds and grinding plate for optimizing the parameters. In addition, high precision tungsten carbide ball milling mode includes that four-axis ball milling, V-groove grinding, conical grinding, spin rotation control, magnetic grinding and two-way rotation grinding.
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Determination of Arsenic,Copper,Manganese,Molybdenum,Phosphorus and Silicon in Ferrotungsten
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- Category: Tungsten Information
- Published on Wednesday, 09 September 2015 17:47
- Written by xinyi
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Determination of arsenic,copper,manganese,molybdenum,phosphorus and silicon in ferrotungsten by inductively coupled plasma atomic emission spectrometry.
A simultaneous determination method of arsenic,copper,manganese,molybdenum,phosphorus and silicon in ferrotungsten by inductively coupled plasma-atomic emission spectrometry was established.The samples were dissolved with oxalic acid and hydrogen peroxide.The matrix elements(W and Fe) and other coexisting elements had no interference with the testing elements.Under the optimal conditions,the detection limits of arsenic,copper,manganese,molybdenum,phosphorus and silicon were 0.009,0.006,0.000 1,0.000 3,0.005 and 0.002 μg/mL,respectively.The standard addition recoveries were 95 %-108 %,and the relative standard deviation(RSD,n=3) was 0.1 %-3.3 %.The proposed method has been applied to the determination of certified reference material,the results were in good agreement with the certified values.
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