Welding Tungsten Boat

welding tungsten boatWelding tungsten boat is also known as heating wolfram boat. Welding is connected directly to connecting position of the two metals together by the melting at high temperature. Heating and pressing five pieces of tungsten plates at a high temperature so that the connection can be melted together, cooling it after welding, forming the final shape of the boat. Welding of pure wolfram is generally divided into two processes: melting welding and brazing. During the melting welding, molten liquid of two workpieces will mix together under interaction of temperature field and gravity but without any pressure. Until the temperature decreases, the melted portion will condense, two workpieces will be firmly welded together to complete the welding. Brazing use metal material which has a lower melting point than the base material as the brazing filler metal, Heating the weldment and brazing filler metal to make its melting point higher than the melting point of brazing filler metal and lower than the melting temperature of the base material, using liquid brazing filler metal to wet the base metal, filling gap of joint and connect the base material. While welding, the joint of the wolfram plates is called soldering seam. Both sides of it would influenced by heating during soldering and organization and performance would change, this area is known as the heat affected zone.

Soldering is a fabrication or sculptural process that joins materials, usually metals or thermoplastics, by causing fusion, which is distinct from lower temperature metal-joining techniques such as brazing and soldering, which do not melt the base metal. In order to improve the quality of soldering wolfram boat, users can use argon, carbon dioxide and other gases to avoid atmosphere so that it can protect the arc and rate of furnace hearth while welding. Finally, a boat shape is formed by welding.

Its size is relatively large, so it can be used for large-scale evaporation device or a large number of material evaporation. Compared to riveting tungsten boat, soldering W-boat can save material of 10% -20%, and it doesn’t need to scribing, drilling, assembling, and other complex processes. Since welding tungsten boat is made of two or more plates, which cannot be made on one time, so the preparation time will be longer.

Sintering Tungsten Boat

sintering tungsten boatSintering wolfram boat is to firing anhydrous wolframic acid to produce tungsten powder, which is an important carrier for making it. Or loading ammonium paratungstate (APT) in firing W-boat to make wolfram powder, the APT is white crystal, which include schistose and acicular, it is applied in the manufacturing process of tungsten metal powder by anhydrous wolframic acid or blue tungsten oxide.

Sintering tungsten boat is mainly used in the production of tungsten powder. Burning ammonium paratungstate into yellow tungsten oxide or blue tungsten oxide, and then make wolfram powder in hydrogen. During the manufacturing process, tungsten oxide should be placed in a W-boat and then put in the reduction furnace. After recycling the hydrogen, remove the carrier. Fritting is divided into three stages, namely the low temperature burn-in step, the medium temperature firing step and keeping warm in a high temperature. In the low-temperature burn-in step is mainly to volatilize the gas and moisture content which is adsorbed in wolfram boat. Anhydrous wolframic acid is a raw material of wolfram powder.

Process for preparing tungsten powder can be divided into two stages. The first procedure is that the  anhydrous wolframic acid is reduced to tungsten dioxide at a temperature of 500 ℃ -700 ℃. The second procedure is that tungsten dioxide is reverted to the wolfram powder under the temperature of 700 ℃ -900 ℃. Purity, particle size, size distribution and other properties of the reduction of W-powder, which primarily rely on the reduction process. When you restore a wolfram powder in a tube furnace, temperature of reduction, charging capacity of tungsten oxide of W-boat, moving speed of W-boat, the flow rate of hydrogen and moisture content of hydrogen content are the main factors to influence the speed of reduction. Particle size of wolfram powder will become thicken as the temperature rises.

While firing, sintering tungsten boat can remove a portion of the harmful impurities, such as sulfur, potassium, sodium and others. This type of W-boat reduces the adverse effects of harmful ingredients (water, oxygen, nitrogen) of the product under vacuum fritting. It is in favor of eliminating the adsorbed gas and the residual gas of the pores which can promote post- fritting shrinkage. However, due to the high temperature, fritting stove would emit large amounts of waste heat.

WO3 Hydrodesulfurization Catalyst - Regeneration Flue Gas Treatment 2/2

desulfurization catalyst3. Preparation of the finished catalyst
Add a complexing agent of active ingredient (citric acid or phosphoric acid) in deionized water, then heated to above 70°C, and the required amount of tungstate, cobalt and nickel salt are added under continuously stirring, stop until the solid completely dissolved, to obtain co-infusion of the active ingredient; impregnating the semi-finished catalyst into the co-infusion of active component for 0.5~1 hour, then drying at 110~150°C for 2~6 hours, calcining at 200~500°C for 2~5 hours to obtain the final tungsten trioxide hydrodesulfurization catalyst. Wherein the content of tungsten oxide is 12%~15%; nickel oxide is 1.0% ~1.5%; cobalt oxide is 2.0%~3.0%; ferrous sulfate is2%~4%; titanium dioxide is 20%~30%; the rest is γ-aluminum-oxide.
 
NOx gases are avoided to produce during the preparation of this tungsten trioxide hydrodesulfurization catalyst, because no metal nitrate is used, to make the production process clean and pollution-free. The using method is to inlet a sulfur-containing gas into the tail gas hydrogenation unit of the sulfur recovery equipment, and then regenerated; the hydrogen sulfide after regeneration returns to the Claus sulfur recovery unit for recovering sulfur, the purified exhaust discharge under the standard after burning by the incinerator.
 
Advantages of this desulfurization treatment are as following:
1. The low using temperature which can be used in the hydrogenation of sulfur-containing gases at an inlet temperature of 220~280°C;
2. Without adding any facilities, sulfur-containing gas may be directly treated after introduced into the sulfur means tail gas treatment unit, which makes it an ideal treatment approach sulfur-containing gas;
3. The regenerated hydrogen sulfide returning to the process can not only recover the sulfur resource, but also avoid environmental pollution;
4. The activity of this kind of tungsten trioxide hydrodesulfurization catalyst is 30% higher than the conventional Claus tail gas hydrogenation catalyst, and the using temperature is lower for 60°C or more, with the excellent economic and environmental benefits by saving energy.

 

Tungsten Alloy Shielding Used For Radiation Technology

Tungsten Alloy Shielding Used For Radiation TechnologyWith the development and application of nuclear technology, radiation technology shows great potential in the medical, radiation processing, power generation, food security, industrial testing and other aspects. Radiation technology is a subject that is closely linked to the fields of high polymer materials, environmental science, biotechnology and medicine. It main uses radiation (such as gamma rays, X-rays, neutrons, etc.) emitted by radiation source to interact with matter to produce activated atoms and activated molecules which will react with matter both in both in physically and chemically, thereby improving the quality and performance of materials or leading to the degradation, polymerization and crosslinking modification of substances and preparation of new substances. The characteristics of radiation technology include high added value, low energy consumption and wide application, radiation technology is widely used in the modification of semiconductor and polymer, food preservation, and radiation sterilization of medical supplies and the like. Radiation technology can be categorized as radiation crosslinking, radiation curing, radiation vulcanization, radiation degradation, radiation grafted.

Radiation technology has brought radiological hazards while bringing the great facility to people. The largest long-term health risk of radiation is cancer. Radiation can destroy the mechanism in vivo which can prevent cancer, so that greatly increases the risk of cancer. Radiation can also enter the body through a variety of ways, causing internal radiation damage, leading to fatigue, dizziness, insomnia, skin redness, ulceration, bleeding, hair loss, leukemia, vomiting, diarrhea and other symptoms. In addition, radiation will increase aberration rate and hereditary disease incidence, to affect the health of future generations. Exposure to radiation will lead to genetic changes, once the DNA in reproductive cells are damaged, the new generation will inherit the altered gene of mother, thus increasing the risks of defects in the offspring. It is understood that the fetal embryos and fetuses are more sensitive to radiation, exposure to radiation before embryo implantation can increase the late fetal mortality rate; while in the case of exposure to radiation during organogenesis, the increased rates are elevated rate of fetal malformations and neonatal mortality.

Tungsten alloy shielding is widely used to absorb and shield radiation generated by the use of radiation technology. Experts have found that the radiation shielding capability of a material is closely related to its density, higher density means better shielding capability to shield and absorb the radiation. Since the tungsten alloy has a higher density compared with other radiation shielding materials (such as lead), tungsten alloy shielding exhibits better radiation shielding capability. Tungsten alloy shielding has high density also means that under the same shielding ability, tungsten alloy shielding is smaller and thinner. 

 

WO3 Hydrodesulfurization Catalyst - Regeneration Flue Gas Treatment 1/2

Adsorbent of gasoline desulfurization requires roasted and regenerated after adsorption saturation, while the regeneration flue gas still has a high content of sulfur dioxide. A secondary pollution will produce when using alkali absorption method to remove the sulfur dioxide, and cause wasting of sulfur resource at the same time. Generally, the volume content of sulfur dioxide in the regeneration flue gas is up to 5.4%, oxygen is up to 3.0%, while the temperature is only 160°C. However, the prior art Claus tail gas hydrogenation catalyst requires the volume content of sulfur dioxide less than 0.5%, the oxygen less than 0.05% at a temperature of over 280°C, which can’t meet the requirements of Flue gas desulfurization regeneration adsorption gasoline hydrotreating.

desulfurization catalyst
 
Chinese patent has referred a new method for processing sulfur-containing gas and developed a tungsten trioxide hydrodesulfurization catalyst with high activity for the hydrogenation of sulfur dioxide and lower using temperatures and, while recovering sulfur resource and avoiding environmental pollution. The catalyst is prepared as follows:
 
1. Preparation of carrier: Put titanium aluminum composite adhesive (the pore volume greater than 0.6mL/g, a specific surface area greater than 250m2/g, a sodium content less than 0.1%, S042- content less than 0.2%), binders (e.g. water, or nitric, acetic, oxalic and citric acid), expanding agent (such as polyvinyl alcohol, polyacrylamide, sesbania powder, citric acid, starch) into a kneader, extruded into a cloverleaf orifice (or other shape); then dry at 110~150°C for 2~4 hours, calcine at 500~600°C for 2~5 hours to obtain the catalyst carrier;
 
2. Preparation of semi-finished product
Add stabilizer (citric acid, acetic acid, hydrochloric acid or sulfurous acid) into the deionized water, stir to dissolve; then add the desired amount of deoxidation additives with stirring to completely dissolve to form a stable solution; and then immersing the carrier in the solution for the 0.5~1 hour, then drying at 110~150°C for 2~6 hours, calcining at 200~500°C for 2~5 hours to obtain the catalyst semi-finished product;

 

 

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