Blue Tungsten Oxide (BTO)

Blue tungsten oxide (BTO) is also called tungsten blue oxide (TBO),from which reduction reaction of ATP by hydrogen come, is an common raw material for tungsten powder,it have certain advantage in high specific surface area,easy reduction.
BTO'S PHOTO
The tungsten-oxygen system is rather complex which could be stable stoichiometric binary oxides(WO3, WO2.9, WO2.72 and WO2).TBO is an mixture of different compounds, mainly WO2.90 and ammonium tungsten bronze(ATB).TBO have been used to produced tungsten powder from 1970s, and now is the most important precursor in the line from oxide to W and WC powder. 
 
The main blue tungsten oxide preparation methods are pyrometallurgical process and hydrometallurgical process.The former is widely applied in industry,commonly using reduction reaction of ATP by hydrogen in rotary furnace.The chemical equations of TBO's preparation as shown follows:
 
5(NH4)2•O•12WO3•5H2O→5(NH4)2•O•12WO3+ 5H2O
5(NH4)2•O•12WO3→12 WO3+10NH3+5H2O
2NH3→N2+3H2
WO3+H2→WO2.9+H2O
 
The factors affecting  properties of TBO in preparation process are temperature,heating rate and heating time, etc.
 

Carbon Distribution of Tungsten Carbide Powder

Tungsten carbide powder is the most important raw material for cemented carbide production, carbonized by tungsten powder and carbon black with an appropriate proportion by carbon distribution calculation. The carbon distribution strongly affected the properties of tungsten carbide powder.

Tungsten atom and carbon atom can synthesize two kinds of compounds, WC and W2C.The former’s Molecular is the main and right ingredient of tungsten carbide powder, which carbon element mass accounted for 6.12%, the principle of carbon distribution. The formula is as follows:

Qc=(Xc/(100-Xc)+(0.75*Xo2)/100)*Qw

Qc­-the carbon black mass;

Xc-the carbon mass ratio;

Xo2-the Oxygen content;

Qw-the tungsten powder mass.

Because of uneven composition or inaccurate condition controlling, carbon mass ratio of tungsten carbide powder often deviate from 6.12%; therefore the extra carbon amount or tungsten powder should be added. The formula is as follows:
Qe=Q((100-Qa)/(100-Qt))

Qe­-the extra carbon black mass needs;

Qa-the Practical carbon black mass;

Q-the WC powder mass;

Qt-the total carbon black mass needs.

[know Tungsten] Tungsten Heavy Alloy Block

tungsten heavy alloy block image

For more details, please visit www.tungsten-alloy.com.

 

[Know Tungsten] Tungsten Wire Types

tungsten wire types image

 

【Know Tungsten】What is Cemented Carbide?

本视频文字图片

 

 

微博
微信

[Know Tungsten] Tungsten Powder

tungsten powder image

For more details, please visit www.tungsten-alloy.com.

 

 

 

 

 

[ Know Tungsten ] Tungsten Heavy Alloy Ball

tungsten heavy alloy ball image

 

[Know Tungsten] Tungsten Heavy Alloy

tungsten heavy alloy image

 

[Know Tungsten] Tungsten Copper Electrode

tungsten copper electrode image

 

[Know Tungsten] Tungsten Oxide

tungsten oxide image

 

 

WeChat