Tungsten heavy alloy is a composite metal alloy with up to 97% tungsten and 3% binding agents. Tungsten alloy often appears as a shield against x-ray and gamma-ray. It is also used for radiation shielding or as a collimator to focus radiation beams onto a target. In fact, these shields work so well that they have been used for many years by engineers that require radiation shielding or collimators. This is because tungsten alloy shielding has very high density,virtually 60% denser than lead. Hence, it provides superior attenuation characteristics for x-ray and gamma radiations.

There are many features of tungsten material is a preferred choice for radiation shielding. Here are some of the main features:
Tungsten has high effective in blocking harmful X-ray and gamma radiation.
Tungsten is nontoxic.
Tungsten is thinner and even lighter than lead shields.
Tungsten is not only easy to sterilize but is also easy to clean.
It is dimensionally stable up to 1000C.
Tungsten is hard, durable and easily machined with conventional tools.

  Tungsten Alloy Manufacturer & Supplier: Chinatungsten Online- http://www.tungsten-alloy.com
  Tel.: 86 592 5129696; Fax: 86 592 5129797
  Email:  sales@chinatungsten.com
  Tungsten & Molybdenum Information Bank: http://i.chinatungsten.com
  Tungsten News & Tungsten Prices, 3G Version: http://3g.chinatungsten.com
  Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn

After the study found that factors which affecting the violet tungsten oxide particle sizes have material (APT) particle size and production process conditions. Production process conditions include reducing temperature, heating rate, water vapor and hydrogen pressure ratio, material thickness and reaction time.
Firstly, the influence factor is water vapor and hydrogen partial pressure ratio, which are water vapor and hydrogen partial pressure ratio increases and the size of products larger. This is mainly due to the formation of hydrogen gas to form a volatile humidity hydrous tungsten oxide, tungsten oxide which is easy to cover the finer particles, so that the particle size increases. Second, the impact factor is heating rate, after experiment found that to produce fine particles the heating speed should not too fast. When the reduction in a tube furnace, the heating rate depends on the furnace temperature gradient and push the boat speed, hence reducing the furnace temperature gradient and push the boat speed are conducive to obtain fine particles of violet tungsten oxide. Thirdly, the reduction temperature influence violet tungsten oxide particle size. When the temperature increase the particle is grouping up. At the same time the reducing time also impacts on violet tungsten particles, the greater the reduction reaction of the longer particle size. Finally, the thickness of the material layer, the material thickness is larger, the larger the particle size of the product.



Tungsten Manufacturer & Supplier: Chinatungsten Online - http://www.chinatungsten.com
Tel.: 86 592 5129696; Fax: 86 592 5129797
Email: sales@chinatungsten.com
Tungsten & Molybdenum Information Bank: http://i.chinatungsten.com
Tungsten News & Tungsten Prices, 3G Version: http://3g.chinatungsten.com
Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn


 

With the development of research, the ultra-fine particles as a new material have been widely used in modern industry and science. Violet tungsten oxide (VTO) has special properties and structure so get a lot of favor in the producing ultrafine tungsten powder. During producing tungsten powder not only process conditions is important but the raw marital particle size is also an important factors. Therefore, to study the factors which influence violet tungsten particle size is very important.

Producing violet tungsten oxide is through boatload an amount of ammonium paratungstate and pushes it into the reduction furnace hot zone. At the same time add a certain proportion of hydrogen and steam mixture to heat at a certain temperature, after a period heat preserving then cooling to obtain.

During the reaction, the factors that influence the violet tungsten oxide grain size are the raw material (APT) particle size and production process conditions. Production process conditions include reducing temperature, heating rate, water vapor and hydrogen pressure ratio, material thickness and reaction time. The study showed that, the relationship between violet tungsten oxide and raw material particle size is raw materials get smaller the particle size is smaller.



Tungsten Manufacturer & Supplier: Chinatungsten Online - http://www.chinatungsten.com
Tel.: 86 592 5129696; Fax: 86 592 5129797
Email: sales@chinatungsten.com
Tungsten & Molybdenum Information Bank: http://i.chinatungsten.com
Tungsten News & Tungsten Prices, 3G Version: http://3g.chinatungsten.com
Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn


 

Understanding the main phase of violet tungsten oxide (VTO) has great impact on producing good properties tungsten powder. Because violet tungsten oxide main phase will influence tungsten particle grains morphology. Violet tungsten oxide in hydrogen reduction process undergone two major phase transition, γ-tungsten oxide→tungsten oxide (WO_2.72) → tungsten dioxide (WO₂) → tungsten powder.
After study found during the restore reaction the first phase transition is violet tungsten oxide to tungsten dioxide. At this stage with the reduction development the oxygen atoms decrease and oxygen vacancy increase of violet tungsten oxide, tungsten dioxide particles become denser than γ- tungsten oxide. But this is not easy to make hydrogen gas into the interior of the particles, the reduction process of the water molecules are also difficult to discharge, which is not conducive to the produce ultrafine or nano tungsten powder.
In the second stage of phase transition is tungsten dioxide restore to tungsten powder. According to the phase data, with the degree of reduction depth, tungsten dioxide’s oxygen atoms decrease and vacancies increased, resulting denser particles of tungsten powder, but little different with tungsten dioxide. Obviously, the morphology change of tungsten powder happen before produce tungsten dioxide.



Tungsten Manufacturer & Supplier: Chinatungsten Online - http://www.chinatungsten.com
Tel.: 86 592 5129696; Fax: 86 592 5129797
Email: sales@chinatungsten.com
Tungsten & Molybdenum Information Bank: http://i.chinatungsten.com
Tungsten News & Tungsten Prices, 3G Version: http://3g.chinatungsten.com
Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn


 

After many observed violet tungsten oxide the researchers found violet tungsten oxide has special structure which is good for producing fine or submicron tungsten powder.
After detailed studies of these three powders found loose structure violet tungsten oxide is conducive to speed up the reaction proceeds, and powder particle size is small than using other tungsten oxide to produce.
Using violet tungsten oxide as raw material to produce tungsten powder and the tungsten powder particle shape is kind of short rod or a chain particles which form by many particles, uniform size, particle size between 0.1 ~ 1um. Tungsten carbide powder particles shape is mainly equiaxed particle, uniform size, particle size is also between 0.1 ~ 1um. But the size is larger than the tungsten powder. This is mainly due to when carbonization the tungsten atoms does not occur large migration.
So using violet tungsten oxide to produce submicron tungsten oxide and tungsten carbide powder the particle shape are complicate and also has little single particle exist.



Tungsten Manufacturer & Supplier: Chinatungsten Online - http://www.chinatungsten.com
Tel.: 86 592 5129696; Fax: 86 592 5129797
Email: sales@chinatungsten.com
Tungsten & Molybdenum Information Bank: http://i.chinatungsten.com
Tungsten News & Tungsten Prices, 3G Version: http://3g.chinatungsten.com
Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn


 

Violet tungsten oxide (VTO) has a special structure and properties, is one of the most suitable materials for producing fine tungsten powder. Using violet tungsten as raw material by hydrogen reduction to obtain tungsten powder, tungsten powder and carbon mixture obtained submicron tungsten carbide powder, and then mixed with carbide powder to form submicron tungsten powder which has great significance for producing outstanding performance superfine alloy. Through the study of tungsten powder and tungsten carbide powder properties so that they can be more widely used in the different fields.

Through data analysis, violet tungsten oxide has special structure which is different form other tungsten oxide. Violet tungsten oxide is combined with rod-like and needle-like crystal, there are non-uniform of thickness, but it has big length-diameter ratio. So the kind of this structure has a lower bulk density which is good for hydrogen reduction reaction. So that the tungsten powder and tungsten carbide powder which produce by violet tungsten oxide can obtain submicron level particle size. 



Tungsten Manufacturer & Supplier: Chinatungsten Online - http://www.chinatungsten.com
Tel.: 86 592 5129696; Fax: 86 592 5129797
Email: sales@chinatungsten.com
Tungsten & Molybdenum Information Bank: http://i.chinatungsten.com
Tungsten News & Tungsten Prices, 3G Version: http://3g.chinatungsten.com
Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn


 

After many researches, the researchers found activated tungsten oxide is good for producing fine tungsten oxide than blue tungsten oxide. So compare the different between blue tungsten oxide and blue tungsten oxide.
The maximum content of the impurity element of activated tungsten oxide is similar with blue tungsten oxide. The mine phase of activated tungsten oxide phase is bronze (ATB) and the main phase of blue tungsten oxide is WO_2.9. The physical properties of activated tungsten oxide are: bulk density of it is 2.3 ~ 2.8g • cm^-1, -100 mesh sieve, specific surface area bigger than 3cm ² • cm^-3. Blue tungsten oxide physical properties is small different with activated tungsten oxide.

The study showed that in the same process, using activated tungsten oxide to produce tungsten powder there are little coarse crystalline grain and particle-piled which compare to blue tungsten oxide, besides tungsten powder are more uniformity and concentrated. So using activated tungsten oxide to produce tungsten powder is finer than using blue tungsten oxide.



Tungsten Manufacturer & Supplier: Chinatungsten Online - http://www.chinatungsten.com
Tel.: 86 592 5129696; Fax: 86 592 5129797
Email: sales@chinatungsten.com
Tungsten & Molybdenum Information Bank: http://i.chinatungsten.com
Tungsten News & Tungsten Prices, 3G Version: http://3g.chinatungsten.com
Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn


 

The quality of tungsten powder will directly affect the quality of tungsten carbide powder, so in order to produce high-quality carbide. The most important thing is to produce high quality tungsten powder. According to the actual situation of industrial production shows that using traditional blue tungsten oxide to produce tungsten powder by reduction reaction can no longer meet the requirements of some special products such as: FWG-4, FW1F and so on.
Using traditional blue tungsten oxide to produce tungsten powder by reduction reaction has some shortages. First, the distribution of tungsten powder particle size is too wide. Second, there are many coarse grains and particle-piled during producing fine tungsten powder. In order to meet the requirements of modern industrial production, the researchers use a fine powder, surface energy developed, high activity, and single phase’s activated tungsten oxide instead of blue oxide blue tungsten oxide to produce fine tungsten powder. 



Tungsten Manufacturer & Supplier: Chinatungsten Online - http://www.chinatungsten.com
Tel.: 86 592 5129696; Fax: 86 592 5129797
Email: sales@chinatungsten.com
Tungsten & Molybdenum Information Bank: http://i.chinatungsten.com
Tungsten News & Tungsten Prices, 3G Version: http://3g.chinatungsten.com
Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn


 

Violet tungsten oxide (VTO) production generally based on ammonium paratungstate (APT) as raw materials in industrial rotary kiln calcination conducted by NH₃, NH₃ decomposition H₂, so that APT in a mild reducing atmosphere calcination, gradually reduced to the violet tungsten oxide.

During the reaction, the furnace temperature, feed rate and speed of the furnace have some influence on the violet tungsten oxide producing. In certain conditions, the furnace temperature is too high, the feed rate is too small or the material staying in the furnace are too all of these factors are likely to cause APT not completely dissolved to violet tungsten oxide(W₁₈O₄₉). This will result in product clumping or knot furnace, thereby affecting the quality of the product.
And after study found when the furnace temperature is too low, while the violet tungsten oxide is needle crystal morphology, while the furnace temperature was higher, and the VTO is rod crystal morphology. Needle-like and rod-like morphology are basic crystalline morphology of VTO. After many studies, researchers found using needle-like crystal‘s VTO to produce tungsten powder are finer. Using rod-like crystal‘s VTO to produce tungsten powder is coarser. At the same time ammonium amount also will impact on VTO production, in order to ensure the reducing atmosphere furnace, for ammonium control is also very important.



Tungsten Manufacturer & Supplier: Chinatungsten Online - http://www.chinatungsten.com
Tel.: 86 592 5129696; Fax: 86 592 5129797
Email: sales@chinatungsten.com
Tungsten & Molybdenum Information Bank: http://i.chinatungsten.com
Tungsten News & Tungsten Prices, 3G Version: http://3g.chinatungsten.com
Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn


 

Cracked tungsten tube prepared by chemical vapor deposition is investigated by ring machine cutting method and X-ray stress analysis system. The results shows that crack initiating at two neighboring columnar crystal grain boundaries of the internal surface with the action of large residual tensile stress in the internal surface of the tungsten tube, and the propagation expended from columnar crystal grain boundaries to the outer surface of the tungsten tube. The existence of a large residual compressive stress on the outer surface of tungsten tube can arrest propagating cracks.

 

Tungsten Metals Manufacturer & Supplier: Chinatungsten Online - http://www.tungsten.com.cn
 Tel.: 86 592 5129696; Fax: 86 592 5129797
 Email: sales@chinatungsten.com
 Tungsten & Molybdenum Information Bank: http://i.chinatungsten.com
 Tungsten News & Tungsten Prices, 3G Version: http://3g.chinatungsten.com
 Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn