Beijing Introduced Low Nitrogen Transformation Subsidy, Tungsten Trioxide Denitration Catalyst Boosts Emission Reduction

June 4, approved by the Beijing Municipal Government, Environmental Protection Bureau, Finance Bureau, Quality and Technical Supervision of Beijing Municipal jointly issued the "Beijing Gas (oil) boiler low nitrogen transformation instead the subsidy of reward funding management rule"(hereinafter referred to as the" Rules "), which subsidizes the gas (oil) boiler low nitrogen transformation project, helps to further reduce emissions of nitrogen oxides, promotes the implementation of the clean air action plan to accelerate the improvement of air quality.

denitrification system and tungsten trioxide
 
Atmospheric pollution is mainly coming from the emissions and life pollution emissions which brought out from rigid demand of running city. The key of the air pollution control is nitrogen oxides, volatile organic compounds and coal-fired (VOC). Reducing the concentration of nitrogen oxides is an urgent need and the only way to improve air quality, while the low nitrogen transformation is a hard task for the implementation of new air pollution emission standards for boilers. In recent years, selective catalytic reduction flue gas denitrification technology (SCR) developed rapidly, and has been widely used in Europe and Japan; currently, the flue gas catalytic reduction denitration technology is the most widely used.
 
At present, the popular SCR processes worldwide are two kinds of SCR of ammonia and urea method. Both methods are occurred under the presence of a catalyst, and finally reduce the NOx into harmless nitrogen and water. The denitration catalyst is a core part of the SCR system, generally takes titanium dioxide as a carrier, vanadium pentoxide as the main active material, tungsten trioxide as a co-agent. Tungsten trioxide plays the roles not only anti-sulfide and anti-toxic in the denitration catalyst, but also enhances anti-sintering ability of the carrier itself, thus its importance is obviously.
 
Beijing introduced the "Rule" will not only stimulate the city's passion for denitrification transformation, but also established a benchmark in the provinces, then, the air quality will be greatly improved.

 

China Tungsten Industry Association Held Bureau Meetings in Chaozhou

In June 7, 2016, China Tungsten Industry Association, the sixth of nine Bureau meetings held in Chaozhou. The meeting analyzed the current tungsten market situation and reached consensus on stable market. Besides, the meeting examined and adopted the China Tungsten Industry 13th Five Years Plan and other relevant resolutions. The meeting was chaired by the vice president, executive chairman, the party committee secretary of Xiamen Tungsten Co., Ltd. Zhuang Zhigang.

China State Department counselor, president of the China Nonferrous Metals Industry Association and China Tungsten Industry Association, Chen Quan Xun attended the meeting and made a speech. He stressed that the members of the Bureau should play a leading role for stable tungsten market, they should enhance communication, unity, play attention to the interest of the whole, joint efforts to control market risks, resist the vicious competition, and maintain market running. He said that this year, the external environment for non-ferrous metal industry development is still very complicated, so we should correctly understand the current situation and grasp any chance for increasing scientific and technological innovation, promoting industrial upgrading. He asked CTIA (China Tungsten Industry Association) should strengthen self-discipline and in-depth research firmly the principal contradiction and hot issues of tungsten industry. Besides, they should operate innovation activities for government, industries and enterprises development. The first Secretary-General Liu Liangxian introduced the tungsten industry economic performance of this year and the china tungsten industry 13th five years development plan (draft).

The meeting considered the resolution of council member adjustment. The meeting agreed Lianpingxian zhujiang kuangye co., Ltd. general manager Ma Songgui to succeed Zhang Zheng, Wendeng, Wendeng Zhengxing Tungsten Industry Co. chairman Gong Shaohua to succeed Liu Yuxin, and Ganzhou Gannan Tungsten Industry Co., Ltd. general manager Zhu Bo to succeed Qi Shen.

The meeting also considered the resolution of development members and the withdrawal the membership and agreed to develop Ganzhou Haichuang Tungsten Industry Co., Ltd., Comin Ganzhou Nonferrous Metal Materials Co., Ltd. as member of the CTIA, respectively anchored smelting branch. On the other hand, there are three companies want to withdraw the membership, including Zhuzhou Lizhou Cemented Carbide Co., Ltd., Changsha Huaxin alloy Electric Engineering Co., Ltd., Shanghai tool works Co., Ltd.. Further, the meeting also approved the China tungsten industry 13th five years development plan.

The meeting discussed the tungsten industry current situation and exchanges the market information. The participants agreed that this year the tungsten concentrate production will significant decrease and the companies who produced tungsten finished products inventories remain at low level. Besides, the end demand overall is getting better. After the meeting, many tungsten companies agree to strengthen coordination and communication, to prevent and control common risk, and continue to take control of production, reducing production, reducing sales, increase business purchase and storage and other measures for tungsten market healthy and stable development.

During the meeting, Guangdong, Chaozhou, Secretary of municipal party committee Li Shuihua met with CTIA chairman Chen Quanxuan and other representatives participating in the conference. Li Shuihua introduced Chaozhou economic and social development situation, hoping China Nonferrous Metals Industry Association can play an important role for industry stable development, providing advanced resources and information and as a bridge for industry member to communication. In addition, in industrial level, technology introduction, marketing and other aspects it can give Chaozhou non-ferrous metals industry more help. Chen Quanxun said that in recent years Chaozhou has made great achievements in accelerating urban development, promoting industrial restructuring and upgrading and other fields. China non-ferrous metal industry should better learn from the advanced experience of the all around the country, focusing on strengthening concept innovation and technological innovation, promoting recycling of resources for industry development to break a new path. CTIA and non-ferrous Tungsten Industry Association will serve as a bridge to promote associations and related enterprises to strengthen the cooperation with the Chaozhou, to promote Chaozhou economic development.

Tungsten market: many manufactures of tungsten finished products willing to hold the price of tungsten finished products at the high level to make tungsten market health and stable development, but the price does not rise and the market doesn’t recovery; tungsten raw materials and tungsten finished products price continues to fall down slight and many buyer want to wait for market recover, so the transaction activity is low.

Rare Earth Market: in this week the rare earth market is running smoothly, many businesses continue to wait and there is not significant adjustment on rare earth price. Many manufacturers expected that the State Reserve Bureau plan will make the price go up, so they reluctant to sale the product at low price. Besides, the finished product manufacturers have low willing for stock up. The market is unstable, so many buyers can not make a decision for purchasing and still want to wait and see until the market is clear.

China Tungsten Industry Association

 

 

Tungsten Trioxide Denitration Catalyst - Air Pollution Controlling Sharp Weapon

Currently, flue gas dust removal, desulfurization, denitrification are the three business segments in air pollution control, the survey statistics of Commercial Industrial Research Institute shows that in 2015, China's desulfurization and denitration industry needs scale over 90 billion RMB, of which the new market capacity is more than 400 billion, and the market of transformation capacity is more than 50 billion RMB, also with the national standards of air pollution regulations becoming more stringent, the next 5--10 years will be the key period for China's air pollution control, the increase of market capacity will continue to be at about 10% .
 
Premier Li Keqiang in his government work report made, 50,000 units of small coal-fired boilers will be eliminated in the end of "12th Five-Year", the transformation desulfurization of 15 million kilowatts of the coal-fired power plant will be promoted, and denitrification transformation of 130 million kilowatts, 180 million kilowatts dust transformation. According to the State Council issued the "2014--2015 Annual Energy Saving And Emission Reduction Carbon Development Action Plan", during the remainder period of  "12th Five-Year", the desulfurization and denitrification projects will be continually promoted, and denitrification transformation of 300 million kilowatts coal-fired units should be done, 250 million kilowatts burning coal flue gas unit should remove bypass, 40,000 square meters of steel sintering machine to install desulphurization facilities, 600 million tons of clinker production capacity of cement production line installed denitration facilities.

analysis and prediction of china desulfurization and denitration industry market in 2010-2020
Wherein, the first, second and third column respectively on behalf of desulfurization and denitration market size, the new market capacity and the transformation market capacity, the unit is all one hundred million RMB.
 
SCR denitration system is widely recognized as the most effective, universal application of denitrification technology. In the current background of full swing flue gas denitrification project settings and renovation project, tungsten trioxide denitration catalyst as the core technology of SCR system, its application prospect is very bright. Tungsten trioxide mainly plays the roles of anti-sulfide, poisoning resistance, and enhance the ability of anti-sintering carrier itself ect. in the denitration catalyst; in addition, due to the cheap price of tungsten trioxide (compared to Au, Pt and other precious metals), tungsten trioxide denitration catalyst as a sharp weapon is expected to become the "Blue-Eyed Boy" of air pollution governance.

 

Nano Tungsten Carbide Has Some Difficulties in Industrialization

Compared with tungsten carbide material with common grains (micron scale), nano-crystalline tungsten carbide has remarkable improvements in density, hardness, fracture toughness and wear resistance, etc. This is due to the grain size reaches nano scale, the volume of the grain decreases, the specific surface area becomes larger, the arrangement of atoms on the interface relative out of order, it will immigrate easily under deformation external interference and the material shows excellent toughness and ductility. Especially in nano tungsten carbide cutting tools, nano-scale microstructure phase due to the size effect, the grain boundary area increases, anti-crack propagation resistance improved, which is beneficial for obtaining excellent mechanical properties and machinability.

However, since the difficulties in manufacturing process, higher cost and nano grains grow easily in the process of sintering, tungsten carbide less than 100nm can not reach the level of industrial production. So the researchers have found that add nano grains in tungsten carbide matrix with fine grains, it can effectively improve the hardness and toughness of the matrix materials. Now the enterprises use nano composite reinforced method to improve the properties of tungsten carbide material with fine grains. The principle of nano tungsten carbide composite strengthening mechanism is nano grain dispersed in the matrix has dispersed toughening effect. When added to a high elastic modulus of the matrix material in the second phase particles (nano particles), these particles in the matrix material by stretching action will prevent the transverse cross-section contraction, but to achieve the same substrate transverse shrinkage, the increase in the large longitudinal tensile stress, so that the material can consume more energy, toughening effect works. At the same time, high modulus particles crack can act as a "pinning" effect, so that the crack deflection, deviation, thereby dissipating power forward crack, so the toughening effect works. In addition, the dispersed nano grains in tungsten carbide matrix can inhibit the growth of carbide grains during the sintering process and greatly improve the mechanical properties of tungsten carbide materials.

nano tungsten carbide mills

 

China Developed High-Capacity, Fast-Charge, Electrochromic Battery Uses Tungsten Oxide

Recently, China has developed a high-capacity, fast charging electrochromic battery. In this type of battery, tungsten oxide (WO2.72, i.e. violet tungsten oxide) nano-wires are taken as a positive electrode, and the metal aluminum is as the negative electrode; compared with other batteries, this kind of cell has some new advantages in the following aspects:
1. It establishes a capacity to identify of interface with the users through color changing, which the specific performance is: the transparent state on behalf of the full status of the battery; when it gradually turns to blue, it means the storage power starts to consume; and when the color reaches the deepest, it says the power is depleted;
2. By adding a trace amount of hydrogen peroxide, it can realize fast charging (full charged within 8s), besides, the traditional external power supply can be used for charging, and also the oxygen in the air can be used to achieve self-charging;
3. The battery capacity is six times (or more) higher than the similar battery.

tungsten trioxide and graphene
 
Electrochromic refers to the optical properties of the material (reflectance, transmittance, absorption rate, etc.) occurs stable and reversible of the phenomenon of color changing under the applied electric field, and it appears in the reversible changing of color and transparency. Electrochromic material is divided into non-organic electrochromic material and organic electrochromic material, wherein the typical non-organic electrochromic material is tungsten trioxide. Violet tungsten oxide is a kind of functional nano material with many properties, such as photochromic, electrochromic and gasochromic, it has broad applications in a variety of sensitive element; at the same time, it is one kind of better and more economical method for preparing nanoscale and ultrafine tungsten powder. The violet tungsten oxide usually comes from the raw material of ammonium paratungstate, to generate by controlling the specific reaction conditions.
 
We all know that the battery capacity is one of the important performance indicators of the battery, with the increasing of the capacity of the battery, the charging time will also be doubled. Of course, in the face of "black technology", this is not a problem, with the rise of all kinds of fast charge technology, the charging time is considerably reduced. The electrochromic battery invented by China, which uses tungsten oxide as a positive electrode, has opened up a new path for the future development of battery.

 

 

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