Foreign Carbide Circular Blade Industry Focus on Brand Building

Tungsten carbide circular blade is a kind of super-hard composite material that mainly composed of refractory metal compound and the binder metal fabricated by PM (Powder Metallurgy). Due to it has many advantages, such as high hardness, high strength, excellent wear and corrosion resistance and is able to keep better performance at high temperature, etc, which becomes indispensable in cutting tool materials. Its appearance was circular, with a hole in the middle for easy fixing, generally used for the equipment cutting, trimming and other operations. According to the shape of the circular blade, it can be specifically divided into flat edge, sharp edge, and irregular edge. Conventional carbide circular blade size diameter φ300-1000mm, thickness 0.5-300mm, common in many industries slitting blades, such as paper making, paper products processing, adhesive tape products, films, wire and cable, rubber, aluminum, chemical fiber , non-manufacturing cloth, composite packaging materials, telecommunications appliances, cigarettes, leather, printing, food, clothing and other industries.

Since tungsten carbide circular blade has many advantages, domestic enterprises also works on that. However, They stressed by low prices, the price war to attract customers, which to some extent led to the cutting tool market vicious competition, low prices can not guarantee the quality of products, but ultimately customers on the domestic carbide circular blade lose confidence, a huge loss of customers caused. Take automobile industry as an example, it has higher requirements on the efficiency and service life of cutting tools. In order to avoid change blades cause the entire production line shut down and causing huge economic losses, usually mandatory unified tool change mode, if the blade quality problems, will affect the entire batch of products. By comparison, foreign tungsten carbide circular blade industries more focus on the brand building, and set the quality and the requirements of customers as first place, which build good foundation for the developments. In aerospace, military aspects of the field of production parts, molds and some large turbines, steam turbines, generators, and its not only high precision machining, material is also difficult to process (such as high temperature alloys, nickel-titanium alloy), high-quality carbide circular blade can perfectly meet the needs.

tungsten carbide circular blade

 

Tungsten Trioxide Denitration Catalyst Regeneration Technology

Recently, the State Environmental Protection Bureau delegation went to Jiangsu, Shanghai investigagion selective catalytic reduction denitration catalyst recycling and subsequent disposal. The study is mainly to promote the selective catalytic reduction denitration resource utilization and safe disposal of the catalyst after elimination, rational planning its whereabouts, thus to reduce the running cost of environmental protection, resolve the environmental issues.

tungsten trioxide and denitration system
 
Denitration system has already become an important part of coal-fired power plant, wherein the tungsten trioxide denitration catalyst is the core part of SCR system which takes the higher proportion of total investment. Currently, the denitration catalyst commonly used in the market are based on titanium dioxide as the carrier, vanadium pentoxide as the main active ingredient, tungsten trioxide (and / or molybdenum trioxide) as the anti-oxidant, anti-sulfide, anti-toxic auxiliary component. Theoretically, as the catalyst, it doesn’t as a reactant and cannot be consumed, so its effect is supposed to be permanent. However, in China, the catalyst market is now really staying in a relatively chaotic situation; usually, the catalyst will be deactivation after about three years. The main reasons which cause catalyst deactivation are sintering, poisoning, intoxication, calcium, alkali metal poisoning, and poisoning of sulfur trioxide, and the voids plug fouling of catalyst, ect..
 
The regeneration or replacement of denitration catalyst will directly affect the running costs of the SCR system, therefore, the research on SCR catalyst deactivation and regeneration has an important practical significance. In practical applications, the regeneration techniques of failure tungsten trioxide denitration catalyst are generally the two kinds of live regeneration and plant regeneration. Since the site regeneration will pollute the around environment and water quality of the plant, also the quality and performance of catalyst which regenerated in the site are poor, and therefore, plant regeneration is the development direction. SCR catalyst is impregnated plant regeneration during a series of cleaning, ash removal, ultrasonic treatment, the active ingredient (vanadium, tungsten, molybdenum, etc.), and finally achieve the goal of restoring catalyst activity.

 

Defects of Large Tungsten Carbide Products in China

Theoretically, tungsten carbide is a kind of super-hard material that consists of refractory metal carbides and binder phase metal and manufactured by PM (Powder Metallurgy). And at the time of cemented carbide industry has just started, most of which are made of tungsten carbide WC and cobalt Co composition, referred to as tungsten carbide cobalt. Since WC-Co has simple structure, high hardness and excellent wear and corrosion resistance, it can be widely used in cutting, drilling, molding and other industries. Besides, tungsten carbide also includes WC-TiC-Co carbides, WC-TiC / TaC / NbC-Co carbides, steel bonded carbides and so on. Common tungsten carbide grades are YG3, YG6, YG8, YG10, YG12, YG15, YG20, YT15, etc, each grade due to the different ratio of WC and Co, with different performance advantages, some suitable for semi-finishing of non-ferrous metals and alloys, some iron alloy suitable for high-speed milling, some suitable for steel forgings, stampings and castings the surface finish.

Although tungsten carbide plays an important role in cutting tools, drilling tools and molding materials because of the excellent wear resistance and toughness, compared with higher hardness of diamond products, it has begun to face the danger of being substituted in some applications. Diamond is a mineral composed of pure carbon, which is the hardest substance in nature. There is little diamond in nature, so people through high temperature and pressure to convert the carbon into diamond nowadays. This synthetic diamond has higher hardness and better performance in strength, nearly a decade of development in our country very rapidly, particularly in some of the cutting tools and handicraft industries are becoming more common. In addition, diamond is also known as super-abrasive in stone, construction, industrial processing, aerospace, electronics, precision measuring instruments and other fields. Currently, due to the rapid development of the diamond industry, it is growing at a high speed to produce a lot of new diamond tools, some far more than conventional carbide tools in performance. Especially domestic priority level of technology and equipment, mainly in small and medium sized carbide rod and plate-based, there some defects in the large carbide products, which is the focus of the future is the development of domestic carbide industry.

tungsten carbide products

 

Tungsten Trioxide Denitration Catalyst Creates a Myth of Clean Diesel Technology

Recently, a report said Volkswagen had altered diesel engines to beat emissions tests, which immediately caused the great anger of the consumers. The agency reported that some diesel powered vehicles made by Volkswagen and its subsidiaries Audi and Porsche contained software which can lower the emissions during tests; however, during the normal driving, the software has gone. On the discharge gate event, Mullen, the CEO of Volkswagen expressed they had especially tough to come through the past few months. On the road, the emissions of some vehicles can even reach up to 40 times as much NOx—a combination of nitric oxide and nitrogen dioxide—as allowed, which has caused enormous pressure on the environment protection.

Volkswagen CEO Murren denitration catalyst
 
In the atmosphere, nitrogen dioxide contributes to the formation of ground-level ozone and particulate matter, which create further negative health effects. A recent study estimated that the excess NOx can cause the additional unexpected deaths and damages compared with the regular emissions. In Europe, however, the excess NOx from the altered cars may have little impact, which shows the high NOx emissions have already upset the region, because it has weaker emissions regulations and more diesel powered cars. So the issue of balancing the NOx emissions control with fuel efficiency is a tough nut to crack.
 
In addition, the exhaust of diesel powered vehicles contains a lot of sulfur, which not only causes air pollution, but also causes the poisoning of the denitration catalyst for automotive exhaust gas, and influence the effect of exhaust treatment. Tungsten trioxide denitration catalyst makes the clean diesel technology not a myth. Since tungsten trioxide can improve the sulfidation resistance of the catalyst, it is widely used in the denitration catalyst. In addition, tungsten trioxide can also broaden the operating temperature of the catalyst, and make it suitable for the denitration catalyst under lean burn conditions; therefore, the denitration catalyst which contains tungsten trioxide has very broad prospect in the clean fuel technologies.

 

Technological Innovation of Shizhuyuan Promotes Development of Tungsten Heater

Recently, the school enterprise cooperation project team of multi metal concentrator of Hunan Shizhuyuan Nonferrous Metals Co., Ltd. and Central South University transform the process flow of tungsten mineral processing, primarily through technological innovation and other means to improve the grade of tungsten concentrates and the recovery rate of tungsten. Reversing the downturn situation of tungsten industry recently. Multi metal concentrator of Hunan Shizhuyuan began to flotation separation test at the end of 2014, using the original wolframite slime idle flotation device. After testing more than five months, recovery and grade of tungsten have been greatly improved, this can be applied in practical production.

After getting good results, this plant promote technology to 2000 tons / day workshop tungsten roughing in August 2015, after technicians careful debugging for a period, the whole plant rougher tungsten segment has a stable milling of ores indicators. In order to further improve the efficiency of new technology tungsten beneficiation experiments, the technicians began a 24-hour spell line system from 2016, monitoring the experimental dynamic of index in real time. As a raw material of tungsten heater, constantly improve the beneficiation process of tungsten can not only improve the quality of products, but also ensure that supply number.

The development of innovative technology also improves the recovery rate, so that resources can be repeated used, which is good for the protection of the environment and greatly reduce production costs. The successful case of this plant plays a leading role on chinese tungsten industry, which is a revolutionary breakthrough in the field of mineral processing of tungsten, and promotes the development of related industries. In the fierce market competition, enterprises are facing a number of random changes. Enterprises can inspire the original and potential innovation vitality only to make innovations constantly that can brings abundant profit.

Shizhuyuan and tungsten heater

 

 

WeChat