Salts of Tungstic Acid-IV

The normal tungstates of the alkali metals are usually obtained by fusing together tungstic anhydride and the alkali hydroxide or carbonate in equivalent proportions. Those of the heavier metals are produced either by double decomposition in solution, or by fusing together an alkali tungstate and the chloride of the metal, often in the presence of sodium chloride. The tungstates of the alkali metals and of magnesium are soluble in water, those of other metals being insoluble, or only slightly soluble, not only in water but also in dilute acids. Concentrated mineral acids (except phosphoric acid) decompose them, with separation of tungstic acid. In this reaction the paratungstates behave similarly, whereas the metatungstates are not decomposed.


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