APT Affect Extracting Tungsten from Scheelite

Ammonium paratungstate(APT) is a white crystalline salt of ammonium and tungsten, with the chemical formula (NH4)10(H2W12O42)·4H2O.A method for extracting tungsten from scheelite, the method comprising the steps of: 1) adding a mixed acid comprising sulfuric acid and phosphoric acid into a decomposition reactor, the mixed acid comprising 150-500g/L of H2SO4 and 15-35 wt. % of P2O5; 2) heating the mixed acid to a temperature of 70-100°C.; adding scheelite to the decomposition reactor and controlling a liquid-solid ratio at 3:1-8:1L/kg; allowing components in the decomposition reactor for reaction for 1-6 h, and filtering to obtain a filtrate; 3) supplementing the filtrate with sulfuric acid consumed in the reaction; 4) crystallizing the filtrate to obtain phosphotungstic acid crystals and mother liquor; 5) dissolving the phosphotungstic acid crystals in water to obtain a phosphotungstic acid solution; 6) transforming the phosphotungstic acid solution to an ammonium tungstate solution for preparing ammonium paratungstate (APT); and 7) supplementing the mother liquor with phosphoric acid and water to an initial level and returning the mother liquor for ore leaching.

 

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