New Tungsten Alloy Preparation Process

The traditional preparation of tungsten alloys is mostly based on sintering technology, which leads to a series of problems such as low densification, uneven microstructure and limited composition of tungsten-based alloys. It is mainly reflected in the slow preparation speed, low efficiency and high preparation cost.

Recently, researchers such as Chen Yixiang and Guo Shibin of the Chinese Academy of Sciences have developed a new process for preparing tungsten alloys. The method is to dry the raw materials of tungsten-based alloys after wet grinding, shape the compacts, and then ignite them in a hypergravity reactor to produce tungsten-based alloys. The preparation includes:

1) Choose the following raw materials
The experimental materials used are: Al powder (purity 99.9%, average particle size 100 micron), W powder (purity 99.9%, average particle size 2.6-5 micron), Fe₂O₃ (purity 99.99%, average particle size less than 45 micron), NiO (purity 99.99%, average particle size about 20 nanometer); raw materials are prepared according to the W₇Ni₃;Fe alloy composition (molar ratio W:Ni:Fe=40:7:3).

2) Raw material pretreatment
After wet grinding, the raw materials are dried and compacted to form the reactant body.

3) Reaction
In step 2, the reactant body is loaded into the graphite crucible, the graphite crucible is put into the reactor of the high gravity melting and casting device, and the reaction is initiated by vacuum extraction and ignition under the high gravity condition; the vacuum degree reached after vacuum extraction in the high gravity reactor is less than 200 Pa; the supergravity condition in the high gravity reactor is that the supergravity coefficient is more than 500 G;

4) Post processing
After the reaction is completed in step 3, the graphite crucible is cooled and removed. The product in the crucible is cut off to remove the ceramic layer containing Al₂O₃. After grinding and polishing, the tungsten alloy product is obtained, which is 40W₇Ni₃Fe product.

The tungsten-based alloys prepared by the new process have the advantages of fast speed, short reaction time, high efficiency and low cost. The tungsten-based alloys have a series of special properties and can be widely used in energy, metallurgy, electronic information, mechanical processing, aerospace, national defense, military and nuclear industries.

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