Tungsten Copper Electrode New Process

With the rapid development of EDM (Electrical Discharge Machining) industry, it has higher and higher requirements for the used electrode. Both tungsten copper with high content of W (mass fraction of W reaches 50%-90%) and tungsten copper with high content of Cu (mass fraction of Cu reaches 60%-90%), the most widely used are mixing method and infiltration method. Theoretically, the mixing method has simple operations and can fabricate tungsten copper products with any ratio of W and Cu. But the powder grain of raw material by this kind of conventional process is too large and the density distribution is uneven, which is difficult to fabricate tungsten copper electrode with compact structure after pressing and sintering process.

While the infiltration process is suitable to fabricate tungsten copper with 8%-40% content of Cu, tungsten skeleton infiltrated by copper in molten state to obtain the densification. Although the infiltration process is the most widely used in tungsten copper electrode now and it has stable working properties, it also has some problems, such as many controlling parameters, difficulties in porosity controlling, difficulties in porosity distribution and so on. So the relevant scholars and researches have further explosion surrounding the raw material preparation and molding process in recent years. Some new technology has gradually developed, which is more practical and operational effects are:

1. Pre-alloying: Its powder refinement and even micro-alloying, so as to achieve increased activity and split the purpose of promoting densification by mechanical and high energy ball milling;

2. Ultrafine particle / nano powder: By the addition of grain growth inhibitors, high-energy ball milling, adding elements and changing the material of the powder form and other methods to refine, even to the nanometer level;

3. Thermoforming: it is pre-loaded with a good blend in the mold cavity, rapid molding under heat and pressure to achieve integration and briquettes pressed sintered compact so as to achieve the densification effect;

tungsten copper electrode

 

Diesel Engined Car Exhaust WO3 Denitration Catalyst

diesel engined car exhaust WO3 denitration catalystOxide catalyst is mainly the vanadium based catalyst, and adding co-agents like tungsten trioxide, such kind of catalyst has a high NOx removal efficiency in the temperature range of 300-400°C with excellent stability. In the past, the catalyst of diesel engined car exhaust is primarily the noble metal catalyst, but its application is limited by high cost. An invention has pointed out that a method for preparing the diesel engined car exhaust tungsten trioxide denitration catalyst which has a high catalytic activity, wide temperature window, as follows:
 
1. Calcine carrier of the titanium dioxide at 300-400°C for 2-5 hours;
2. Preparation of the active ingredient solution: dissolve the ammonium metavanadate and ammonium metatungstate in deionized water, then add the appropriate amount of oxalic acid solution and uniformly stirred, to obtain the active catalyst component solution;
3. Impregnation method to load the active component: The carrier is immersed in the calcined active component solution prepared in step 2;
4. Natural drying the catalyst obtained in step 3, then transferred to drying conditions at 80~120°C for 8~12 hours;
5. After drying, the catalyst is calcined at 300~600°C for 2 to 5 hours, then heated to 680-800°C and continually calcined for 2 to 5 hours to obtain the tungsten trioxide denitration catalyst which is suitable for diesel engined car exhaust.
Noted: wherein the carrier is titanium dioxide which takes 90-99.5% of the mass of catalyst; the main active component vanadium pentoxide takes 0.5-10%; additive- tungsten trioxide takes 0.5-10%.
 
The preparation method of this catalyst without introducing any chemical agent, just by changing the preparation process; by changing the calcining temperature to improve the distribution of the active component in the catalyst support surface, has the advantages of simple operation, excellent repeatability, easy to optimize the size and modifying the conventional catalyst.

 

WO3 Denitration Catalyst Regeneration - Bubble Flow Device Method

WO3 denitration catalystIn the running, tungsten trioxide denitration catalyst will part or entire inactivated due to the fly ash poisoning and deposition of solids ect., and end its life after a certain period of time (approximately 2 to 5 years), therefore needs to be regenerated or obsolete processed. The bubble flow device (Air Lift Loop Reactor) can recover the activity of honeycomb SCR catalyst which deactivated from heavy metal poisoning in fly ash and solids deposition pollution ect. to the activity before polluted.
 
Most honeycomb-type SCR catalysts take titanium dioxide as the carrier, with the main active ingredient of organic and inorganic binders of vanadium (1~3%) and tungsten (10-20%). Experiment uses the mixture solution of sulfuric acid, ammonium vanadate and ammonium paratungstate to carry out the catalyst regeneration by bubble flow device, which the steps are showed as bellows.
 
1. Install the inactivated tungsten trioxide denitration catalyst in the bubble flow device, then washing for about 1 hour with the mixture solution of sulfuric acid which generated by pure water at room temperature, ammonium vanadate and ammonium paratungstate;
2. Dry the washed catalyst at a high temperature of 200°C in the air;
3. Calcined to obtain the regenerated tungsten trioxide denitration catalyst.
 
Remarks:
1. When weight content of the active ingredient- vanadium pentoxide less than 1.0%, the NOx removal rate is very low; however, when it reaches 10% or more, the NOx removal will decline rapidly at the high temperatures above 400°C, and promote the oxidation of sulfur dioxide, therefore, the selection of ammonium vanadate solution shall base on the vanadium pentoxide content which is controlled among 1.0~10%.
2. When the content of active ingredient- tungsten is higher than 20%, the oxidation of sulfur dioxide will be promoted, and the price is very expensive, therefore, the selection of appropriate concentration of ammonium paratungstate solution will be suggested to the economic.

 

What Is Stamping Tungsten Boat?

Stamping is also divided into forging, ginning, combining and other types. Processing of iron can be referred to as punching. Conventional press working method is cut, bent, twist. Also there are a variety of molds, including plastic, rubber molds, glass molds. Stamping dies are used for stamping, including arbitration die, progressive die, compound die, precision die, drawing die, bending die, molding, die cutting and other types of stamping dies, according to the differences of the finished product, users can choose different stamping dies.

At the beginning of it, tungsten plate should be blended into a certain angle, or bending the blended workpiece again. After that, it should be pressed into any hollow shape by mould, or bending the hollow mould workpiece further deformation. Afterward the hole or the outer edge of tungsten plate should be folded into a straight wall by mould. Forcing an outward radial force on the hollow member by mould, so that the local diameter can be expanded. After expansion, pressing the outside-in radial pressure on the hollow member so to narrow the local diameter. Next, putting the bloom into the die cavity, squeeze it out from the gap of mould to form the hollow or solid workpiece. Roll the panel into a ball peen whose shape approximate to a close one. Finally, press the bended or stretched workpiece into a right stamping tungsten boat shape.

The main features of the stamping W-boat is the high rate of final products. Because that this type of W-boat stamping tungsten boatadopting the stamping equipment and stamping mould, the accuracy of size and shape the stamping wolfram crucible are much higher. What’s more, it has a long life time and it is not easily to be damaged, therefore, the shape of the stamping tungsten boat from the same production batch is almost the same whose quality is also stable. However, during the stamping process, the device will produce noise and vibration which would have a great influence on operators. Furthermore, the mould is an essential material for stamping process, so the quality of the mould determines the quality of the W-boat.

Surface and internal performance of panel have a great impact on the quality of the finished product by stamping, it requires that the thickness of stamping material should be precise and without any spots, scars, bruises, surface cracks.

AJ Carbon Sulfur Analyzer and Tungsten Granule

Jena Analytik Jena AG brand, called AJ, was established in 1990 in Germany, which is evolved by Carl Zeiss Carl -Zeiss Jena GmbH. Nowadays, AJ carbon sulfur analyzer has become one of the most popular brands of analytical instruments in Germany. The brand is mainly focus on the development, design and manufacturing of total organic carbon (TOC) / total nitrogen (TN) analyzers, organic halogen compounds (AOX) analyzer elements (C, S, N, Cl) analyzer, atomic absorption spectrometer (AAS), ICP-OES emission spectrometers, inductively coupled plasma mass spectrometry and UV / visible (UV / VIS) light meter points and biochemical analytical instruments. Analytik Jena is a provider of analytical measuring technology, and life science instruments. With its core expertise in optical spectroscopy and elemental analysis its portfolio includes analytical systems for qualitative and quantitative analysis of liquids, solids, and gases. 

Multi EA S® 5000 Elemental Analyzer is launched by AJ brand in 2008, which is a kind of multi-element professional analysis system for the analysis of total nitrogen, total carbon, total sulfur, total chlorine content of a variety of gaseous, liquid, LPG, solid samples. The instrument has many excellent features. Tungsten granule is used as the mainly flux, which can the accelerate reaction rate for the analysis process, shortening the time of determination. Its appearance and structure design is the main attraction, users can select the elements to be analyzed and the corresponding detector.

In the software you can choose to switch carbon and sulfur analysis, without any mechanical conversion. In addition, AJ carbon sulfur analyzer is a lightweight instrument, which does not require any maintenance vertical injector and a vertical furnace, so that it can ensure that good reproducibility of the instrument. After installation is completed, it doesn’t need any manual adjustment. Voltage stabilizing system in the gas circuit is equipped to avoid the pressure fluctuations while detecting. Any parameters of instrument are set and optimized and controlled by computer, which has the characteristics of full intelligence and full automation. Because the instrument has a heated filter device, there is no need for membrane dryers and detection system to be maintained repeatedly, which can greatly reduce operating costs.

tungsten granule and AJ carbon sulfur analyzer

Annealing Effect on Tungsten Bronze Niobate Dielectric Properties

Dielectric constant and loss changes with frequency of both unannealed and annealed Ba4Nd2Fe2Nb8O30 ceramics is shown in Fig. The dielectric constant of all samples increase with frequency decreases, which is due to the low frequency, there area variety of different mechanisms of polarization like electron polarization, ionic polarization, dipole orientation polarization, space charge polarization and spontaneous polarization in niobate ferroelectric, while as the frequency rises, some of the slow polarization mechanisms such as space charge polarization will be gradually too late to reverse, leading to its disappearance, thus reducing the dielectric constant.
 
When the frequency changes from 1kHz to 1MHz, the relative dielectric constant ε of Ba4Nd2Fe2Nb8O30 ceramic without annealing treatment is reduced from 179 to 143, the dielectric loss tanδ reduced from 0.088 to 0.021. When Ba4Nd2Fe2Nb8O30 ceramics annealing in the oxygen atmosphere, there is a similar variation, the relative permittivity ε reduced from 168 to 137, the dielectric loss tanδ reduced from 0.17 to 0.016.
 
However, compared with the unannealed situation, Ba4Nd2Fe2Nb8O30 ceramic annealed in the nitrogen atmosphere, the relative dielectric constant increases rapidly from 179 to 5000 (1kHz). When the frequency changes from 1kHz to 1MHz, the relative dielectric constant quickly dropped from 5000 to 140. Over the entire frequency range, dielectric loss tanδ has always been huge, when the frequency at 1kHz to 10kHz, there has been a loss peak. This phenomenon is typical spatial charge polarization. After the annealing treatment in the nitrogen atmosphere, the oxygen vacancies of Ba4Nd2Fe2Nb8O30 ceramic increased significantly, resulting in conductivity ceramics decreased, thereby greatly enhancing the space of charge polarization, resulting in dielectric constant surge, and dielectric loss peak appeared at the corresponding frequency. The changes of dielectric properties indicates that the oxygen vacancies have a significant impact on dielectric properties of tungsten bronze niobate ceramics.

dielectric constant and dielectric loss

Tungsten Alloy Shielding For Nuclear Electricity Generation

Tungsten Alloy Shielding For Nuclear Electricity GenerationNuclear electricity generation is the use of fissile materials in nuclear reactors (such as uranium-235, plutonium-239, uranium-233, etc.) that release thermal energy by nuclear fission to generate electricity. Nuclear fission is a radioactive decay process in which the nucleus of an atom splits into smaller parts. The fission process often produces free neutrons and gamma photons, and releases a very large amount of energy. A nuclear chain reaction occurs when one single nuclear reaction causes an average of one or more subsequent nuclear reactions, thus leading to the possibility of a self-propagating series of these reactions. Nuclear chain reaction is the precondition of nuclear electricity generation. Compared with thermal power generation, which uses thermal energy generated by the combustion of chemical fuels to generate electricity, the heat energy released from the nuclear reactor is much higher than that released from the combustion of fossil fuels, while the volume of fuels required is much less.

Fission fragment which is generated when the nuclear fission of nuclear fuels is radionuclide that will occur a series of decay with strong radioactivity (mainly are β-ray and γ-ray). β ray is a high-energy, high-speed electron or positron, whose penetrating power is stronger than α-ray. When it penetrates the skin, it can cause radiation injury. And when it enters the body, it will change the chemical balance of cells, causing cells to become cancerous and the genetic material DNA to be damaged; the penetrating power of γ-ray is also very strong, it can enter into human body to interact with cells in vivo, to damage the molecular components of living cells (such as proteins, nucleic acids and enzymes), leading the body's normal chemical processes to get disturbed, thus causing harm to humans. Neutron radiation emitted by nuclear reactor also has manifested the very strong lethality, it can cause organ failure, central nervous system and digestive system damage.

Tungsten alloy shielding can be used for shielding the radiation released from the process of nuclear electricity generation. Experts find that radiation exposure could be reduced by maxing shielding. The radiation shielding ability of a material is related to its density. Higher density means better radiation shielding ability. Due to a higher density, tungsten heavy alloy has a much higher radiation shielding ability than lead. Alternatively equal amounts of tungsten alloy shielding provide diminished exposure risks than equivalent lead shielding. 

 

Energy Consumption and Metabolic of Tungsten Darts Sport

There is the process of energy supply of aerobic and anaerobic metabolism in every sport, and tungsten darts sport is a sport of energy supply of aerobic metabolism, which requires athletes to have good aerobic endurance qualities. The so-called aerobic metabolism for energy simply refers to the process of fat, carbohydrate and protein oxidation produce water and carbon dioxide in the participation of oxygen, this is called aerobic metabolism. Aerobic metabolism released energy and synthesized of ATP, and constituted skeletal muscle aerobic energy supply system. Because many professional athletes of tungsten darts sport are often in a low-intensity, long training status, so their stamina and energy consumption are all huge.
 
Due to long time bated breath during tungsten darts sport training; there will appear the energy supply of anaerobic metabolism circumstances caused by body hypoxia. But in fact this is not because of the high strength and high output power, but because of the lack of oxygen caused by the body in a short time. So for the professional darts athletes, they often suffer from mental and physical fatigue after training. So in peacetime training, they should pay attention to timely supplement energy to their body. For ordinary tungsten darts sport enthusiasts, the appropriate exercise time may train you to centralize your spirit, while going on an aerobic-metabolism process. So for many people who are too painful to do bodybuilding, tungsten darts sport would be a best project for you to do exercise.
tungsten darts

SCR Denitration Catalyst Recovers Tungsten Trioxide

low temp ultra SCR catalyst Currently, working life of SCR denitration catalyst is generally 3~5 years, the commonly treatment ways of the deactivated catalyst are regenerating or landfill. Landfill will not only result in the occupation of land resources, but also a tremendous waste of resources. According to statistics, by 2018, it will produce annually 38,000 tons of waste SCR denitration catalyst, which contains 1520 tons of tungsten trioxide. Because tungsten is a rare metal and the very high price of tungsten trioxide, if the waste SCR catalyst can’t get reasonable treatment and the valuable resources can’t be recovered, the great waste of resources will cause.
 
Simple method for recovering tungsten trioxide from SCR denitration catalyst is as following:
1. Crushing the tungsten trioxide contained waste SCR denitration catalyst into dry powder, and calcining under a high temperature;
2. Add the waste SCR denitration catalyst and ammonia in a sealed reactor and heated to 60~180°C;
3. Stand until the liquid-solid layers stratified after fully dissolved (for 5~15 hours), then collect the upper layer of serum;
4. The lower layer of solid residue and ammonia are added into the reactor, heating and collect the supernatant upper layer of serum;
5. Repeat steps 3 and 4 at least once;
6. Collect the upper layer of serum of tungsten trioxide component and evaporate to dryness and water is sufficiently dried, to obtain a solid;
7. Calcining the solid obtained in the step 6 under the high-temperature (conditions: 500~800°C, roasting time for 1~5 hours) to generate tungsten trioxide, thus completing the process of waste SCR denitration catalyst recycling tungsten trioxide.
 
Using this method, the recovery rate of tungsten trioxide can ensure up to 95%, and with high purity (98.5%), which can be directly re-used for the production of SCR denitration catalyst; in addition, the waste of resource is reduced which brings the positive implications of both economic and environmental protection.

 

WO3 Desulfurization Catalyst Used for Preparing Superior Grade White Oil

desulfurization catalystWhite oil, alias paraffin oils, mineral oils, is the highly refined colorless oily liquid with odorless, and has excellent chemical and light stability. It is widely used in industries such as cosmetics, food, pharmaceutical, plastics, chemical fiber, machinery and light industry.
Hydrogenation method to prepare white oil often bases on the material of hydrocracking tail oil, and dewaxed by solvent or catalytic, and then generated by high-pressure hydrogenation nickel catalyst saturating; with the advantages of no pollution, high yield, wide source of raw materials, full product range, etc., it gets rapidly development and universal application.
 
The specific process of hydrogenation process for producing high quality white oils include: under the suitable conditions, oil feedstock and hydrogen successively go through the reaction zone which contains three catalysts, the first reaction zone packed with a hydrotreating function catalyst, the second reaction zone loaded with the pour function catalyst, and the third reactor zone packed with a hydrogenation saturation function catalyst. The packing volume ratio of catalysts in three reaction zones can be 0.2~0.6:0.2~0.6. Reaction conditions: temperature 220~360 ℃; hydrogen partial pressure of 2.0~16.0MPa; the liquid hourly space velocity is 0.2~3.0 hours; the ratio of hydrogen and oil is 120~1000.
 
The three catalysts are:
1. Pre-hydrogenation refining catalyst, the aluminum oxide as carrier adding with other refractory oxide, the main components: cobalt oxide or nickel oxide, 15 ~ 40wt% of tungsten trioxide or molybdenum oxide;
2. The high activity of hydrodewaxing catalyst, which contains 3~25% of tungsten trioxide, 2-10% of molybdenum trioxide, 1-10% of nickel oxide, 1-8% of zinc oxide, 1-10% of tin oxide;
3. The high activity hydrofinishing catalyst, which the content of cobalt oxide or nickel oxide is 2~10wt%; content of tungsten trioxide is 15 ~ 40wt%.

 

 

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