2016 Green Technology and Device Negotiation holds, Tungsten Trioxide Denitration Catalyst Governs Optical Smoke

denitration catalyst and optical smokeBecause the environmental situation of China's petroleum and chemical industry is extremely serious, especially oil refining, coal chemicals, pesticides and other key industries, they are faced with recycling high concentrations of waste water, zero liquid discharge, dangerous to handle volatile organic gases and other environmental protection technical problems. The environmental problems have gradually become the biggest bottleneck in the development of chemical industry park, the park's pollution control and comprehensive management has come to a critical moment. To promote the application of advanced environmental protection technology and equipment in the oil and chemical industries, as well as to build a contact platform for equipment manufacturers and petroleum & chemical industry, in June this year, Beijing will hold the 2016 China's petroleum and chemical industry environmental technology and equipment supply and demand negotiation. The meeting will include: flue gas purification and sulfur recovery technology and engineering topics; high concentration organic wastewater treatment and zero liquid discharge thematic; VOCs and odorous gas treatment and other topics.
 
NOx is a major source of air pollution, the large number of NOx discharging directly into the atmosphere not only cause photochemical smog, but also result in acid rain, which corrodes buildings, damages vegetation, injuries personal and so on. The most effective method for removing NOx is SCR, which takes tungsten trioxide denitration catalyst as the core technology. Tungsten trioxide is an important intermediate state compound in the tungsten metallurgical industry, and a large number of it used in the preparation of tungsten powder, tungsten carbide, etc; Meanwhile, because tungsten trioxide has the capabilities of anti-curing, anti-sintering of carrier, it greatly enhances the performance of SCR denitration catalyst, thereby to improve the denitration efficiency.
 
With the continuous improvement of people's environmental awareness, environmental issues have received very much attention; and, also attached great importance to the national, the 12th Five-Year Plan of energy-saving projects has concluded the desulfurization and denitrification project in, and furthermore, thermal power, cement and steel industries are the top priority. Tungsten trioxide denitration catalyst is used in the SCR denitration projects after combustion, thus to achieve the goal of NOx removal, exhaust gas purification.

 

New Nano Photocatalyst Increased 2 Times Hydrogen Production Efficiency, Tungsten Trioxide Alternative

tungsten trioxide and molybdenum oxideNot long ago, Yi Cui research team, the American College of Materials Science and Engineering at Stanford University, designed perovskite solar powered water splitting complex system, which makes the hydrogen conversion efficiency of photolysis of water up to 6.2% (three times of the conversion efficiency by using conventional methods).Since the photocatalyst of hydrogen production from hydrolysis facing the low conversion for long-term and the stability of photocatalyst and other problems, the efficiency of the conventional method is only 2%. In order to improve the hydrogen conversion rate, the group devised a new electrode with nano-structured photocatalyst, which deposits the molybdenum-doped bismuth alumina film with the hydrolysis of the superior performance on a conductive nanocone arrays, thereby greatly enhance the light hydrolysis electrode performance. Compared to the conventional planar structure of the electrode, the electrode with nanocone array structure has a better light utilization, charge collection and other properties; at the same time, it can play a good light utilization effect at different times during the whole day.
 
Tungsten and molybdenum are elements in the same column of the periodic table, and exhibit the mostly consistent properties. Tungsten is a modern national economy and national defense irreplaceable strategic resources and basic materials, the important material for electronic power equipment manufacturing, metal materials processing, glass manufacturing, furnaces member structural component manufacturing, aerospace and defense industry, which is taken as the "Industrial Teeth". Tungsten trioxide is an important tungsten compound, which commonly used in the preparation of metal tungsten, WC, tungsten carbide, etc; in addition, because of its special property, it is widely applied in the desulfurization denitration catalyst, gas fittings, photocatalyst, and other fields.
 
Tungsten trioxide is a semiconductor catalyst, when irradiated with light energy greater than the band gap (2.4eV ~ 2.8eV), its electrons in the valence band come to transit, and generate the photo-generated electrons and holes which forma redox system, and can catalyze the hydrolysis process of producing hydrogen. The study found that some of the tungsten trioxide doped with lanthanide can improve its ability to absorb visible light, thereby improving the photocatalytic hydrogen production activity.

 

Situation Analysis of Domestic Cemented Carbide Industry

Our country plays an important role in cemented carbide industry around the world, which is one of the main countries of raw materials and manufacture. Tungsten carbide materials have many advantages, such as high hardness, high strength, good thermal-setting, excellent wear and corrosion resistance and so on, which have been widely used in modern machining tools, wear-resistant materials, corrosion-resistant and high-temperature materials, etc, especially indispensable in tungsten carbide cutting tools. Development status and problems of cemented carbide industry in our country, mainly in three aspects: total production of large, relatively low profit margin; carbide products lack comprehensive export channels; related business technology innovation development is insufficient.

Although China in terms of production of cemented carbide is far ahead in the world, but at the margin is far lower than other developed countries. The main reason is that the domestic carbide products are mainly concentrated in the low-end products; the low degree of processing, low-tech, value-added products is not high, supporting the poor, such as the number of bars, plates and so on. While foreign enterprises focus on high-performance, high-precision and high-end CNC inserts, micro drills as well as some parts of precision instrument, so the profit is dramatically increasing. In terms of export channels, our carbide products export channels the vast majority still remain in the traditional way of wholesalers and retailers a simple intermediate channels. Each member of the channel as an independent economic entity, it will be in order to maximize their own profits, difficult to form a benefit-sharing, risk-sharing marketing model. Therefore, we should adopt multi-channel marketing management according to different carbide industries; design reasonable, flexible product pricing mechanism, keeping the right balance of sales channels; Improve information management of sales channels, improve the efficiency of distribution channels, establish direct marketing system, carbide production enterprises.

tungsten carbide drills

 

LiFi Technology Successful Networking, Accelerating the Foreign Trade of Tungsten Market (Tungsten Heater)

Although the WiFi technology has become increasingly popular, but there are still exist some problems. If there are a lot of people connect a WiFi at a time, the internet speed will be very slow, and the wireless signal would become instability. What’s more, not all of places install the wireless network. For its own drawbacks of WiFi, German physicist Herald Haas and his team of the University of Edinburgh invented a patented technology that uses a bunch of flash to transmit the wireless of digital information. This technique commonly refers to visible light communication (VLC). In this way, LED bulbs can quickly transmit binary encoding. But to the naked eye, this type of flashing is not visible, only the light-sensitive receiver can detect it.

Visible light communication technology, the nickname of Li-Fi is not just improving the coverage of the Internet. As the most important technology of wireless data transfer, WiFi use radio frequency signals. However, radio wave is only a small part of the entire electromagnetic spectrum. With demand of users of wireless internet is increasing, the available radio spectrum are increasingly less. For example, when people surf the internet in a cafe, if there are more and more people use the internet, people will find that speed is very slow, which is the same as the 3G mobile networks. At the same time, according to Cisco's data, the amount of information transmitted through mobile devices is doubled every year. Data transfer rate of LiFi network is up to 1GBps, which is 100 times as quick as WiFi.

Once this technology can be improved perfectly, this will be a milestone for network information technology. The accelerating of the transmission speed of the network will help domestic enterprises, such as tungsten communicates with foreign enterprises. And it benefits domestic enterprises to get more foreign tungsten market information, which will bring good economic benefits to the world's tungsten market (tungsten heater).

Lifi and tungsten heater

China's Self-Renovation of Tungsten Trioxide Denitration Catalyst Operating Stable

Recently, China Petroleum announced the news that after the initial 168 hours of continuous and stable operation in the 1.6 million tons of the FCC flue gas denitration unit, the self-developed catalytic cracking (FCC) flue gas SCR denitrification catalyst -- PDN-102 of the Research Institute of Petrochemical has driven success at one time. The successful test marked the PetroChina has completely owned a set of FCC flue gas denitrification technology with independent intellectual property rights. It is reported that by processing with SCR denitration apparatus containing this kind of denitration catalyst, nitrogen oxides dropped from 180 ~ 350mg / mg/m3 to 50 mg / mg/m3, escape of ammonia is less than 1.5mL, various technical indicators have reached the leading China domestic level. Furthermore, after adjusting the catalyst formulation and production process, it can also be used for dry gas boiler, process furnace, coal-fired boiler and other flue gas denitrification, with good environmental and economic benefits.

SCR denitration catalyst
 
SCR (selective catalytic reduction) because of its excellent denitration effect, stable performance, is widely used in flue gas denitration, in which the denitration catalyst is the core technology. Currently denitration catalyst widely used mainly is vanadium-based catalyst, which takes vanadium pentoxide as the main active ingredient, titanium dioxide as a carrier, tungsten trioxide (and / or molybdenum trioxide) as a catalyst promoter. Wherein tungsten trioxide due to its unique properties plays the roles of anti-sulfide, anti-sintering of carrier ect. in the catalyst. In addition, tungsten trioxide has the properties of photochromic, gas sensitive, photocatalytic and so on, and has an important position in architectural glass, toxic gas detection, photocatalyst and other industries.
 
In the past, Japan, the United States and other countries monopolized the SCR denitration catalyst production technology, China denitration catalyst is mainly outsourcing, which not only makes the high cost of procurement, but also has to pay technological packages using fee. Therefore, the development of independent intellectual property rights of FCC flue gas denitration catalyst is very urgent. This time, Chinese homegrown catalytic cracking (FCC) flue gas SCR denitrification catalyst -- PDN-102 continued to run smoothly up to 7 days, which not only gave China great encouragement of independently developed passion, but also added some contribution for China changing towards to creative country.

 

 

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