Tungsten Trioxide Photocatalyst Eases Groundwater and Soil Pollution

On June 23rd, the fourteenth session of the Shanghai Municipal People's Congress of the thirtieth session "(Revised Draft) Shanghai Environmental Protection Ordinance" for the water pollution problem, the Committee believed that, at presently the phenomenon of secretly pouring and discharging of the production waste-water in the shipping out is quite serious, and seriously affecting the safety of drinking water. People can not live without water, the production waste-water directly discharge may not only cause groundwater pollution, but also cause serious soil pollution. In view of the current Shanghai sewage pipe network construction is quite completely, the forbidden on the production waste water treatment by shipping out has practice feasible.

photocatalyst purify water and soil pollution
 
Recently, with the soil pollution around schools and other news was broken, soil pollution has already caused public concern. Soil pollution can be divided into two categories of inorganic and organic pollutants. Inorganic pollutants include acids, alkalis, heavy metals, and radioactive elements; organic pollution is mainly organic pesticides, petroleum and urban sewage, sludge and so on. Compared to the atmosphere, water pollution, the soil problem has the properties of hidden, hysteresis, accumulation, regional and irreversibility, therefore, its governance is difficult, and requires a long term. However, I think the key in the soil pollution is the prevention, what is to say the source control. Production and domestic waste water, sludge and other emissions are the major cause of soil pollution.
 
Tungsten trioxide has a narrow band gap, can effectively respond to visible light; as a photocatalyst, it can be used to treat the polluted water which contains organic and inorganic pollutants. Studies have shown that the photocatalytic of tungsten trioxide photocatalyst can solve the problem of pollution chromium, mercury, lead and other heavy metals; moreover, it also plays an extremely high utility in COD removal and organic matter degradation of the polluted water.

 

Desulphurization Industry Continues Expand, Tungsten Trioxide Desulfurization Catalyst Market Growing

tungsten trioxide desulfurization catalystWith the more stringent standards of Chinese air pollution regulations, the next 5--10 years will be the key period for Chinese air pollution control, the growth rate of market capacity will continue to maintain of around 10%. Statistics show that, in 2015 China's air pollution control industry scale was over 130 billion RMB, of which about 18.7 billion RMB belongs to desulfurization industrial, the scale of denitration industrial was about 75 billion RMB, industrial scale of dust removal was about 430 billion RMB. In 2014, the thermal power industry desulfurization market size was 168 billion RMB, building materials, chemicals, nonferrous metals, petrochemical, and other non-thermal power desulphurization industry market size was about 54 billion RMB.
 
Judging from the emission source of sulfur, China mainly emissions the sulfur dioxide, "2015--2020 of China desulphurization industry market supply and demand forecasting and market special research report" showed that the Chinese sulfur dioxide emissions was 20.439 million tons, which reduced by 3.5% compared to the previous year. At present, the desulphurization business is mainly directly expanded to the industries of thermal power plants, steel and cement ect.. China currently has nearly 80% of the electric power is coming from thermal power which takes coal as the raw material, large amounts of harmful gases (such as sulfur dioxide, nitrogen oxides, etc.) discharged into the atmosphere through the chimney, causing the pollution of the surrounding environment, resulting in human respiratory diseases and crop failures, etc. .
 
Desulfurization and denitrification technology is the best way now available to effectively control sulfur dioxide and nitrogen oxides and other harmful gases, in which desulfurization catalyst is used as a core technology in desulfurization technology. The surface of tungsten trioxide desulfurization catalyst has tension, which can reduce the surface tension of the limestone slurry and the radius of the critical nucleus, thereby strengthening the bisulfite to be oxidized and to precipitate gypsum, thus to realize reducing emissions. Hydrodesulfurization catalyst is presently the most widely used in this industry, which is added the mainly active components of tungsten trioxide, cobalt oxide ect., and aluminum oxide as the carriers, and then prepared by drying and calcining; it plays an extremely important role in industrial gas desulfurization, diesel cracking, gasoline hydrotreating and other areas, therefore, tungsten trioxide catalyst desulfurization market will continue to expand.

 

Tungsten Trioxide Photocatalyst Helps Village Polluted Water Treatment

According to E20 Institute survey shows that, in the end of 2015, China has 607.6 million rural population, more than 2.7 million distributed in natural villages, the annual generated polluted water has amounted to about 10 billion tons. Because the village polluted water treatment facilities has the problems of ubiquitous network construction imperfect and low levels, so the rural polluted water treatment rate is still less than 10%, which means that there are still a large number of untreated polluted water random emissions. When you walk through the village enough, you will find that most of the village even has no garbage, let alone what the polluted water treatment facilities; moreover, most of the villagers believe that it is enough to discharge the polluted water and other rubbishes directly into the river and just flow them away, no more action is excess? Furthermore, this concept is widespread in the village areas. Thus, compared to the current more than 90 percent of urban polluted water treatment rate, the countryside polluted water treatment works has a long way to go; it not only requires the government pay attention to it, and strengthen the construction of infrastructure, but also, the vast and most long-term project is to deeply root the environmental protection concept in the hearts of every citizen.

waste water  treatment plant number and processing capacity change
Column on behalf of the processing capacity (unit: cubic meters/day), line graph on behalf of the number of plant
 
Experiments using photocatalyst under light conditions, to carry out photocatalytic degradation of the life wastewater, and found that due to the COD concentration domestic polluted water are low, therefore, nano photocatalyst is more suitable for processing. Tungsten trioxide photocatalyst has been shown in using for degrading organic pollutants, and play a good effect, include: degradation of pesticides, bleaching treatment, water purification and so on. Furthermore, as a catalyst, the tungsten trioxide photocatalyst itself is not consumed, and can be long-term viability.
 
The crystal structure of the tungsten trioxide is monoclinic, the photocatalytic activity caused in this state has a good effect on the responsive of visible light, and being a good performance of the photocatalyst. In particular, nano tungsten trioxide because of its large specific surface area, the surface effect is remarkable, is a good catalyst, either can be suggested as the primary catalyst, but also as the co-catalyst, and has a high selectivity on the reaction.

 

The Seventh National Congress of Nfsoc would Save Tungsten Market (Tungsten Heater)

In June 15, the seventh national congress of Nfsoc was held in Beijing. China Nonferrous Metals Industry Network reported that President Chen Quanxun said that The Nonferrous Metals Society of China (Nfsoc) is an important force in China's nonferrous metals industry. Since the Society was established, it always adhere to the principle of service, play an important role on the bridge link, science and technology think tank, leading innovation, which has won recognition and trust of companies in this filed. The current development of China's nonferrous metals industry is stagnation, and it is facing slower growth, reduced investment, decline in exports, decreased efficiency and other severe problems, in short, the recent nonferrous metals industry is experiencing difficulties, for these serious problems, the meeting put forward the corresponding measures, which will has a good promotion effect for nonferrous metals industry in the future, such as the development of tungsten market (tungsten heater).

The president Chen Quanhui emphasized that as an industry-wide science and technology academic organization, Nfsoc shoulders the sublime historical task of technological innovation, the society should lead the development of China’s nonferrous metals industry. Song Jun, who is the party member of China Association for Science and Technology and ministry of Academic department, also said that it is time to organize the good innovation activities to stimulate the create enthusiasm of science and technology workers. In addition, enterprisers themselves should innovate in, producing, marketing, service, research and development, finance, human resource, which would directly promote the development of the tungsten market (tungsten heater). Ma Xiaohe, the well-known expert and the president of the Academy of Macroeconomic Development of China, was also invited to this meeting to do the report for the current economic situation and the supply-front economics. This is undoubtedly in rescue the tungsten market in dire straits.

Nfsoc and tungsten heater

Waste Tungsten Trioxide Denitration Catalyst Included China Hazardous Waste Management

regenerated denitration catalystDuring the period of 2013 to 2015, the main dynamic development of Chinese desulfurization and denitration industry are:
(1) Environmental bursts "three gold medals", the especially emission limit helps the birth of "ultra low emission";
(2) Coal-fired power industry is still the focus and leading industry of electricity desulfurization and denitration, coal-fired power plants’ ultra-low emissions have formed a culture;
(3) Waste denitration catalyst will be included in the national hazardous waste management; moreover, the zero discharge of desulfurization wastewater has attracted attention, numbers of power plants have carried out zero discharge of wastewater;
(4) Desulfurization and denitration market expanded to non-electric industry, industrial boiler is the focus, steel, cement, and kiln ect. will be strengthen supervision, to encourage the industry with the capacity of using clean coal to use more coal, and also restrict the arbitrary use of coal.
 
According to the "National List of Hazardous Wastes", hazardous waste (form of solid or liquid) is as following:
1. Corrosive, toxic, flammable, reactive or infectious and other one or several hazardous characteristics;
2. Do not exclude hazardous properties, and may cause harmful effects on the environment or human health, which needs to be managed following hazardous waste.
 
Denitration catalyst is the core of SCR system, the current international widely used is taking vanadium pentoxide as the main active substance; titanium dioxide as the carrier; tungsten trioxide (or molybdenum trioxide) as an assistant, plays the role of anti-poison, anti-sulphuric, anti-sintering of the carriers; also adds the other adhesive components. In the running of tungsten trioxide denitration catalyst, due to fouling, abrasion, alkali metal poisoning, catalyst will cause deactivation, and affects the denitration activity.
 
Due to the abandoned denitration catalyst contains highly toxic of vanadium pentoxide, which will cause great harm to the environment and the human body, and belongs to the category of hazardous waste; if it is not been well handled, a huge potential harm will cause on the environment, and also cause a great waste of resources. Common treatment includes landfill, incineration and recycling, wherein recycling is the most promoted way, the comprehensive recycling can not only solve the pollution problem, but also making the recycling of resources (such as tungsten, vanadium, titanium and other metals) at the same time, therefore, its research has very practical significance.

 

Development of Tungsten Carbide Used for Mining

Recent years, since the development of mining and energy exploration as well as some large-scale infrastructure construction projects, tungsten carbide for mining, such as tungsten carbide buttons, bits, picks, mills, DTH drills and some supporting tools has been widely used and the market demands increased gradually. With the rapid development of metallurgical industrial technology of our country, in gas, fuel oil, natural gas drilling, some demands of mechanical mining equipment and large and medium pore diameter drill with carbide ore also increased. Mining tools take advantage of WOB and rotation of the impact load itself broken rock, drill and buttons during operation when subjected to high impact loads at the same time by twisting, bending, stretching, compression and other complex stress. And it subjected to the wear and corrosion by rocks, rock dust, mineral water, etc. at high-speed rotation. So it requires that tungsten carbide used for mining not only has high hardness and toughness, but also has good wear and corrosion resistance.

In order to combine wear resistance with toughness, relevant researchers develop many new types of carbide, such as ultra-fine or nano cemented carbide, high-temperature powder based carbides, functional gradient tungsten carbide, low-Co and coarse grain carbide, double binder phase and double crystalline structure, etc. Double binder phase was developed by American company, which fully dense WC-Co pellets embedded in Co matrix to remain the similar wear resistance of common alloys. The binder phase can be any bonding metal, alloy or another kind of cemented carbide.

The most outstanding characteristic is that the hard phase is not a hard compound (WC), which is composed of refractory metal compound and Co sintered hard material into crystalline pellets (WC-Co) composition and mixed with binder metal for secondary sintering. Compared with most of double phase tungsten carbide, double binder phase carbide has greater design freedom (size, hardness, toughness, strength of base and so on), which has been widely used in rolling cutter bits, impacting bits, dragging bits and other tools. Double crystalline tungsten carbide is also called as non-uniform grain carbide. Since the WC grain size distribution curve has two peaks, it can be also known as bimodal-structure tungsten carbide. This kind of structure coarse grain WC can provide good ductility and toughness, and a certain proportion of fine grain WC is able to provide high wear resistance.

tungsten carbide buttons used for mining

 

CNC Machine Has Become Powerful Policy Development Priorities of China

In the year of 2015's "Made in China 2025" is the Programme of Action for the Decade of manufacturing power, which was first proposed implementation strategy. It takes "high-end CNC machine tools and robots" as a key area to vigorously promote. And it has proposed development of a number of precision, high speed, high efficiency, flexible CNC machine tools and basic manufacturing equipment and integrated manufacturing systems; accelerate the development of high-end CNC machine tools, manufacturing, and other materials by cutting-edge technology and equipment; To enhance the reliability, precision keeping the focus on the development of high-end CNC system, servo main features and key applications software motor, bearing, grating, accelerate industrialization; enhance the user process validation capacity building.

CNC machine tools is the mainstream of modern manufacturing equipment, which is he embodiment of modern technology, an important symbol of modern machinery manufacturing technology level, is relative to the people's livelihood, national defense building strategic materials. Although since 2002, China has become the biggest country in world machine tool imports and consumption, it has significant export deficit, especially in High-grade, large, sophisticated, high-speed CNC machine tools and CNC systems degree dependence on imports. So overcome technical bottlenecks, narrowing the gap with the international advanced level in the country has become the direction of development of CNC machine tools. Due to tungsten carbide has high hardness, excellent wear resistance, and it can be the best choice for indexable insert. In the process of CNC machining, tungsten carbide indexable inserts have many advantages:
1. It is difficult to produce the cracks and cracks expansion;
2. It can adopt CVD or PVD to deposit a harder layer (TiC, TiN, CBN) on tungsten carbide matrix surface to improve the cutting property;
3. Simple operation, shorter time for tool changing, high machining efficiency;
4. Tungsten carbide indexable inserts are standardized and centralized production, which has consistent blade geometry parameters, cutting control and stability, and a very wide scope.

tungsten carbide indexable insert

 

The Localization of Ultra-High-Purity Aluminum and its Alloy Coating Materials Promotes the Development of Tungsten Heater

Due to a high melting point and high corrosion resistance, tungsten heater is widely used in vacuum aluminizing. With the rapid development of electronic information market, high-performance chips, the new display and other electronic devices market has a good development space. The key support of electronics manufacturing is a thin film material, and because of the lower resistivity, and it is easy to deposit, and the mature technology and other excellent characteristics, a thin aluminum film has become core material for integrated circuits, discrete devices, liquid crystal display and other related fields. Compared to developed countries, the time of the development of ultra-high purity aluminum and its alloys evaporation material is relatively late, there is still a certain gap to well-known international companies in process maturity and industry development. Although China is one of the largest countries for reserves of tungsten resources in the world, but due to the immaturity of the technology, tungsten heater cannot satisfy domestic market in vacuum aluminizing. As a result of it, most buyers have to import products from abroad, which would not only time consuming but also a greater cost.

tungsten heaterRecently, China News reported that sets of technology system have been established of ultra-high purity aluminum and its alloy coating materials, realizing the development and industrialization of electronic information field the ultra-high purity aluminum evaporation materials, semiconductor of aluminum and its alloy target material and a full range of coating materials. The localization of ultra-high-purity aluminum and its alloy coating materials will accelerate the development of high-end high-purity thin film material, greatly facilitate the improvement of traditional non-ferrous metal industries and industrial extension technology, and prefect the advanced electronic information manufacturing industry and supply chain of accessory products. Vacuum aluminizing has the feature of plastic film and the properties of the metal. The function of vacuum aluminizing is that it can prevent ultraviolet ray, which prolongs quality guarantee period and improves the brightness and perception of film.

Severe Economic Situation Causes a Slow Growth of Tungsten Market (Tungsten Heater)

tungsten heaterIn recent years, China's economic situation is not optimistic, not only China, the global economy is in the doldrums, although China's GDP is still growing, but the growth rate has declined for five years, and it is likely to continue declining in next few years. After years of rapid economic growth, the current slow growth is a normal phenomenon. Peking University scholars believe that China is undergoing historic economic restructuring. In this tough economy condition, businesses and individuals need to do the pre-judgment for the future development. In addition, the continuous depreciation of the RMB has a great impact on the domestic economy.

What are the main reasons for the decline of China's current economy? Professor of Economics Hai Wen said that the first reason is a long-term trend. The growth of a country's economic cannot always keep 10% of high growth. On the other hand, the second reason is now China is now facing macroeconomic cycle. This recession is still a continuation of the 2009 recession. It can be seen from the tungsten market a few months ago that the price is fluctuating and most buyers have been kept wait-and-see attitude for a long time, resulting in the overall trading volume of whole tungsten market (tungsten heater) is in decline. While China's GDP growth rate has slowed compared to previous years, China's economy still has a great potential for development. Because China is in the take-off stage of economic, and the development potential is from the four areas, including services, urbanization, technology, innovation and manufacturing industry and the new developed space to brought by " The Belt and Road Initiative ". With the development of science and technology, it is believed that there will be more room for the development of China's economy in the future. Therefore, the tungsten market will be better soon.

Further Enhance of Tungsten Ore Exploration would Influence Tungsten Heater

tungsten heaterMineral resources are non-renewable resources, due to its limited reserves, China has strengthen the control of it in recent years. It is an important material basis for the development of social production, and production and life of modern society have already cannot separate with mineral resources. Moreover, China is currently in the mid-industrialization, the demand of mineral resources is increasing. China Mining News reported that the Ministry of Land and Resources of the People’s Republic of China made it clear in the near future that China will further strengthen the exploration and protection of important mineral resources. Land and Resources issued the “Land Resources ‘Thirteen Five’ Plan” which focus on the implementation of effective control of mining tungsten, rare earth ions, etc., strictly limiting the development of minerals and tailings resources which cannot be reasonably used, so that it can avoid the destruction and the waste of resources. Strictly managing development access of mineral resources, improving entry barriers of environmental protection, technology, investment, efficiency of resource use and others.

Although China is one of the biggest tungsten ore reserves countries in the world, but because of irrational exploitation and utilization, leading to the depletion of mineral resources. This regulation has the impact on the tungsten market. On the one hand, it would limit the production of the tungsten heater to a certain extent, and now it can ease the problem of oversupply of tungsten market. On the other hand, this plan can improve the development and utilization of mineral resources, protection China’s mineral resources. With the development of China's industrialization process, environmental pollution has also increased year by year, haze, acid rain and other natural disasters annually cause some damage to economy and the environment. This strengthening of controls will slow down the pollution of the environment to some extent.

 

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