China Pioneered New Type Silicon Carbide Desulfurization Pipeline, Tungsten Trioxide Desulfurization Catalyst-Haze Govern Weapon

June 18, scientific and technological achievements identification and products exchange of subject of "gradient porous silicon carbide ceramic / resin composite pipe wear and corrosion resistance" held in Beijing. In the meeting, the chief expert of this project reported the overall implementation of the project and accepted the questions from Expert Group. After discussion, the experts agreed that the product has a significant "wear-resisting and corrosion-resisting, super-long life and light weight" and other properties, thus the project passed through the technical inspection, and determined that the international pioneering, the overall technology has reached the international advanced level. It is reported that the product can significantly reduce power enterprises desulfurization system operating costs, reduce the emission of pollutants, and otherwise has good promotion prospects.

new type silicon carbide desulfurization pipeline and desulfurization catalyst
 
At present, China has a quite severe situation of energy-saving and emission-reduction, the sulfur dioxide is one of the main culprits in the formation of haze, however, thermal power enterprises are the main source of China's industrial sulfur dioxide exhaust gas. At present, the Chinese power companies desulfurization pipeline is widely using the traditional rubber lining and lining ceramic desulfurization pipeline, however, because these products are prone to corrosion, wear, fracture and other statuses, resulting in an annual loss of a variety of more than ten billion RMB; In addition, because of the unpredictability of the pipe broken, the unplanned shutdown of desulfurization system occur now and then, which greatly affects the efficiency and effectiveness of the entire power system. The program of "comprehensive implementation of coal-fired power plants ultra-low emissions and energy-saving work" which China issued noted that by 2020, China will fully implement of energy-saving coal-fired power plant, and the coal-fired generating units must be installed devices of desulfurization, denitrification and dust removal according to rules, thus to reach the goal of significantly reduce pollution emissions.
 
Tungsten trioxide desulfurization catalyst has active surface, which can occur catalytic oxidation, and promote the direct reaction of sulfur dioxide, accelerate the dissolution of calcium carbonate, promote calcium carbonate rapidly oxidized into calcium sulfate, strengthen the precipitation of calcium sulfate, lower the ratio of liquid and gas, reduce the ratio of calcium and sulfur and the water evaporation. In addition, the participate of tungsten trioxide desulfurization catalyst may play a role of preventing dirt, anti-corrosion and corrosion mitigation, reducing the desulfurization system maintenance and replacement of spare parts, broaden the range of options desulfurization materials, improve reliability of the system. Thus tungsten trioxide desulfurization catalyst has broad market in flue gas desulfurization, playing considerable economic and social benefits, thus to be the sharp weapon of haze governing.

 

A Meeting of Eight Enterprises for Tungsten Heater

After two meetings of tungsten enterprises in November, 2015 and February, 2016, the third meet whether it can further improve the tungsten market in June 7 was attracted much attention by public. The meeting was held in Chaozhou, enterprises who attended the meeting own more than 27 tungsten mine, and the production of tungsten concentrate is more than 50% of domestic production, so the market is accustomed to call these eight tungsten mining enterprises as "Eight Tungsten Enterprises". Recently, economic situation in China is in a depressed state, and tungsten market is also in turmoil. China's mainstream tungsten enterprises have been facing serious losses and the loss of strategic raw materials for 2 years. During this period, China's mainstream tungsten enterprises continue to take positive action to keep market stability, which save the critical situation of tungsten market.

tungsten heaterThe convening of the meeting could help restore confidence of private tungsten enterprises, and the leading of those large tungsten enterprises will directly has a significant impact on the private enterprises. Some effective policies put forward in the meeting, such as limited production, support value, restricted sales and other measures, which will greatly save the current sluggish state of the market. Eight tungsten enterprises reached an agreement in this meeting agreed to make that would reverse the declining situation of tungsten market.

As a national rare earth resource, China will introduce some relevant policies for tungsten, continuing to promote the steady development of tungsten market. The volume of tungsten has been continuing to reduce for a long time. This the third meeting likes fuel delivered in the snow, tungsten prices are expected to rise to a certain extent, but the possibility of a sharp rise is relatively small. Prices of tungsten heater and other related products will also increase. All in all, these three meetings will directly promote the future development of the tungsten market.

Beijing Held Third Party Industrial VOCs Governance Policy Seminar, Tungsten Trioxide Photocatalyst Handle VOC

June 15th, the third party industrial VOCs governance policy seminar which organized by the State Environmental Protection petrochemical industry VOCs Pollution Control Engineering Technology Center and the National Federation of Chamber of Commerce held in Beijing, in-depth discussed the status quo of VOCs market, analyzed the existing problems of development in this industry, and made recommendations for a number of system construction stage of industrial VOCs third-party governance and management.
 
The important means of controlling VOCs during the Thirteen Five period is "comprehensive treatment + oil and gas recovery + source control." During the Thirteen Five period, China predicts to carry out a comprehensive improvement of VOCs in the petrochemical, organic chemicals, surface coating, packaging, printing and other industries. In China, VOCs (volatile organic compounds), refers to the all volatile organic compound corresponding which saturated vapor pressure at room temperature, and greater than 70 Pa, an organic compound having a boiling point at atmospheric pressure below 260 ℃ or under 20 ℃ condition vapor pressure greater than or equal to 10 Pa.

VOCs governance policy seminar photocatalyst removes formaldehyde
 
After years of research, photocatalytic technology to governance VOCs has been large-scale used in the China industrial waste-gas fields, and constantly improve the industry to form a series of organic light catalytic exhaust gas purification device. Studies have shown that the tungsten trioxide photocatalyst is a very effective catalyst to governance VOCs, which can eventually break down the volatile organic compounds into harmless carbon dioxide and water under the action of light. Thus, the photocatalyst has the functions like strong sterilization, deodorant, anti-mildew, air purification. In particular, the composite tungsten trioxide photocatalyst, such as doped ceria, yttria, lattices of tungsten trioxide itself have changed due to the contamination of other metallic elements, the advantageously combination with the composite metal enhanced photocatalytic activity. However, the doping amount of the metal should not be too much, otherwise it may be counterproductive, on the contrary, it will lower photocatalytic activity of the photocatalyst.

 

Denitration Catalyst Industry Research Report, V2O5-WO3 / TiO2 Used Widely

The whole China's environmental protection industry started late for about 30 years up to now, its development is driven largely depending on government policy, and still in the stage of rapid development. Environmental protection industry and new energy development is generally considered to be the driving force of reshape the structure of economic development. The report analyzed that the upstream and downstream industry overview; the beneficial factors of this industry are: under the support of national industrial policy, the denitration equipment manufacturing market has a broad prospect, environmental protection equipment manufacturing technology continues to improve; however the disadvantages are: the economic development has faced with the greater downward pressure, thus to affect the environmental investments and expenses, the implementation of environmental protection policies in the system, mechanism, the implementation of environmental new policy in the aspects of system, mechanism and management are not perfect, besides, both the autonomous innovation and comprehensive ability are weak; the China domestic denitration industries market size of thermal power, steel, cement and others are in the rapid development, the market demand continued to increase. Of course, a lot of problems also encountered, such as technical, financial, talented person and performance barriers ect..

tungsten trioxide denitration catalyst
 
Air pollution control equipment manufacturing industry, especially the denitration catalyst industry is the technology, capital-intensive industry. In the early development of the China denitration technology, all the SCR key technologies and equipments are relied on the introduction of foreign. In recent years, as China's flue gas denitrification technology localization, industrialization, and the innovation development, the complexity and diversity SCR technology which adapted to Chinese coal-fired has been rapidly expanded across the thermal power industry.
 
The raw materials of SCR denitration catalyst including precious and non-precious metal oxide, wherein the precious metal is mainly Pt, Pd, Rh and Ag, etc., metal oxides are mainly V2O5,Fe2O3, CrOx, MnOx, MgO and NiO and so on. With the SCR denitration catalyst being continually researched deeply, the noble metal catalyst is soon replaced by the metal oxide catalyst. Among them, particularly the V2O5-WO3/TiO2and V2O5/TiO2 researched and applied for the most, and being used in conventional SCR devices to play high catalytic activity. WO3 is a yellow tungsten oxide with many unique properties, such as: photochromic, gas properties, catalytic, and so on, as an additive of denitration catalyst to primarily play the role of anti-sulfide, anti-sintering of carrier.

 

China Allocated 17.2 Billion RMB to Govern Heavy Metal Pollution, Tungsten Trioxide Photocatalyst Enrichs Metal Ion

In June 14th, China State Council Information Office announced the "<National Human Rights Action Plan (2012-2015)> Implement assessment report", in the section of "environmental rights" it pointed out that:
1. China modified the Environmental Protection Act, which strengthen citizen's right to know, and perfect public interest litigation system, strengthen the system of accountability;
2. In the period of 6 years from 2010 to 2015, the central finance allocated 17.2 billion RMB to support the governing of heavy metal pollution, and achieved good results. Compared to 2007, in 2014, the national emissions of the focused five heavy metals which are lead, mercury, cadmium, chromium and metalloid of arsenic decreased by 20%; besides, heavy metal pollution incidents decreased from more than 10 cases per year of 2010 - 2011 on average to less than 3 cases of 2012-2015 the annual average;
3. The capacity of the water pollution treatment has been enhanced;
4. Air pollution governing intensified.
 
The original meaning of heavy metal refers to the metal which the specific weight is greater than 5 (The metal with density greater than 4.5 grams per cubic centimeter), including gold, silver, copper, iron and lead ect.. Heavy metal pollution refers to the environmental pollution caused by the heavy metals or their compounds, mainly caused by human factors mining, emissions, waste water for irrigation and use of heavy metals exceeded products. The heavy metal discharged with wastewater, although the concentration is very small, it can accumulate in sediments and algae, adsorbed on the surface of fish and shellfish, thus to generate food chain concentrated and become a public disaster.

photocatalyst water purification and heavy metal pollution
 
Photocatalyst can well solve the problem of chromium, mercury, lead, cadmium and other metal ions pollution. Its photocatalytic reduction can be divided into three types:
1. Photocatalytic reduction to remove toxic metal ions;
2. Photocatalytic deposition to recover precious metals;
3. Photocatalytic deposition to load metal, thus to improve activity of photocatalyst.
 
Tungsten trioxide is a photocatalyst with excellent performance, which responses to visible light, rather than only rely on ultraviolet light. Tungsten trioxide photocatalyst has a strong adsorption for metal ions, furthermore, with the light intensity increasing, the precipitation of metal ions accelerated noticeably. In addition, the outstanding advantage of photocatalytic reaction like tungsten trioxide photocatalyst is that it can be applied into a very dilute solution, to play a role of potently concentrating metal ions. Meanwhile, as a catalyst, it does not consume itself, and can be put into use after the separation of metal through an appropriate process.

 

Ninth Shanghai International Water Exhibition Grand Opening, Tungsten Trioxide Photocatalyst as Magical Water Treatment Weapon

June 15th to 17th, 2016, the ninth ECOTECHCHINA Shanghai International Environmental Protection Exhibition will hold at the National Exhibition Center (Shanghai). The exhibition presents for the audience from municipal and industrial water treatment to the civilian latest technologies and solutions, to include5 major environmental content of "water treatment", "Solid waste gas", "Air New Wind", "pump control valve", "building water", etc.. Wherein, the carried out of AQUATECH CHINA International Water Exhibition Shanghai is always known as "the world's largest environmental exhibition industry platform". As we all know, in today's China and the deterioration of water quality and surface water showed a rising trend, the Chinese government attaches great importance to water pollution control. The Shanghai International Water Exhibition is not just a trade show, its proposed of the importance of water management relating in future of mankind.

tungsten trioxide and shanghai international water exhibition
 
The United Nations Food and Agriculture Organization estimated that in 2025, 2.8 billion people in the world will be lacking of drinking water. For this reason, in 2015, Japan had developed a new photocatalytic purification technology, which is expected to solve the problem of thirsty of world's 2.8 billion people. The representatively conventional photocatalyst is titanium dioxide; the technology is already quite mature. However, since the titanium dioxide responds only to ultraviolet light, its application restricted to some extent. 
 
Tungsten trioxide not only has a good performance of excellent catalytic hydrogenation deoxygenation, oxidation, etc., but also has the excellent properties of photochromic and gas sensitivity. The inorganic pollutants which photocatalytic can degrade including: nitrate radical, sulfite root, sulfur dioxide, NO and so on. The study found that the tungsten trioxide photocatalyst has ideal catalytic degradation on the wastewater which contains sulfite root, sulfur ions, iodine ions and nitrate radical. In addition, the tungsten trioxide photocatalyst can also solve the pollutions of metal ions like chromium, mercury, and lead, to achieve the effect of purifying water quality. Therefore, tungsten trioxide photocatalyst becomes a “Magical Weapon” for handling polluted water, since then, Water Girl would have been "Excessive Magnificence washed".

 

Beijing Introduced Low Nitrogen Transformation Subsidy, Tungsten Trioxide Denitration Catalyst Boosts Emission Reduction

June 4, approved by the Beijing Municipal Government, Environmental Protection Bureau, Finance Bureau, Quality and Technical Supervision of Beijing Municipal jointly issued the "Beijing Gas (oil) boiler low nitrogen transformation instead the subsidy of reward funding management rule"(hereinafter referred to as the" Rules "), which subsidizes the gas (oil) boiler low nitrogen transformation project, helps to further reduce emissions of nitrogen oxides, promotes the implementation of the clean air action plan to accelerate the improvement of air quality.

denitrification system and tungsten trioxide
 
Atmospheric pollution is mainly coming from the emissions and life pollution emissions which brought out from rigid demand of running city. The key of the air pollution control is nitrogen oxides, volatile organic compounds and coal-fired (VOC). Reducing the concentration of nitrogen oxides is an urgent need and the only way to improve air quality, while the low nitrogen transformation is a hard task for the implementation of new air pollution emission standards for boilers. In recent years, selective catalytic reduction flue gas denitrification technology (SCR) developed rapidly, and has been widely used in Europe and Japan; currently, the flue gas catalytic reduction denitration technology is the most widely used.
 
At present, the popular SCR processes worldwide are two kinds of SCR of ammonia and urea method. Both methods are occurred under the presence of a catalyst, and finally reduce the NOx into harmless nitrogen and water. The denitration catalyst is a core part of the SCR system, generally takes titanium dioxide as a carrier, vanadium pentoxide as the main active material, tungsten trioxide as a co-agent. Tungsten trioxide plays the roles not only anti-sulfide and anti-toxic in the denitration catalyst, but also enhances anti-sintering ability of the carrier itself, thus its importance is obviously.
 
Beijing introduced the "Rule" will not only stimulate the city's passion for denitrification transformation, but also established a benchmark in the provinces, then, the air quality will be greatly improved.

 

China Tungsten Industry Association Held Bureau Meetings in Chaozhou

In June 7, 2016, China Tungsten Industry Association, the sixth of nine Bureau meetings held in Chaozhou. The meeting analyzed the current tungsten market situation and reached consensus on stable market. Besides, the meeting examined and adopted the China Tungsten Industry 13th Five Years Plan and other relevant resolutions. The meeting was chaired by the vice president, executive chairman, the party committee secretary of Xiamen Tungsten Co., Ltd. Zhuang Zhigang.

China State Department counselor, president of the China Nonferrous Metals Industry Association and China Tungsten Industry Association, Chen Quan Xun attended the meeting and made a speech. He stressed that the members of the Bureau should play a leading role for stable tungsten market, they should enhance communication, unity, play attention to the interest of the whole, joint efforts to control market risks, resist the vicious competition, and maintain market running. He said that this year, the external environment for non-ferrous metal industry development is still very complicated, so we should correctly understand the current situation and grasp any chance for increasing scientific and technological innovation, promoting industrial upgrading. He asked CTIA (China Tungsten Industry Association) should strengthen self-discipline and in-depth research firmly the principal contradiction and hot issues of tungsten industry. Besides, they should operate innovation activities for government, industries and enterprises development. The first Secretary-General Liu Liangxian introduced the tungsten industry economic performance of this year and the china tungsten industry 13th five years development plan (draft).

The meeting considered the resolution of council member adjustment. The meeting agreed Lianpingxian zhujiang kuangye co., Ltd. general manager Ma Songgui to succeed Zhang Zheng, Wendeng, Wendeng Zhengxing Tungsten Industry Co. chairman Gong Shaohua to succeed Liu Yuxin, and Ganzhou Gannan Tungsten Industry Co., Ltd. general manager Zhu Bo to succeed Qi Shen.

The meeting also considered the resolution of development members and the withdrawal the membership and agreed to develop Ganzhou Haichuang Tungsten Industry Co., Ltd., Comin Ganzhou Nonferrous Metal Materials Co., Ltd. as member of the CTIA, respectively anchored smelting branch. On the other hand, there are three companies want to withdraw the membership, including Zhuzhou Lizhou Cemented Carbide Co., Ltd., Changsha Huaxin alloy Electric Engineering Co., Ltd., Shanghai tool works Co., Ltd.. Further, the meeting also approved the China tungsten industry 13th five years development plan.

The meeting discussed the tungsten industry current situation and exchanges the market information. The participants agreed that this year the tungsten concentrate production will significant decrease and the companies who produced tungsten finished products inventories remain at low level. Besides, the end demand overall is getting better. After the meeting, many tungsten companies agree to strengthen coordination and communication, to prevent and control common risk, and continue to take control of production, reducing production, reducing sales, increase business purchase and storage and other measures for tungsten market healthy and stable development.

During the meeting, Guangdong, Chaozhou, Secretary of municipal party committee Li Shuihua met with CTIA chairman Chen Quanxuan and other representatives participating in the conference. Li Shuihua introduced Chaozhou economic and social development situation, hoping China Nonferrous Metals Industry Association can play an important role for industry stable development, providing advanced resources and information and as a bridge for industry member to communication. In addition, in industrial level, technology introduction, marketing and other aspects it can give Chaozhou non-ferrous metals industry more help. Chen Quanxun said that in recent years Chaozhou has made great achievements in accelerating urban development, promoting industrial restructuring and upgrading and other fields. China non-ferrous metal industry should better learn from the advanced experience of the all around the country, focusing on strengthening concept innovation and technological innovation, promoting recycling of resources for industry development to break a new path. CTIA and non-ferrous Tungsten Industry Association will serve as a bridge to promote associations and related enterprises to strengthen the cooperation with the Chaozhou, to promote Chaozhou economic development.

Tungsten market: many manufactures of tungsten finished products willing to hold the price of tungsten finished products at the high level to make tungsten market health and stable development, but the price does not rise and the market doesn’t recovery; tungsten raw materials and tungsten finished products price continues to fall down slight and many buyer want to wait for market recover, so the transaction activity is low.

Rare Earth Market: in this week the rare earth market is running smoothly, many businesses continue to wait and there is not significant adjustment on rare earth price. Many manufacturers expected that the State Reserve Bureau plan will make the price go up, so they reluctant to sale the product at low price. Besides, the finished product manufacturers have low willing for stock up. The market is unstable, so many buyers can not make a decision for purchasing and still want to wait and see until the market is clear.

China Tungsten Industry Association

 

 

Nano Tungsten Carbide Has Some Difficulties in Industrialization

Compared with tungsten carbide material with common grains (micron scale), nano-crystalline tungsten carbide has remarkable improvements in density, hardness, fracture toughness and wear resistance, etc. This is due to the grain size reaches nano scale, the volume of the grain decreases, the specific surface area becomes larger, the arrangement of atoms on the interface relative out of order, it will immigrate easily under deformation external interference and the material shows excellent toughness and ductility. Especially in nano tungsten carbide cutting tools, nano-scale microstructure phase due to the size effect, the grain boundary area increases, anti-crack propagation resistance improved, which is beneficial for obtaining excellent mechanical properties and machinability.

However, since the difficulties in manufacturing process, higher cost and nano grains grow easily in the process of sintering, tungsten carbide less than 100nm can not reach the level of industrial production. So the researchers have found that add nano grains in tungsten carbide matrix with fine grains, it can effectively improve the hardness and toughness of the matrix materials. Now the enterprises use nano composite reinforced method to improve the properties of tungsten carbide material with fine grains. The principle of nano tungsten carbide composite strengthening mechanism is nano grain dispersed in the matrix has dispersed toughening effect. When added to a high elastic modulus of the matrix material in the second phase particles (nano particles), these particles in the matrix material by stretching action will prevent the transverse cross-section contraction, but to achieve the same substrate transverse shrinkage, the increase in the large longitudinal tensile stress, so that the material can consume more energy, toughening effect works. At the same time, high modulus particles crack can act as a "pinning" effect, so that the crack deflection, deviation, thereby dissipating power forward crack, so the toughening effect works. In addition, the dispersed nano grains in tungsten carbide matrix can inhibit the growth of carbide grains during the sintering process and greatly improve the mechanical properties of tungsten carbide materials.

nano tungsten carbide mills

 

Tungsten Trioxide Denitration Catalyst - Air Pollution Controlling Sharp Weapon

Currently, flue gas dust removal, desulfurization, denitrification are the three business segments in air pollution control, the survey statistics of Commercial Industrial Research Institute shows that in 2015, China's desulfurization and denitration industry needs scale over 90 billion RMB, of which the new market capacity is more than 400 billion, and the market of transformation capacity is more than 50 billion RMB, also with the national standards of air pollution regulations becoming more stringent, the next 5--10 years will be the key period for China's air pollution control, the increase of market capacity will continue to be at about 10% .
 
Premier Li Keqiang in his government work report made, 50,000 units of small coal-fired boilers will be eliminated in the end of "12th Five-Year", the transformation desulfurization of 15 million kilowatts of the coal-fired power plant will be promoted, and denitrification transformation of 130 million kilowatts, 180 million kilowatts dust transformation. According to the State Council issued the "2014--2015 Annual Energy Saving And Emission Reduction Carbon Development Action Plan", during the remainder period of  "12th Five-Year", the desulfurization and denitrification projects will be continually promoted, and denitrification transformation of 300 million kilowatts coal-fired units should be done, 250 million kilowatts burning coal flue gas unit should remove bypass, 40,000 square meters of steel sintering machine to install desulphurization facilities, 600 million tons of clinker production capacity of cement production line installed denitration facilities.

analysis and prediction of china desulfurization and denitration industry market in 2010-2020
Wherein, the first, second and third column respectively on behalf of desulfurization and denitration market size, the new market capacity and the transformation market capacity, the unit is all one hundred million RMB.
 
SCR denitration system is widely recognized as the most effective, universal application of denitrification technology. In the current background of full swing flue gas denitrification project settings and renovation project, tungsten trioxide denitration catalyst as the core technology of SCR system, its application prospect is very bright. Tungsten trioxide mainly plays the roles of anti-sulfide, poisoning resistance, and enhance the ability of anti-sintering carrier itself ect. in the denitration catalyst; in addition, due to the cheap price of tungsten trioxide (compared to Au, Pt and other precious metals), tungsten trioxide denitration catalyst as a sharp weapon is expected to become the "Blue-Eyed Boy" of air pollution governance.

 

 

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