Tungsten Ceramic Rings

An incredibly strong and dense metal, tungsten can be combined with ceramic to make rings and other fine jewelry. Tungsten ceramic rings are becoming a popular choice for many wedding bands due to their durability and beauty.

Identification
Tungsten is a steel-gray metal. When paired with tungsten, ceramic is often polished black for greater contrast.

Strength
When processed with carbon at high temperatures, tungsten forms tungsten carbide, the hardest metallic substance in the world. Tungsten ceramic rings have unmatched strength.

Benefits
Tungsten ceramic polishes to a mirror-like finish. It's also highly resistant to abrasions and scratches. It would take deliberate scratching from diamonds or corundum to inflict any damage whatsoever.

Considerations
Tungsten ceramic rings, while nearly impervious to scratching, are not indestructible. Tungsten ceramic's hardness makes it slightly more brittle than traditional jewelry metals, meaning it can be crushed under severe stress.

Warning
Once manufactured, tungsten ceramic rings can not be resized due to tungsten's remarkable hardness.

 

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Tungsten in the Human Body

According to the Centers for Disease Control and Prevention (CDC), tungsten "is a naturally occurring steel-gray to tin-white metal or fine powder that comes from more than 20 different tungsten-bearing minerals." Its atomic number is 74, and its atomic symbol is W. Normally used to toughen steel, the increase of industrial activity in the United States has heightened the chances of people being exposed to tungsten.

Means of Exposure
People can be exposed to tungsten by drinking water, eating food or breathing air that has been contaminated by tungsten. Although tungsten is naturally present in the environment in small amounts as minerals, industrial plants that manufacture tungsten can release large quantities of tungsten into the air.

Entering and Leaving the Body
Tungsten enters the body through eating, drinking, touching or breathing. Scientists are unsure about the metabolism of tungsten in the body, but it does enter the bloodstream and is spread to all parts of the body. Most of the tungsten is quickly processed in the digestive system, leaving your body either through urine or feces.

Health Effects
When exposed to high levels of tungsten, the immediate effects on the body can be irritation of the skin, eyes, throat or nose. Long-term effects can involve a myriad of lung problems, most likely coughing, wheezing and shortness of breath. Many of the long-term effects have been attributed to the use of cobalt in the tungsten-refining and compounding processes. It is important to understand that these side effects are the result of long-term heavy exposure to tungsten, not the minimal exposure to tungsten that most people experience.

Inconclusive Research
Currently, there is not enough scientific research to determine whether tungsten exposure leads to leukemia or other forms of cancer. The general rule of thumb is the more a person is exposed to tungsten, the higher the likelihood of that person experiencing some health effects

 

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Tungsten Carbide Cutting Tools

The quality of a cutting tool can determine whether cuts will be smooth and clean or difficult and sloppy. A metal cutting tool's quality begins with the hardness and durability of its metal. According to the Society of Manufacturing Engineers, "carbide and carbide-coated tools cut about three to five times faster than high-speed steels" and "higher tungsten content increases wear resistance." There are tungsten carbide cutting tools for a wide variety of applications and, once you understand the breadth of their possible uses, you'll be able to choose one for professional, amateur or even industrial projects.

Circular Saw Blades
Circular blades surrounded by sharp, tungsten carbide-tipped teeth can be found in factories for manufacturing, carpenters' tool kits for milling---and in the home, because do-it-yourselfers can buy them at hardware stores. These circular saw blades are sized to fit not only in industrial machinery but also in standard table saws and hand-held circular saws. The most common tungsten carbide circular saw blades are not solid tungsten carbide; their body is typically tempered steel and only the cutting edges of the teeth are coated with tungsten carbide. A variation of the toothed saw blade is the grinding "wheel" or abrasive blade---still circular but without teeth. Their edge is coated with tungsten carbide and used to exert abrasive force as they grind through stone, ceramics and metal.

Reciprocating Saw Blades
Tungsten carbide coats the edges of blades for reciprocating saws, such as jigsaws and demolition reciprocal saws. The back-and-forth sawing motion of these types of saws is well-suited for abrasion, and their coating of tungsten carbide grit allows them to grind through metals, ceramics and masonry. Applications include removing cast iron pipes and metal fasteners during demolition or cutting access holes through stone and tile during remodeling.

Drill Bit Tools
Drill bits may be solid tungsten carbide or tipped with it to provide the speed, accuracy and wear resistance required by machine shops and high-precision manufacturing applications. Construction professionals and amateurs buy similar bits that attach to hand power drills, drill presses and hobbyist rotary tools. Precision drill bit and grinding tools with tungsten carbide tips might be used for milling or sculpting metal as well as decorative carving of stone and precious gemstones. As materials scientist Dale Wittmer stated in a Southern Illinois University publication, "Tungsten carbide tools have been the standard for over 50 years in the mining industry."

 

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How Is Tungsten Obtained?

Finding Tungsten
Tungsten is often found in conjunction with other metals such as wolframite (the element in which tungsten was first discovered whose name means "devourer of tin") and scheelite. Around the world, China is the most common place that tungsten is found and mined, though other locales such as Austria, Bolivia and Portugal also have mines that produce respectable amounts of this metal for use in light bulbs, rockets, and in the case of some first world countries, spacecraft.

Refining the Tungsten
Once the ores containing tungsten have been mined from the earth, a process developed by those who discovered tungsten (the Elhuyar brothers Juan and Fausto who were chemists in the late 1700s) is used to purify the metal. The ore that contains the tungsten is crushed, cleaned and then treated with various alkalis so that tungsten trioxide is formed. The tungsten trioxide is then heated using either carbon or hydrogen gas, which then separates the tungsten metal from either the water vapor or the carbon dioxide that forms, depending on which gas was used in the heating and refining process.

The Final Step
Pure tungsten, which is often a whitish or a gray color once it's separated from the ore it was mined in, is in a state referred to as powered tungsten. If necessary, powered tungsten can be used right away without any further modifications. However, if there is no pressing need for the tungsten right then, it will be shaped into bars to be stored or transported. Given that tungsten is a relatively malleable and ductile metal, this process isn't a very difficult one.

 

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Tungsten Applications - Lamps

Background

Osmium has the highest optical emission rate of all metals. Consequently, after Edison’s carbon filaments, it was used at the beginning of the lamp industry. Osmium’s big disadvantage is its high vapour pressure, resulting in a short lamp life. Tungsten withstands considerably higher temperatures than osmium and has a very low vapour pressure, resulting in more luminosity combined with a long lifetime.

Wire Properties

Tungsten wire possesses characteristics that have provided it with a unique place in the origin and growth of the lamp industry. The lamp industry represents the largest commercial application of tungsten wire. It is used in this application because it displays excellent creep resistance at elevated temperatures. Tungsten is an attractive lamp filament material because it has an extremely high melting temperature (~3680 K) and a low vapour pressure at high temperatures. Tungsten is also intrinsically brittle and, initially, this prevented the manufacture of tungsten wire. However, at the beginning of this century William Coolidge, working at the General Electric Company, pursued the idea of deforming tungsten at elevated temperatures in order to make small diameter tungsten wire. Two important findings of his work were, first, to develop a method to work a powder metallurgy ingot down to wire by using deformation at elevated temperatures; and, second, to produce a ductile material from this deformation. Today, the ability to handle tungsten wire and coil filaments without breakage is the backbone of the whole incandescent lamp industry.

Processing

The initial stages of thermomechanical processing of sintered tungsten ingot are usually performed by rolling and / or swaging. These operations allow large deformations at relatively high temperatures and during the initial stages of deformation the ingot reaches full density. By working the tungsten at elevated temperatures, the tungsten is maintained well above the ductile to brittle transition temperature but below the recrystallisation temperature. At various points during this deformation, anneals must be applied, or the tungsten will become overworked and begin to fracture. Finally, wire drawing is used to reduce the tungsten to its final desired diameter. At this point, the microstructure consists of fibres which have very high aspect ratios: they act like fibres in a rope and provide bend ductility.

It was not until the advent of transmission electron microscopy that potassium was located in small bubbles in the tungsten. It is these potassium bubbles which provide the wire with its unique high temperature creep resistance. Potassium is essentially insoluble in the tungsten. The bubbles are first formed from the doped powder in the ingot during sintering. During thermomechanical processing, these initial bubbles are drawn out into tubes. When the wire is annealed, these tubes break up to form the rows of bubbles.

Once wire drawing is complete, the tungsten can be coiled into a filament and recrystallised. When the wire is recrystallised, the grain boundaries interact with the potassium bubble rows as the boundaries migrate, giving rise to an interlocking grain structure.

‘Bamboo’ Structure

Recrystallized pure tungsten wire forms a bamboo structure: the grains occupy the entire wire diameter, and the boundaries are essentially perpendicular to the wire axis. At elevated temperatures, under the stress produced by gravity, these boundaries would slide past one another by diffusion and produce a rapid failure. However, when potassium is present in the wire, the interlocking grain structure reduces the rate of grain boundary sliding and extends the filament life. These bubbles continue to pin the grain boundaries at the temperatures of lamp operation, and thus maintain a stable microstructure during the life of the lamp.

Applications

Tungsten is used in many different types of incandescent lamps. The most common types are the general household lamps, automotive lamps, and reflector lamps for floodlight or projector applications. There are also many thousands of speciality lamps, which have a broad range of applications, such as audio-visual projectors, fibre-optical systems, video camera lights, airport runway markers, photocopiers, medical and scientific instruments, and stage or studio systems.

 

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