Denitration Catalyst Industry Research Report, V2O5-WO3 / TiO2 Used Widely

The whole China's environmental protection industry started late for about 30 years up to now, its development is driven largely depending on government policy, and still in the stage of rapid development. Environmental protection industry and new energy development is generally considered to be the driving force of reshape the structure of economic development. The report analyzed that the upstream and downstream industry overview; the beneficial factors of this industry are: under the support of national industrial policy, the denitration equipment manufacturing market has a broad prospect, environmental protection equipment manufacturing technology continues to improve; however the disadvantages are: the economic development has faced with the greater downward pressure, thus to affect the environmental investments and expenses, the implementation of environmental protection policies in the system, mechanism, the implementation of environmental new policy in the aspects of system, mechanism and management are not perfect, besides, both the autonomous innovation and comprehensive ability are weak; the China domestic denitration industries market size of thermal power, steel, cement and others are in the rapid development, the market demand continued to increase. Of course, a lot of problems also encountered, such as technical, financial, talented person and performance barriers ect..

tungsten trioxide denitration catalyst
 
Air pollution control equipment manufacturing industry, especially the denitration catalyst industry is the technology, capital-intensive industry. In the early development of the China denitration technology, all the SCR key technologies and equipments are relied on the introduction of foreign. In recent years, as China's flue gas denitrification technology localization, industrialization, and the innovation development, the complexity and diversity SCR technology which adapted to Chinese coal-fired has been rapidly expanded across the thermal power industry.
 
The raw materials of SCR denitration catalyst including precious and non-precious metal oxide, wherein the precious metal is mainly Pt, Pd, Rh and Ag, etc., metal oxides are mainly V2O5,Fe2O3, CrOx, MnOx, MgO and NiO and so on. With the SCR denitration catalyst being continually researched deeply, the noble metal catalyst is soon replaced by the metal oxide catalyst. Among them, particularly the V2O5-WO3/TiO2and V2O5/TiO2 researched and applied for the most, and being used in conventional SCR devices to play high catalytic activity. WO3 is a yellow tungsten oxide with many unique properties, such as: photochromic, gas properties, catalytic, and so on, as an additive of denitration catalyst to primarily play the role of anti-sulfide, anti-sintering of carrier.

 

China Allocated 17.2 Billion RMB to Govern Heavy Metal Pollution, Tungsten Trioxide Photocatalyst Enrichs Metal Ion

In June 14th, China State Council Information Office announced the "<National Human Rights Action Plan (2012-2015)> Implement assessment report", in the section of "environmental rights" it pointed out that:
1. China modified the Environmental Protection Act, which strengthen citizen's right to know, and perfect public interest litigation system, strengthen the system of accountability;
2. In the period of 6 years from 2010 to 2015, the central finance allocated 17.2 billion RMB to support the governing of heavy metal pollution, and achieved good results. Compared to 2007, in 2014, the national emissions of the focused five heavy metals which are lead, mercury, cadmium, chromium and metalloid of arsenic decreased by 20%; besides, heavy metal pollution incidents decreased from more than 10 cases per year of 2010 - 2011 on average to less than 3 cases of 2012-2015 the annual average;
3. The capacity of the water pollution treatment has been enhanced;
4. Air pollution governing intensified.
 
The original meaning of heavy metal refers to the metal which the specific weight is greater than 5 (The metal with density greater than 4.5 grams per cubic centimeter), including gold, silver, copper, iron and lead ect.. Heavy metal pollution refers to the environmental pollution caused by the heavy metals or their compounds, mainly caused by human factors mining, emissions, waste water for irrigation and use of heavy metals exceeded products. The heavy metal discharged with wastewater, although the concentration is very small, it can accumulate in sediments and algae, adsorbed on the surface of fish and shellfish, thus to generate food chain concentrated and become a public disaster.

photocatalyst water purification and heavy metal pollution
 
Photocatalyst can well solve the problem of chromium, mercury, lead, cadmium and other metal ions pollution. Its photocatalytic reduction can be divided into three types:
1. Photocatalytic reduction to remove toxic metal ions;
2. Photocatalytic deposition to recover precious metals;
3. Photocatalytic deposition to load metal, thus to improve activity of photocatalyst.
 
Tungsten trioxide is a photocatalyst with excellent performance, which responses to visible light, rather than only rely on ultraviolet light. Tungsten trioxide photocatalyst has a strong adsorption for metal ions, furthermore, with the light intensity increasing, the precipitation of metal ions accelerated noticeably. In addition, the outstanding advantage of photocatalytic reaction like tungsten trioxide photocatalyst is that it can be applied into a very dilute solution, to play a role of potently concentrating metal ions. Meanwhile, as a catalyst, it does not consume itself, and can be put into use after the separation of metal through an appropriate process.

 

Ninth Shanghai International Water Exhibition Grand Opening, Tungsten Trioxide Photocatalyst as Magical Water Treatment Weapon

June 15th to 17th, 2016, the ninth ECOTECHCHINA Shanghai International Environmental Protection Exhibition will hold at the National Exhibition Center (Shanghai). The exhibition presents for the audience from municipal and industrial water treatment to the civilian latest technologies and solutions, to include5 major environmental content of "water treatment", "Solid waste gas", "Air New Wind", "pump control valve", "building water", etc.. Wherein, the carried out of AQUATECH CHINA International Water Exhibition Shanghai is always known as "the world's largest environmental exhibition industry platform". As we all know, in today's China and the deterioration of water quality and surface water showed a rising trend, the Chinese government attaches great importance to water pollution control. The Shanghai International Water Exhibition is not just a trade show, its proposed of the importance of water management relating in future of mankind.

tungsten trioxide and shanghai international water exhibition
 
The United Nations Food and Agriculture Organization estimated that in 2025, 2.8 billion people in the world will be lacking of drinking water. For this reason, in 2015, Japan had developed a new photocatalytic purification technology, which is expected to solve the problem of thirsty of world's 2.8 billion people. The representatively conventional photocatalyst is titanium dioxide; the technology is already quite mature. However, since the titanium dioxide responds only to ultraviolet light, its application restricted to some extent. 
 
Tungsten trioxide not only has a good performance of excellent catalytic hydrogenation deoxygenation, oxidation, etc., but also has the excellent properties of photochromic and gas sensitivity. The inorganic pollutants which photocatalytic can degrade including: nitrate radical, sulfite root, sulfur dioxide, NO and so on. The study found that the tungsten trioxide photocatalyst has ideal catalytic degradation on the wastewater which contains sulfite root, sulfur ions, iodine ions and nitrate radical. In addition, the tungsten trioxide photocatalyst can also solve the pollutions of metal ions like chromium, mercury, and lead, to achieve the effect of purifying water quality. Therefore, tungsten trioxide photocatalyst becomes a “Magical Weapon” for handling polluted water, since then, Water Girl would have been "Excessive Magnificence washed".

 

Beijing Introduced Low Nitrogen Transformation Subsidy, Tungsten Trioxide Denitration Catalyst Boosts Emission Reduction

June 4, approved by the Beijing Municipal Government, Environmental Protection Bureau, Finance Bureau, Quality and Technical Supervision of Beijing Municipal jointly issued the "Beijing Gas (oil) boiler low nitrogen transformation instead the subsidy of reward funding management rule"(hereinafter referred to as the" Rules "), which subsidizes the gas (oil) boiler low nitrogen transformation project, helps to further reduce emissions of nitrogen oxides, promotes the implementation of the clean air action plan to accelerate the improvement of air quality.

denitrification system and tungsten trioxide
 
Atmospheric pollution is mainly coming from the emissions and life pollution emissions which brought out from rigid demand of running city. The key of the air pollution control is nitrogen oxides, volatile organic compounds and coal-fired (VOC). Reducing the concentration of nitrogen oxides is an urgent need and the only way to improve air quality, while the low nitrogen transformation is a hard task for the implementation of new air pollution emission standards for boilers. In recent years, selective catalytic reduction flue gas denitrification technology (SCR) developed rapidly, and has been widely used in Europe and Japan; currently, the flue gas catalytic reduction denitration technology is the most widely used.
 
At present, the popular SCR processes worldwide are two kinds of SCR of ammonia and urea method. Both methods are occurred under the presence of a catalyst, and finally reduce the NOx into harmless nitrogen and water. The denitration catalyst is a core part of the SCR system, generally takes titanium dioxide as a carrier, vanadium pentoxide as the main active material, tungsten trioxide as a co-agent. Tungsten trioxide plays the roles not only anti-sulfide and anti-toxic in the denitration catalyst, but also enhances anti-sintering ability of the carrier itself, thus its importance is obviously.
 
Beijing introduced the "Rule" will not only stimulate the city's passion for denitrification transformation, but also established a benchmark in the provinces, then, the air quality will be greatly improved.

 

China Tungsten Industry Association Held Bureau Meetings in Chaozhou

In June 7, 2016, China Tungsten Industry Association, the sixth of nine Bureau meetings held in Chaozhou. The meeting analyzed the current tungsten market situation and reached consensus on stable market. Besides, the meeting examined and adopted the China Tungsten Industry 13th Five Years Plan and other relevant resolutions. The meeting was chaired by the vice president, executive chairman, the party committee secretary of Xiamen Tungsten Co., Ltd. Zhuang Zhigang.

China State Department counselor, president of the China Nonferrous Metals Industry Association and China Tungsten Industry Association, Chen Quan Xun attended the meeting and made a speech. He stressed that the members of the Bureau should play a leading role for stable tungsten market, they should enhance communication, unity, play attention to the interest of the whole, joint efforts to control market risks, resist the vicious competition, and maintain market running. He said that this year, the external environment for non-ferrous metal industry development is still very complicated, so we should correctly understand the current situation and grasp any chance for increasing scientific and technological innovation, promoting industrial upgrading. He asked CTIA (China Tungsten Industry Association) should strengthen self-discipline and in-depth research firmly the principal contradiction and hot issues of tungsten industry. Besides, they should operate innovation activities for government, industries and enterprises development. The first Secretary-General Liu Liangxian introduced the tungsten industry economic performance of this year and the china tungsten industry 13th five years development plan (draft).

The meeting considered the resolution of council member adjustment. The meeting agreed Lianpingxian zhujiang kuangye co., Ltd. general manager Ma Songgui to succeed Zhang Zheng, Wendeng, Wendeng Zhengxing Tungsten Industry Co. chairman Gong Shaohua to succeed Liu Yuxin, and Ganzhou Gannan Tungsten Industry Co., Ltd. general manager Zhu Bo to succeed Qi Shen.

The meeting also considered the resolution of development members and the withdrawal the membership and agreed to develop Ganzhou Haichuang Tungsten Industry Co., Ltd., Comin Ganzhou Nonferrous Metal Materials Co., Ltd. as member of the CTIA, respectively anchored smelting branch. On the other hand, there are three companies want to withdraw the membership, including Zhuzhou Lizhou Cemented Carbide Co., Ltd., Changsha Huaxin alloy Electric Engineering Co., Ltd., Shanghai tool works Co., Ltd.. Further, the meeting also approved the China tungsten industry 13th five years development plan.

The meeting discussed the tungsten industry current situation and exchanges the market information. The participants agreed that this year the tungsten concentrate production will significant decrease and the companies who produced tungsten finished products inventories remain at low level. Besides, the end demand overall is getting better. After the meeting, many tungsten companies agree to strengthen coordination and communication, to prevent and control common risk, and continue to take control of production, reducing production, reducing sales, increase business purchase and storage and other measures for tungsten market healthy and stable development.

During the meeting, Guangdong, Chaozhou, Secretary of municipal party committee Li Shuihua met with CTIA chairman Chen Quanxuan and other representatives participating in the conference. Li Shuihua introduced Chaozhou economic and social development situation, hoping China Nonferrous Metals Industry Association can play an important role for industry stable development, providing advanced resources and information and as a bridge for industry member to communication. In addition, in industrial level, technology introduction, marketing and other aspects it can give Chaozhou non-ferrous metals industry more help. Chen Quanxun said that in recent years Chaozhou has made great achievements in accelerating urban development, promoting industrial restructuring and upgrading and other fields. China non-ferrous metal industry should better learn from the advanced experience of the all around the country, focusing on strengthening concept innovation and technological innovation, promoting recycling of resources for industry development to break a new path. CTIA and non-ferrous Tungsten Industry Association will serve as a bridge to promote associations and related enterprises to strengthen the cooperation with the Chaozhou, to promote Chaozhou economic development.

Tungsten market: many manufactures of tungsten finished products willing to hold the price of tungsten finished products at the high level to make tungsten market health and stable development, but the price does not rise and the market doesn’t recovery; tungsten raw materials and tungsten finished products price continues to fall down slight and many buyer want to wait for market recover, so the transaction activity is low.

Rare Earth Market: in this week the rare earth market is running smoothly, many businesses continue to wait and there is not significant adjustment on rare earth price. Many manufacturers expected that the State Reserve Bureau plan will make the price go up, so they reluctant to sale the product at low price. Besides, the finished product manufacturers have low willing for stock up. The market is unstable, so many buyers can not make a decision for purchasing and still want to wait and see until the market is clear.

China Tungsten Industry Association

 

 

Nano Tungsten Carbide Has Some Difficulties in Industrialization

Compared with tungsten carbide material with common grains (micron scale), nano-crystalline tungsten carbide has remarkable improvements in density, hardness, fracture toughness and wear resistance, etc. This is due to the grain size reaches nano scale, the volume of the grain decreases, the specific surface area becomes larger, the arrangement of atoms on the interface relative out of order, it will immigrate easily under deformation external interference and the material shows excellent toughness and ductility. Especially in nano tungsten carbide cutting tools, nano-scale microstructure phase due to the size effect, the grain boundary area increases, anti-crack propagation resistance improved, which is beneficial for obtaining excellent mechanical properties and machinability.

However, since the difficulties in manufacturing process, higher cost and nano grains grow easily in the process of sintering, tungsten carbide less than 100nm can not reach the level of industrial production. So the researchers have found that add nano grains in tungsten carbide matrix with fine grains, it can effectively improve the hardness and toughness of the matrix materials. Now the enterprises use nano composite reinforced method to improve the properties of tungsten carbide material with fine grains. The principle of nano tungsten carbide composite strengthening mechanism is nano grain dispersed in the matrix has dispersed toughening effect. When added to a high elastic modulus of the matrix material in the second phase particles (nano particles), these particles in the matrix material by stretching action will prevent the transverse cross-section contraction, but to achieve the same substrate transverse shrinkage, the increase in the large longitudinal tensile stress, so that the material can consume more energy, toughening effect works. At the same time, high modulus particles crack can act as a "pinning" effect, so that the crack deflection, deviation, thereby dissipating power forward crack, so the toughening effect works. In addition, the dispersed nano grains in tungsten carbide matrix can inhibit the growth of carbide grains during the sintering process and greatly improve the mechanical properties of tungsten carbide materials.

nano tungsten carbide mills

 

Tungsten Trioxide Denitration Catalyst - Air Pollution Controlling Sharp Weapon

Currently, flue gas dust removal, desulfurization, denitrification are the three business segments in air pollution control, the survey statistics of Commercial Industrial Research Institute shows that in 2015, China's desulfurization and denitration industry needs scale over 90 billion RMB, of which the new market capacity is more than 400 billion, and the market of transformation capacity is more than 50 billion RMB, also with the national standards of air pollution regulations becoming more stringent, the next 5--10 years will be the key period for China's air pollution control, the increase of market capacity will continue to be at about 10% .
 
Premier Li Keqiang in his government work report made, 50,000 units of small coal-fired boilers will be eliminated in the end of "12th Five-Year", the transformation desulfurization of 15 million kilowatts of the coal-fired power plant will be promoted, and denitrification transformation of 130 million kilowatts, 180 million kilowatts dust transformation. According to the State Council issued the "2014--2015 Annual Energy Saving And Emission Reduction Carbon Development Action Plan", during the remainder period of  "12th Five-Year", the desulfurization and denitrification projects will be continually promoted, and denitrification transformation of 300 million kilowatts coal-fired units should be done, 250 million kilowatts burning coal flue gas unit should remove bypass, 40,000 square meters of steel sintering machine to install desulphurization facilities, 600 million tons of clinker production capacity of cement production line installed denitration facilities.

analysis and prediction of china desulfurization and denitration industry market in 2010-2020
Wherein, the first, second and third column respectively on behalf of desulfurization and denitration market size, the new market capacity and the transformation market capacity, the unit is all one hundred million RMB.
 
SCR denitration system is widely recognized as the most effective, universal application of denitrification technology. In the current background of full swing flue gas denitrification project settings and renovation project, tungsten trioxide denitration catalyst as the core technology of SCR system, its application prospect is very bright. Tungsten trioxide mainly plays the roles of anti-sulfide, poisoning resistance, and enhance the ability of anti-sintering carrier itself ect. in the denitration catalyst; in addition, due to the cheap price of tungsten trioxide (compared to Au, Pt and other precious metals), tungsten trioxide denitration catalyst as a sharp weapon is expected to become the "Blue-Eyed Boy" of air pollution governance.

 

China Developed High-Capacity, Fast-Charge, Electrochromic Battery Uses Tungsten Oxide

Recently, China has developed a high-capacity, fast charging electrochromic battery. In this type of battery, tungsten oxide (WO2.72, i.e. violet tungsten oxide) nano-wires are taken as a positive electrode, and the metal aluminum is as the negative electrode; compared with other batteries, this kind of cell has some new advantages in the following aspects:
1. It establishes a capacity to identify of interface with the users through color changing, which the specific performance is: the transparent state on behalf of the full status of the battery; when it gradually turns to blue, it means the storage power starts to consume; and when the color reaches the deepest, it says the power is depleted;
2. By adding a trace amount of hydrogen peroxide, it can realize fast charging (full charged within 8s), besides, the traditional external power supply can be used for charging, and also the oxygen in the air can be used to achieve self-charging;
3. The battery capacity is six times (or more) higher than the similar battery.

tungsten trioxide and graphene
 
Electrochromic refers to the optical properties of the material (reflectance, transmittance, absorption rate, etc.) occurs stable and reversible of the phenomenon of color changing under the applied electric field, and it appears in the reversible changing of color and transparency. Electrochromic material is divided into non-organic electrochromic material and organic electrochromic material, wherein the typical non-organic electrochromic material is tungsten trioxide. Violet tungsten oxide is a kind of functional nano material with many properties, such as photochromic, electrochromic and gasochromic, it has broad applications in a variety of sensitive element; at the same time, it is one kind of better and more economical method for preparing nanoscale and ultrafine tungsten powder. The violet tungsten oxide usually comes from the raw material of ammonium paratungstate, to generate by controlling the specific reaction conditions.
 
We all know that the battery capacity is one of the important performance indicators of the battery, with the increasing of the capacity of the battery, the charging time will also be doubled. Of course, in the face of "black technology", this is not a problem, with the rise of all kinds of fast charge technology, the charging time is considerably reduced. The electrochromic battery invented by China, which uses tungsten oxide as a positive electrode, has opened up a new path for the future development of battery.

 

China-South Korea Signed Free Trade Agreement, Tungsten Products Tariffs Reduced by 5%

China-South Korea after signed FTA, up to 20 years, China zero-tariff products will achieve up 92% of tax items and achieve up 91% of imports. Korean and China 90% products tax items and 85% trade volume all achieve linearization, namely the tariff is zero. China to reduce some clothing, footwear, skin care products, diapers and other consumer goods import tariffs and the average range fell more than 50%. The agreement covers trade in goods, services, investment and rules, a total of 17 areas, including the e-commerce, competition policy, government procurement, environment and other 21st century economic and trade issues. In terms of tungsten products, South Korea imported tungsten products form China can enjoy most-favoured-nation clause and the tariff of tungsten products reduced by 5%.

MFN is an important provision of trade treaty, which refers to contracting party A present and future giving all the privileges, concessions and exemptions to any third party and should give to the contracting party B. The MFN principle requires members to grant each other most-favored among parties, namely the GATT contracting principle is: a member of the trade preferences and licensing another party member must be automatically extended to all other members. As the basic and the most important principle of GATT, the MFN principle to regulate trade in goods between the members of the party, to promote the expansion of international trade and development played an important role.

The treatment range of MFN is large, and the most important is tariff treatment of the major import and export commodities, including imports, exports or transit goods and other taxes; there are some strict customs regulations, procedure and fees about merchandise import, export, transit, warehousing and change ships. In the Treaty of Commerce and Navigation, the scope of the MFN clause applies even bigger, the contracting state into the ship and its cargo, and pulled out all kinds of taxes, fees and formalities at berth are included.

tungsten products

 

 

China Made a Process in High-performance Tungsten Carbide

Chinese R&D team in tungsten carbide has a breakthrough in the research and development of high-performance tungsten carbide composite material, it mainly includes:

1. Phase controlled particle size adjustable nano WC-Co composite powder scale preparation techniques: It takes tungsten-cobalt oxide and carbon as raw material, and uses solid-phase synthesis in-situ reaction to synthesize ultrafine or nano WC-Co composite powder. It has many advantages, such as simple operation, short process, Low-cost equipment, energy saving and so on. The synthesis of composite powder has high purity, low oxygen content, Co content within a wide range of 6-20wt% is accurate and adjustable, which reached on the current international quality ultrafine nano WC-based powder control standards.

2. High liquidity, nano-structure WC-based spraying powder scale preparation techniques: It based on the principle of spray-drying and combines with heat treatment, which not only maintains the characteristics of nano structure, but also can fabricate the thermal spray powder with high fluidity. So it gets to the root of nano powder thermal spraying at high temperature flame flow easily decomposed decarbonization, which is a difficulty in international technical fields.

3. High density, high surface quality and technical preparation of carbide wear and corrosion coating: The technology synergistically adjust the initial powder component, thermal spray granulation and agglomeration process, by a combination of carbon content design, unique heat treatment process, recombinant size, thermal spraying process parameters optimization to fabricate high-performance nano-structure carbide coating. The coating having a porosity of <0.5% of a high density; compared with the conventional micro structure, the surface quality has significantly improved, the surface roughness Ra <0.5m.

4. Ultrafine size nano-crystalline tungsten carbide block preparation: The technology develops a low-temperature region slow heating rate, low pressure, high temperature rapid heating region segmentation, greater pressure, does not heat the unique field effect sintering process. And produces nano tungsten carbide block with average grain size of 60-100nm. The average grain size of 60nm dense nano-crystalline alloy is the smallest grain size reported so far around the world. Meanwhile, nano-crystalline tungsten carbide sintered material can meet the requirements of high hardness and high fracture toughness.

 

WeChat

Tungsten Metal

Tungsten Metal Price

Tungsten Alloy

Tungsten Alloy Price

Tungsten Carbide

Tungsten Carbide Price

Tungsten Powder

Tungsten Powder Price

Tungsten Copper

Tungsten Copper Price

Tungsten Oxide

Tungsten Oxide Price