W/Tic Nanopowders Fabricated with APT by Wet Chemical Process

image of tungsten filament lamp
Tungsten (W) and its alloys present high melting point, good thermal conductivity, high strength at elevated temperatures, low sputtering yield in irradiated environments, and low tritium inventory. One of the common usages of tungsten is as the filament of lamp due to its high melting point. These properties also make W the most promising plasma facing material (PFM) in future fusion reactors. However, W becomes brittle under low-temperatures, high-temperatures, and radiation exposure.

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Recovery of Tungsten from SCR Catalysts as Ammonium Paratungstate

image of SCR catalyst
In order to recycle expensive rare metals such as V2O5 and WO3, a method of separating and recovering solid oxide particles by leaching it in a liquefied form is available. Tungsten has been recovered from SCR catalysts as the form of ammonium paratungstate (APT), the recovery rate as high as 96.0% could be obtained. The SCR catalysts contains 1.23% V2O5 and 7.73% WO3.

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Synthesis of Ca3WO6 for Cleaner APT Production

SEM image of Ca3WO6
The manufacture process of ammonium paratungstate (APT) by treating tungsten concentrates at present can be divided into acidic leaching method, soda or caustic soda leaching method and ammonium salt leaching method. The former two methods are conventional processes, in which the tungstic acid or sodium tungstate obtained need to be transformed into ammonium tungstate for producing APT, therefor there are a great amount of wastewater together with a plenty of auxiliary materials consumption due to difficult recycling of leaching reagents. The ammonium salt leaching method can directly obtain ammonium tungstate solution and thus has drawn great attention. It is of great significance to search a cheap and easily-cycled ammonium salt as leaching reagent to produce APT cleanly and efficiently. 

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Synthesis of Nanosized Tungsten Carbide from Water Soluble Tungsten Source—APT

image of tungsten carbide rod

Thermal sprayed cemented carbides such as WC–Co(Cr) and Cr3C2–NiCr coatings are well known and widely used for wear protection purposes. Nanocarbides in cermets have shown promising results in gaining the hardness , wear performance in abrasion, cavitation  or slurry type of wear conditions. Even friction properties have been reported to be improved by the use of nanocarbides. The driving force for reducing the carbide grain size comes from the fact that, as the carbide size becomes smaller, the binder mean free path is reduced, resulting in higher resistance to deformation and material loss. Many researchers have pursued such a hypothesis so as to improve the wear performance of HVOF WC–Co by reducing the WC grain size to the nanoscale.

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rGO/WO3 Composites with Excellent Electrochemical Performance from Ammonium Paratungstate

FESEM images of the (a) WO3 and (b) rGO-WO3 composites

The global energy demand has increased due to rapid population growth. The depletion of energy sources and increase in energy demand have urged researchers worldwide to study the electrochemical energy storages system, such as batteries, conventional dielectric capacitors, and fuel cells. Supercapacitors are one of the electrochemical capacitors that have attracted much research interest because of their long cycle life, high power density, excellent reversibility, environment friendly and higher safety.

Read more: rGO/WO3 Composites with Excellent Electrochemical Performance from Ammonium Paratungstate

 

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