What Are the Preparation Methods for Tungsten Diiodide?

Pyrex glass tubes for the generation of tungsten diiodide

There are three direct preparation methods for tungsten diiodide, which are obtained by high-temperature chemotaxis, halide exchange reaction, and reaction of tungsten hexacarbonyl with elemental iodine. Meanwhile, tungsten diiodide can also be obtained by indirect method.

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What Is the Stability of Tungsten Diiodide?

Tungsten diiodide powder

Tungsten diiodide (WI2) has good stability at room temperature but readily reacts chemically at high temperatures and in the presence of oxygen. Tungsten diiodide is an inorganic compound with the following chemical properties.

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What Are the Physical Properties of Tungsten Diiodide?

Semiconductor wafers

Tungsten Diiodide is an inorganic compound with the molecular formula WI2 and a relative molecular mass of 437.7. It is a metal salt of tungsten and hydroiodic acid, characterized by black or dark brown crystals, usually in powder or lump form. Tungsten diiodide has good solubility in alkalis but is insoluble in cold water, ethanol, and carbon disulfide. It has a density of 6.79 g/cm3 and a melting point of about 300°C, which allows it to remain stable at everyday ambient temperatures.

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What Kind of Crystal Is Tungsten Diiodide?

Regular geometrical crystal shapes different from tungsten diiodide

Tungsten diiodide is a transition crystal. Transitional crystals are different from many substances in nature with regular geometrical shapes, such as ionic crystals, molecular crystals, atomic crystals, and metal crystals. The inter-particle role of the lattice junctions of the transitional crystals has changed, and the interactions between particles of the crystalline structure and the nature of the crystal between the different types of crystalline forms, which is difficult to be classified as any of the above-mentioned typical crystals, and there are a lot of actual crystals belonging to the transitional crystals.

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What Is the Solubility of Tungsten Diiodide?

Immiscible solvents and solutes

The solubility of tungsten diiodide has no specific pattern. For inorganic solvents, tungsten diiodide is soluble in alkali but insoluble in water at room temperature; for organic solvents, tungsten diiodide is insoluble in ethanol and carbon disulfide (CS2).

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