Growth And Characterization of Type-II ZnO/ZnTe Core-Shell Nanowire Arrays for Solar Cell Applications

Large area, well-aligned type-II ZnO/ZnTe core-shell nanowire arrays have been fabricated on an a-plane sapphire substrate. The ZnO nanowires were grown in a furnace by chemical vapor deposition with gold as catalyst and then were coated with a ZnTe shell on the ZnO nanowires surface by a metal-organic chemical deposition chamber. The morphology and size distribution of the ZnO/ZnTe core-shell nanowire arrays were studied by scanning electron microscopy (SEM) and the crystal structure was examined by x-ray diffraction (XRD). Transmission measurement was used to study the optical properties of the core-shell nanowires. The results indicated that the ZnO/ZnTe core-shell nanowire arrays have good crystalline quality. In addition, it was found that the nanowire arrays have good light absorption characteristics and these properties make it suitable for making photovoltaic devices.

ZnTe single crystals were grown by the solution growth method using a Te solvent. The growth has been performed in a vertical Bridgman arrangement. As the seeding material, oriented sapphire substrates with a similar diameter as that of the ZnTe crystals to be grown have been applied. ZnTe single crystals with a diameter of 21 mm could successfully be grown.


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