Can Ordinary Glass Be Used as a Bulb Shell for Iodine Tungsten Lamp?

Glass material for making iodine tungsten lamp shell

Ordinary glass cannot be used as a bulb shell for an iodine tungsten lamp. The iodine tungsten lamp is a kind of illumination lamp that uses the principle of halogen-tungsten circulation to fill iodine into the bulb to control the sublimation of the tungsten wire. It has the characteristics of high brightness and long life. It is often used as the light source of cinematography stage factory building square.

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Can Iodine Tungsten Lamp Be Used on the Construction Site?

Tungsten iodine lamps used at construction sites

Iodine tungsten lamp is not allowed to be used on the construction site. Iodine tungsten lamp is an improved version of incandescent lamps. Its principle is similar to that of incandescent lamp. A chemical combination reaction occurs at the lamp wall, and the sublimated tungsten on the lamp wall and other parts of the lamp tube is recycled to the filament and sublimated at a relatively high temperature (above 1200-2000℃) so that the filament will not burn out quickly due to high temperature.

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Does a Tungsten Iodine Lamp Have an Ignition Capacity?

Change of central temperature of iodine tungsten lamp with different power

Iodine tungsten lamp has ignition capacity. An iodine tungsten lamp is a kind of tungsten filament lamp filled with iodine vapor for a chemical reaction. It is often used in indoor and outdoor lighting places with high illumination requirements and high installation points. This kind of lamp has a high degree of thermal light source, and there is a risk of burning combustibles on the outer wall of the lamp tube in a short time. Therefore, it is of great significance to understand the ignition ability of iodine tungsten lamp to combustibles for fire prevention and fire investigation.

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What Is the Standard Molar Enthalpy Change for the Reaction of Tungsten Diiodide?

Chemical reaction process of tungsten diiodide

The standard molar enthalpy change for the reaction of tungsten diiodide (WI2) is -70.61 kJ/mol. it is defined as the thermodynamic energy change between the reactants (i.e., W and I2) required for the formation of 1 mol of WI2 and its corresponding reaction product (i.e., the WI2 gas) under the standard condition. Specifically, the enthalpy of formation of the reaction of tungsten diiodide can be determined by determining the standard molar enthalpy of formation of tungsten, iodine, and tungsten diiodide, a value that can be obtained by experimental measurement.

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What Is the Standard Molar Enthalpy of the Formation of Tungsten Diiodide?

Reaction process to produce tungsten diiodide

The standard molar enthalpy of formation of tungsten diiodide is -8.37 kJ/mol. The standard molar enthalpy of formation of tungsten diiodide, ΔfHmθ(WI2, g, 298 K), is defined as the standard molar enthalpy of formation for the reaction to produce the substance tungsten diiodide (νB=+1) from the monomers of the reference state at 298 K. The standard molar enthalpy of formation is -8.37 kJ/mol.

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What Is the Type of Crystal Structure of Tungsten Diiodide?

Tungsten-iodine octahedron

The type of crystal structure of tungsten diiodide is an orthorhombic crystal system, space group Bbem (No. 64), with lattice parameters a = 1258 pm, b = 1259 pm, and c = 1584 pm, and is a crystal cell with hexahedra. Each hexahedron has a tungsten atom in the center surrounded by six iodine atoms, forming a tungsten-iodine octahedron. The tungsten and iodine atoms are located at positions (0,0,0) and (0.5,0.5,0.5), respectively. The crystal has a layered structure with each layer consisting of tungsten-iodine octahedra, with neighboring layers interacting with each other through weak van der Waals forces.

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How to Obtain Tungsten Diiodide by Indirect Preparation?

Reaction formula for the production of tungsten diiodide intermediates

The indirect preparation method of tungsten diiodide does not aim at obtaining the product directly but is a method of preparing other tungsten iodide compounds before preparing the final product. The indirect preparation method develops based on the direct preparation method and chooses tungsten iodide compounds that are easier to prepare relative to tungsten diiodides, such as tungsten triiodide (WI3) and tetraiodide (WI4), as intermediate products, to reduce the requirements and uncontrollable factors of the reaction conditions and to improve the yield of tungsten diiodide.

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What Is the Tungsten Elemental Valence in Tungsten Diiodide?

Electrically neutral tungsten atoms

In tungsten diiodide, the tungsten element has a valence of +2, and the iodine element has a valence of -1. Therefore, the quantity ratio of iodine to tungsten in tungsten diiodide is 2:1, which is determined according to the principle of electroneutrality.

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How to Make a Preparation of Tungsten Diiodide from Tungsten Hexachloride?

Structure of tungsten diiodide prepared from tungsten hexachloride

Tungsten hexachloride (WCl6), as one of the reactants, can be reacted with hydrogen iodide (HI) to prepare tungsten diiodide, but attention should be paid to the temperature of the reaction to reduce the chances of the formation of other products.

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How to Make a Preparation of Tungsten Diiodide from Tungsten Hexacarbonyl?

Reaction equation for the preparation of tungsten diiodide from tungsten hexacarbonyl

There can be two methods of preparing tungsten diiodide using tungsten hexacarbonyl, the main difference between the two being in the choice of temperature.

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