W/TaC Composites as Plasma-Facing Materials Using Ammonium Paratungstate

image of tungsten alloy rod

The development of high-performance plasma-facing materials (PFMs) is one of the key issues in realizing the safe application of nuclear fusion reactors. The extreme working environment of PFMs in fusion devices is primarily characterized by high thermal load, high-energy particle bombardment, and high flux hydrogen (H)/helium (He) plasma irradiation. Tungsten and its alloys are promising plasma-facing materials (PFM) that were used for the international thermonuclear experimental (ITER) divertor and have been regarded as the most promising plasma materials for future fusion reactors.

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WO3/Titania Nanotubes with Improving Photocatalytic Activity Fabricated Using Ammonium Paratungstate

TEM image of WO3-TNT

Titanium dioxide (Titania) has been utilized in photocatalysis since the discovery of the early 1970s. Since then, researchers have developed a variety of methods to tune the nanostructure and the composition to optimize the photocatalytic efficiency. Compared with nanoparticles or the bulk materials, nanotubular-structure titania possesses larger specific surface area and stronger adsorption capacity that results to a better photocatalytic effect. These unique chemical and physical properties allow titania nanotubes (TNT) to be widely used in sewage treatment, air purification, and sterilization areas.

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Recovery of Tungsten from SCR Catalysts as Ammonium Paratungstate

image of SCR catalyst
In order to recycle expensive rare metals such as V2O5 and WO3, a method of separating and recovering solid oxide particles by leaching it in a liquefied form is available. Tungsten has been recovered from SCR catalysts as the form of ammonium paratungstate (APT), the recovery rate as high as 96.0% could be obtained. The SCR catalysts contains 1.23% V2O5 and 7.73% WO3.

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W/Tic Nanopowders Fabricated with APT by Wet Chemical Process

image of tungsten filament lamp
Tungsten (W) and its alloys present high melting point, good thermal conductivity, high strength at elevated temperatures, low sputtering yield in irradiated environments, and low tritium inventory. One of the common usages of tungsten is as the filament of lamp due to its high melting point. These properties also make W the most promising plasma facing material (PFM) in future fusion reactors. However, W becomes brittle under low-temperatures, high-temperatures, and radiation exposure.

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Synthesis of Nanosized Tungsten Carbide from Water Soluble Tungsten Source—APT

image of tungsten carbide rod

Thermal sprayed cemented carbides such as WC–Co(Cr) and Cr3C2–NiCr coatings are well known and widely used for wear protection purposes. Nanocarbides in cermets have shown promising results in gaining the hardness , wear performance in abrasion, cavitation  or slurry type of wear conditions. Even friction properties have been reported to be improved by the use of nanocarbides. The driving force for reducing the carbide grain size comes from the fact that, as the carbide size becomes smaller, the binder mean free path is reduced, resulting in higher resistance to deformation and material loss. Many researchers have pursued such a hypothesis so as to improve the wear performance of HVOF WC–Co by reducing the WC grain size to the nanoscale.

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