Niobium Doped Tungsten Oxide Nanomaterials

niobium doped tungsten oxide nanomaterials image

Tungsten oxide is a transition metal oxide widely studied because of its unique properties. It has been widely used in electrochromic devices, sensors, separation materials and so on. In recent years, great progress has been made in the synthesis of nanoparticles, and the focus of research has shifted to the study of anisotropic nanoparticles.

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Cerium-Zirconium-Tungsten Composite Catalyst Material

cerium-zirconium-tungsten composite catalyst material image

Nitrogen oxides (NOx) are known to be harmful to the environment. It is necessary to process gases containing these oxides or gases originating from motor vehicles or fixed engines to convert them into nitrogen. One known treatment is SCR selective reduction.

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Tungsten Oxide Target Densification

tungsten oxide target densification image

Tungsten oxide film is a widely studied functional material. It has excellent short-wavelength transmission, and the forbidden band width is easily adjusted by doping. Through ion implantation, ultraviolet photon irradiation, and gas molecule adsorption, its optical and electrical properties will change significantly, so it is displayed on optical glass and flat panel. There are wide application prospects in the fields of photoelectric conversion, electrochromism and photochromism.

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Electrochromic Glass Tungsten Thin Oxide Films Preparation

electrochromic glass tungsten oxide film preparation image

Building energy consumption generally accounts for more than one third of the total social energy consumption. At the same time, building energy contributes up to 25% of the world's greenhouse gas emissions, and is one of the major greenhouse gas emission reduction households. Glass windows are the main channel for building to exchange light and heat with the outside world, and 50% of building energy consumption is carried out through glass windows. The heat absorption of building exterior walls also aggravates the phenomenon of heat island in urban center.

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Oxidation of Tungsten Disulfide

tungsten disulfide picture

Oxidation of tungsten disulfide refers to the process in which tungsten disulfide reacts with oxygen to produce sulfur dioxide and tungsten trioxide when heated in air. As one product of the oxidation, tungsten trioxide can form a protective film during the lubrication process so as to reduce the wear of the metal surface.

tungsten disulfide picture

Oxidation is a chemical reaction between a substance and oxygen. Slow reaction of substance and oxygen is called eremacausis while the intense oxidation is called burning.

When heated in air, tungsten disulfide reacts with oxygen to form sulfur dioxide and tungsten trioxide. Its initial rate of slow oxidation is 460°C, and the initial rate of fast oxidation is 802°C. At 427°C, it starts to lose sulfur. The oxidation of tungsten disulfide is affected by temperature and particle size. The higher temperature and the smaller tungsten disulfide particles lead to the more intense reaction.

There are two products of the oxidation of tungsten disulfide:

1.Sulfur dioxide

Sulfur dioxide (SO2) is colorless transparent gas with a pungent smell. It is soluble in water, ethanol and ether. It has a property of bleaching and is often used to bleach pulp, wool as well as silk. As it can inhibit the growth of mold and bacteria, it is usually used as a preservative.

However, sulfur dioxide is one of the major pollutants in the atmosphere. It is produced by the burning of traditional fuels such as coal and oil. With the dissolution and oxidation, it can form sulfuric acid (the main component of acid rain), doing harm to the environment.

2.Tungsten trioxide

Tungsten trioxide (WO3) is yellow powder, being insoluble in water, being soluble in alkali and being slightly soluble in acid. It is used for making tungsten wires, fireproof materials and alloys with high melting points.

tungsten trioxide image

During the lubrication, tungsten trioxide is formed by the slow oxidation of tungsten disulfide under high temperature. As a protective film, tungsten trioxide can inhibit the further oxidation and prevent the fast loss of tungsten disulfide. At the same time, it can protect the surface of metal with its low friction coefficient.

 

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