W/TaC Composites as Plasma-Facing Materials Using Ammonium Paratungstate

image of tungsten alloy rod

The development of high-performance plasma-facing materials (PFMs) is one of the key issues in realizing the safe application of nuclear fusion reactors. The extreme working environment of PFMs in fusion devices is primarily characterized by high thermal load, high-energy particle bombardment, and high flux hydrogen (H)/helium (He) plasma irradiation. Tungsten and its alloys are promising plasma-facing materials (PFM) that were used for the international thermonuclear experimental (ITER) divertor and have been regarded as the most promising plasma materials for future fusion reactors.

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WO3/Titania Nanotubes with Improving Photocatalytic Activity Fabricated Using Ammonium Paratungstate

TEM image of WO3-TNT

Titanium dioxide (Titania) has been utilized in photocatalysis since the discovery of the early 1970s. Since then, researchers have developed a variety of methods to tune the nanostructure and the composition to optimize the photocatalytic efficiency. Compared with nanoparticles or the bulk materials, nanotubular-structure titania possesses larger specific surface area and stronger adsorption capacity that results to a better photocatalytic effect. These unique chemical and physical properties allow titania nanotubes (TNT) to be widely used in sewage treatment, air purification, and sterilization areas.

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W/Tic Nanopowders Fabricated with APT by Wet Chemical Process

image of tungsten filament lamp
Tungsten (W) and its alloys present high melting point, good thermal conductivity, high strength at elevated temperatures, low sputtering yield in irradiated environments, and low tritium inventory. One of the common usages of tungsten is as the filament of lamp due to its high melting point. These properties also make W the most promising plasma facing material (PFM) in future fusion reactors. However, W becomes brittle under low-temperatures, high-temperatures, and radiation exposure.

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Recovery of Tungsten from SCR Catalysts as Ammonium Paratungstate

image of SCR catalyst
In order to recycle expensive rare metals such as V2O5 and WO3, a method of separating and recovering solid oxide particles by leaching it in a liquefied form is available. Tungsten has been recovered from SCR catalysts as the form of ammonium paratungstate (APT), the recovery rate as high as 96.0% could be obtained. The SCR catalysts contains 1.23% V2O5 and 7.73% WO3.

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Synthesis of Nanosized Tungsten Carbide from Water Soluble Tungsten Source—APT

image of tungsten carbide rod

Thermal sprayed cemented carbides such as WC–Co(Cr) and Cr3C2–NiCr coatings are well known and widely used for wear protection purposes. Nanocarbides in cermets have shown promising results in gaining the hardness , wear performance in abrasion, cavitation  or slurry type of wear conditions. Even friction properties have been reported to be improved by the use of nanocarbides. The driving force for reducing the carbide grain size comes from the fact that, as the carbide size becomes smaller, the binder mean free path is reduced, resulting in higher resistance to deformation and material loss. Many researchers have pursued such a hypothesis so as to improve the wear performance of HVOF WC–Co by reducing the WC grain size to the nanoscale.

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Synthesis of Ca3WO6 for Cleaner APT Production

SEM image of Ca3WO6
The manufacture process of ammonium paratungstate (APT) by treating tungsten concentrates at present can be divided into acidic leaching method, soda or caustic soda leaching method and ammonium salt leaching method. The former two methods are conventional processes, in which the tungstic acid or sodium tungstate obtained need to be transformed into ammonium tungstate for producing APT, therefor there are a great amount of wastewater together with a plenty of auxiliary materials consumption due to difficult recycling of leaching reagents. The ammonium salt leaching method can directly obtain ammonium tungstate solution and thus has drawn great attention. It is of great significance to search a cheap and easily-cycled ammonium salt as leaching reagent to produce APT cleanly and efficiently. 

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rGO/WO3 Composites with Excellent Electrochemical Performance from Ammonium Paratungstate

FESEM images of the (a) WO3 and (b) rGO-WO3 composites

The global energy demand has increased due to rapid population growth. The depletion of energy sources and increase in energy demand have urged researchers worldwide to study the electrochemical energy storages system, such as batteries, conventional dielectric capacitors, and fuel cells. Supercapacitors are one of the electrochemical capacitors that have attracted much research interest because of their long cycle life, high power density, excellent reversibility, environment friendly and higher safety.

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Extraction of Tungsten from Acidic High-Phosphorus Solution for Producing APT

image of high-phosphorus tungsten ore

Tungsten is one of the most important high-tech metals, and its high-purity products are vital for developing advanced materials. Wolframite and scheelite have been used as main resources for tungsten extraction. However, the high-quality wolframite and scheelite resources reduced with the continuously exploitation and utilization and the tungsten deposits with high content of impurities must be exploited. As one of the main impurities, phosphorus significantly affects the quality of the ammonium paratungstate (APT) products. In order to obtain qualified APT, the phosphorus impurity contained in tungsten deposits must be removed in the process of tungsten hydrometallurgy.

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Potassium-Doped Tungsten with High Thermal Shock Resistance Prepared from APT

image of inner wall of nuclear fusion device

As one of the most promising candidates for plasma-facing material (PFM) in future fusion reactors, tungsten was extensively investigated in recent years. However, even though tungsten has many advantages like high melting point, high thermal conductivity, low tritium inventory and low erosion rate under plasma loading, there still exist some disadvantages such as high ductile–brittle transition temperature (DBTT), low recrystallization temperature (RCT), irradiation induced hardening, and so on.

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Ammonium Paratungstate Applied in Photocatalytic Degradation of Herbicides

TEM image of Pd-WO3

Many types of herbicides and pesticides can be used for the growth inhibition of weeds and protection of crops from insect pests. However, through the transfer of wastewater that contains residual herbicides and pesticides, groundwater and rivers can be polluted. Many crops contain 2,4-dichlorophenoxyacetic acid (2,4-D), as it was considered a main ingredient for more than 1500 herbicides and pesticides. It is a carcinogenic and highly toxic pollutant that causes injury to the heart and central nervous system, and because of its high biological and chemical stability, it is very difficult to decompose

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