Tungsten Disulfide for Electrocatalysis Application

XPS spectrum of the S 2p and W 4f signals for the pristine image

Tungsten disulfide (WS2) is promising electrocatalysis with a layered structure with adjustable electrical properties and exposed edges that can act as the active center. It is mainly used as an electrocatalyst for hydrogen evolution reactions. The surface of WS2 is inert; however, the catalytic activity of WS2 occurs at the lamellar edges, which determines the overall catalytic performance. In order to improve the catalytic effect of WS2, the electrolyte must be in complete contact with the WS2 layer.

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WS2 Films for Catalysis Application

Catalytic decomposition of different samples under ultraviolet light irradiation image

Due to its unique band gap properties, inherent vacancy defects, and low electrical conductivity, WS2 films can be used for catalysis. Catalysis including photocatalysis and electrocatalysis is essential in our daily life, and they have been widely used for environmental protection and clean energy generation.

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Chemical Methods for WS2 Film Preparation

Schematic of the processes for producing WS2 thin films by one-step CVD and hydrothermal method image

Two common methods for preparing tungsten disulfide (WS2) films by chemical methods are chemical vapor deposition (CVD) and hydrothermal growth of single-crystal tungsten disulfide from aqueous solutions under high temperature and pressure conditions. CVD is the most common method used to prepare tungsten disulfide. The CVD method involves a reaction process in which a gaseous precursor reacts chemically on a solid surface to produce a solid deposit.

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Stripping Method for WS2 Preparation

WS2 film preparation by mechanical stripping and liquid-phase stripping and lithium-ion intercalation image

Bulk tungsten disulfide (WS2) can be stripped by physical and chemical methods, which are classified as mechanical and stripping method, and lithium-ion intercalation method. In recent years, in order to obtain large-area, high-quality monolayer tungsten disulfide films, researchers have tried to grow monolayer tungsten disulfide films on ingot substrates and then exfoliate them by atomic or molecular intercalation methods.

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Properties of Tungsten Disulfide

Schematics of the deposition chambers for WS2-CF coating prepared by magnetron sputtering image

Owing to unique physical and chemical properties, transition metal dichalcogenides (TMDs) attract research interest. Among the family of TMDs, tungsten disulfide (WS2) has a unique band structure due to its semiconductor properties; i.e., its broadband spectral response characteristics, ultra-fast bleaching recovery time, and excellent saturable light absorption.

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