The Influence on Intrinsic Light Emission of Calcium Tungstate and Molybdate Powders by Multivalence Pr Codoping

For trivalent praseodymium (Pr³⁺) and quadrivalent praseodymium (Pr⁴⁺) codoped CaMO₄ (M = W, Mo) powders, the luminescence propriety of matrix is obviously influenced by carrier concentration. The light emission intensity of CaWO₄ matrix decreases exponentially with increasing of Pr concentration because oxygen-deficient obtains an electron supplied by Pr³⁺ (5d). However, the light emission intensity of CaMoO₄ is enhanced by Pr codoping because the quasi-free electrons increase the probability of radiative combination. The difference of photoluminescence properties in the two materials are attributed to the bonding character of M and O in the CaMO₄ structure.

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