The Introduction of Tungsten Heavy Alloys in Aircraft and Medical Shielding Materials

Tungsten heavy alloys comprising by weight from about 80 to about 100% tuten and from about 0 to about 20% of one or more heavy alloying metals are produced by introducing powders of tungsten and the alloying metals into a thermal spray plasma gun, melting the powders in the hot zone of the gun to form a molten alloy and then spraying the molten alloy in droplet form into a collecting chamber where the droplets are solidified, and the resultant alloy in powdered form is collected. The powdered alloy can be further mixed with powdered copper, iron, nickel, cobalt or tantalum and compacted by dynamic or explosive compaction to form a near full density material. Full density materials are produced by further thermomechanical processing of the compact.

Tungsten heavy alloys, which are of great value in counter weights for aircraft, in ballistics, and in other applications, are conventionally produced by liquid phase sintering of mixed elemental powders. Alloys produced by this method are generally two-phase composites consisting of rounded tungsten grains dispersed in an alloy metrix.

The mechanical properties of tungsten heavy alloys are strongly dependent upon their specific microstructural features: for example, the grain size, contiguity, dihedral angle and the volume fraction of the tungsten phase. For a given tungsten content, the optimal microstructure exhibits low contiguity, small grain size, and strong W-W grain boundary and W-matrix interface.


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