Synthesis of Nanosized Tungsten Carbide from Water Soluble Tungsten Source—APT

image of tungsten carbide rod

Thermal sprayed cemented carbides such as WC–Co(Cr) and Cr3C2–NiCr coatings are well known and widely used for wear protection purposes. Nanocarbides in cermets have shown promising results in gaining the hardness , wear performance in abrasion, cavitation  or slurry type of wear conditions. Even friction properties have been reported to be improved by the use of nanocarbides. The driving force for reducing the carbide grain size comes from the fact that, as the carbide size becomes smaller, the binder mean free path is reduced, resulting in higher resistance to deformation and material loss. Many researchers have pursued such a hypothesis so as to improve the wear performance of HVOF WC–Co by reducing the WC grain size to the nanoscale.

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Synthesis of Ca3WO6 for Cleaner APT Production

SEM image of Ca3WO6
The manufacture process of ammonium paratungstate (APT) by treating tungsten concentrates at present can be divided into acidic leaching method, soda or caustic soda leaching method and ammonium salt leaching method. The former two methods are conventional processes, in which the tungstic acid or sodium tungstate obtained need to be transformed into ammonium tungstate for producing APT, therefor there are a great amount of wastewater together with a plenty of auxiliary materials consumption due to difficult recycling of leaching reagents. The ammonium salt leaching method can directly obtain ammonium tungstate solution and thus has drawn great attention. It is of great significance to search a cheap and easily-cycled ammonium salt as leaching reagent to produce APT cleanly and efficiently. 

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Extraction of Tungsten from Acidic High-Phosphorus Solution for Producing APT

image of high-phosphorus tungsten ore

Tungsten is one of the most important high-tech metals, and its high-purity products are vital for developing advanced materials. Wolframite and scheelite have been used as main resources for tungsten extraction. However, the high-quality wolframite and scheelite resources reduced with the continuously exploitation and utilization and the tungsten deposits with high content of impurities must be exploited. As one of the main impurities, phosphorus significantly affects the quality of the ammonium paratungstate (APT) products. In order to obtain qualified APT, the phosphorus impurity contained in tungsten deposits must be removed in the process of tungsten hydrometallurgy.

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rGO/WO3 Composites with Excellent Electrochemical Performance from Ammonium Paratungstate

FESEM images of the (a) WO3 and (b) rGO-WO3 composites

The global energy demand has increased due to rapid population growth. The depletion of energy sources and increase in energy demand have urged researchers worldwide to study the electrochemical energy storages system, such as batteries, conventional dielectric capacitors, and fuel cells. Supercapacitors are one of the electrochemical capacitors that have attracted much research interest because of their long cycle life, high power density, excellent reversibility, environment friendly and higher safety.

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Potassium-Doped Tungsten with High Thermal Shock Resistance Prepared from APT

image of inner wall of nuclear fusion device

As one of the most promising candidates for plasma-facing material (PFM) in future fusion reactors, tungsten was extensively investigated in recent years. However, even though tungsten has many advantages like high melting point, high thermal conductivity, low tritium inventory and low erosion rate under plasma loading, there still exist some disadvantages such as high ductile–brittle transition temperature (DBTT), low recrystallization temperature (RCT), irradiation induced hardening, and so on.

Read more: Potassium-Doped Tungsten with High Thermal Shock Resistance Prepared from APT

 

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