The Calcium‐Silicate‐Tungstate Phosphor: Phase Relationships and Fluorescent Properties

An efficient phosphor can be prepared by a co‐crystallization of Formula and Formula . The fluorescence, exicted by either 2537Aå or cathode radiation, is that of a mechanical mixture of Formula and Formula . In the presence of tungstic oxide, the formation of Formula is greatly accelerated.

Determination of the pertinent compatibility tetrahedra in the system Formula revealed that the phosphor compositions lie in the sub ‐ tetrahedron Formula . X‐ray data showed that there was no solid solubility of Formula in Formula ; the fluorescence of Formula is adversely affected by Formula .

 

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