Sintering - Rearrangement of Particles

sinter capillary action image
During the sintering, there will be stages of liquid phase formation, rearrangement, dissolving-reprecipitation and solid phase sintering. After the liquid phase is generated, it flows under the influence of pore pressure difference and capillary force, which makes the solid particles suspended in the liquid phase rearrange. It is the mechanism of particle rearrangement in liquid sintering.

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Mechanism of Solid Phase Sintering

dihedral angle image
After the two stages of particle rearrangement and dissolution-reprecipitation, the densification process has slowed obviously. Because the pores have basically disappeared, the distance between the particles is narrower, making it more difficult to flow into the pores. Then the particles are drawn close together, and the sintering is entered into the phase of solid phase sintering, forming the skeleton.

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Mechanism of Solid Phase Dissolution and Reprecipitation

change of sintering solid phase image
After the liquid phase formation and particle rearrangement, the densification process of the sintered body has made great progress during the sintering. However, the resistance of the liquid viscous flow is increased because the particles are formed to a certain extent and form a bridge. The phase of particle rearrangement cannot be completely compact, so it is necessary to further advance through solid phase dissolution and reprecipitation.

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Influence Factors of Particle Pattern and Distribution

different wetting effects of liquid phase image
The sintering of tungsten carbide is a liquid phase sintering process. Particle pattern and distribution (mainly refractory carbide particles) will directly affect the properties of the tungsten carbide, such as hardness, strength and so on. Microstructure of liquid phase sintered alloy, namely solid particle shape and distribution, depending on the crystallographic characteristics of solid substances in the liquid wettability or the size of the dihedral angle.

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Removal of Chromium from Tungsten Waste

removal of chromium from tungsten waste image

Recovering tungsten from tungsten waste has become an important measure to alleviate the shortage of raw materials. At present, the main ways to treat tungsten waste at home and abroad include mechanical crushing, electrolysis, alkali leaching, sodium roasting and zinc melting. Among them, sodium roasting technology is more mature and has wide applicability to waste tungsten materials. Therefore, this method is generally used to recycle tungsten carbide and various kinds of tungsten.

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Liquid Form Synthesis of Tungsten Carbide

tungsten cobalt chromium metal reduction calcination image

Tungsten carbide is the main raw material for the production of hard alloy. The process of producing alloy powder in the tungsten production and processing enterprises is basically the combination of tungsten carbide powder and cobalt powder through mechanical mixing, and the uniformity of the alloy powder is not ideal. It has a great influence on the pressing of the subsequent cemented carbide. Some scholars have tried to pre - configure the alloy powder in the liquid state and then reduce the alloy powder.

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Preparation Method of Tungsten Molybdenum Alloy Crucible

tungsten molybdenum alloy crucible image

Rare earth metal is an important resource and strategic resource in China. It is widely used in various fields and has been known as "industrial monosodium glutamate". Rare earth elements are highly active metals, which are usually difficult to be extracted from their compounds in general conditions. The electrolytic extraction requires the crucible and tungsten electrode.

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Tungsten Oxide Structural Water Model

Tungsten oxide picture

Structural water model of tungsten oxide produced by the hydrogen gas dehydrogenation of Pt catalyze the reaction of tungsten oxide and hydrogen on the surface of Pt: a part of hydrogen ions reacts with the oxygen ions on the surface of tungsten oxide to generate water molecules and release them from the film.

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Tungsten Oxide Small Size Effect

Tungsten oxide picture

When the size of the tungsten oxide material is as small as nanometers, the tungsten oxide material exhibits different physical and chemical properties from those of conventional materials. Nano-sized tungsten oxide materials will produce small size effects, surface effects, quantum size effects and tunneling effects, resulting in new properties of acoustic, optical, electrical, magnetic and thermal properties.

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Oxygen-deficient Tungsten Oxide

Tungsten oxide picture

As an important semiconductor material, tungsten oxide has been widely applied to gas sensing, photocatalysis, electrochromic and field emission due to its special defect structure and chemical properties. There are some non-stoichiometric proportions of tungsten oxide in the actual preparation.

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