Ultra-Strong Acid Desulfurization Catalyst Containing Tungsten Trioxide

desulfurization catalystThe sulfide in the In the fuel will unavoidable release into the air in the form of gas when in the combustion process, which will probably causes a series of issues that destroying ecosystems like acid rain, damaging buildings. As the improving of people's awareness of environmental protection and vehicle fuel emission standards, increasingly strict restrictions on the sulfur content of fuel oil index has been worked out, therefore, the production and using of ultra-low sulfur fuel oil is imperative. In deep desulfurization, the application of traditional method of hydrodesulfurization (HDS) has been limited, because of its disadvantages such as harsh reaction conditions, equipment investment and higher operating costs.
 
Oxidative desulfurization is using an oxidizing agent to oxidize the sulfur compounds like thiophene in the fuel which are difficult to remove to sulfoxide or sulfone sulfur-containing materials with stronger polar in normal temperature, pressure and the presence of catalyst conditions, and then removing the sulfoxide or sulfone sulfur-containing materials by the methods like extraction, thus to achieve the goal of deep desulfurization. Oxidative desulfurization is considered to be a very attractive desulfurization technology, which usually consists of two steps: first, the fuel sulfide oxidation; second, removing the oxidized sulfur compounds from fuel oil by extraction, adsorption and distillation methods.
 
 The key of desulfurization method is developing an oxidative desulfurization catalyst with good properties of high desulfurization rate, oil yield, and low cost. Research indicates that a kind of zirconium hydroxide as a carrier, then immerse in the aqueous solution constitute of ammonium metatungstate after finely crushed; the immersion liquid placed in an ultrasonic generator ultrasonic to promote the dipping, evaporating the water, dried, and roasting at the high temperature to generate the WO3/ZrO2 solid ultra-strong acid desulfurization catalyst. This catalyst exhibits good activity and selectivity, and high desulfurization rate when used for the deep desulfurization of diesel fuel.

 

Steel Joining Process of Tungsten Carbide Roller (2/2)

Tungsten carbide consists of refractory metal carbide as the matrix and binder metal fabricated by powder metallurgy, which has many differences in mechanical properties with common steel (cast iron, cast steel, carbon steel, etc.). Especially the difference in linear expansion coefficient is the key factor of affecting the connecting property directly, which is easy to produce internal stress in the joints. If the stress exceeds the tensile strength of the cemented carbide, carbide will lead to cracking. In addition, due to the particularity of cemented carbide, the common methods are hot charging, casting, hot isostatic pressing, welding and cementing method in which the WC composite cast iron and soldering processes and solder wettability is poor.

Hot charging method uses the inner interference to thermal inner and outer layers together. The process requires tungsten carbide must have a certain thickness of the outer ring to avoid ring cracking under tension effect. So the biggest defect of the process is the consumption of tungsten carbide, which can not save the cost. The cementation method, as the name suggests is to use an epoxy resin adhesive polymer inner and outer ring are bonded together. But since he adhesive properties of the physical and chemical limits such composite roll through the process of the preparation can not be used at high temperature and pressure environment, under the alternating stress and mechanical stress joint action, is extremely prone to surface cracking phenomenon.

Thus, the three methods currently used mainly casting, hot isostatic pressing and welding. Casting is a method of pre-plating the outer layer of metal carbide as a buffer layer, using the casting method in conjunction with the iron carbide into a composite outer roll. CIC (cast in carbide) can casting carbide ring and ductile iron and form a strong metallurgical connection, so that the stress distribution can be dispersed cemented carbide. Tungsten carbide outer ring can with high hardness and excellent wear resistance withstand pure rolling force, and ductile iron with good toughness can deliver the rolling moment by the connection with tungsten carbide ring. But there are also casting some technical problems, such as the casting process is difficult to obtain precise control, so that will cause the quality of the composite roll stability can not be guaranteed.

Dragon Tungsten Gold Plated Bar

Rat, Ox, Tiger, Rabbit, Snake, Horse, Sheep, Monkey, Rooster, Dog and Pig, these are the Chinese twelve zodiacs. In China, both young and old can casually counter some zodiacs. With China’s continuous improvement of comprehensive national strength, the culture of Zodiac becomes more and more popular during the recent years. Dragon must be one of the most favorable in the twelve Zodiacs, as it is a symbol of power in Chinese ancient traditional culture. Not only because of the ancient implication dragon, but because it has the symbol of strength, courage and fearlessness.
 
Dragon tungsten gold plated bar could be gold plated in various gold type such as 18K, 24K, etc. The biggest difference between Dragon tungsten gold plated bar and Dragon real gold bar is that the former does not have as expensive value as real gold. But in addition, Dragon tungsten gold plated bar possesses with many advantages which the real gold bar does not have, such as: good wear resistance, corrosion resistance etc. The good wear-resistance and corrosion-resistant properties of tungsten alloy make Dragon tungsten gold plated bar can be saved permanently without decay, its non-toxic and environmentally friendly features also make it more safe and secure in the usual playing time. Also it could be engraved as per clients’ requirements. As it is special properties such as wear resistance, corrosion resistance and cost-effective, Dragon tungsten gold plated bar could be used as gift for friends or relatives who was born in the year of Dragon, also it could be the commemoration for families to express good wishes for their whole life. The unit weight, size, gold thickness (0.3 micrometer to 10 micrometer), engraving and gold type could be offered customized.
 
Dragon tungsten gold plated bar

Steel Joining Process of Tungsten Carbide Roller (1/2)

With the rapid development of technology, the corresponding requirements of rolling industry are also increasing. Roller is the important part of mill, which uses a pair or a set of roller to roll the steel. It mainly endures static and dynamic loads during rolling, abrasion and temperature changes. Common roll hardness testing are Shore and Leeb hardness testing, both of which are rebound hardness testing, surface hardening hardness can reach HS45-105.

However, the roller made by single material has been difficult to meet the changing requirements of rolling today. Although using coating process can guarantee the achievement of specified performance requirements, there are some matching problems in the binding strength between coating layer and the matrix, the coefficient of thermal expansion and other parameters. Furthermore, the higher cost is also the obstacle in the way of promoting.

Composite roller has uniform structure, high density and stable rolling properties, which has become one of the hotspot of many relevant researchers at home and abroad. Tungsten carbide composite roller by steel joining process, on the one hand, it has the advantages of tungsten carbide, such as high hardness, high density, excellent wear resistance and corrosion resistance and low coefficient of thermal expansion; on the other hand, it makes full use of the strength and toughness of steel, which makes tungsten carbide composite roll can meet the most of rolling industry.

Theoretically, connection of different materials is usually difficult than the connection of the same material. This is due to the quality of the connection of different materials not only be affected by the performance of physical and chemical properties of the material itself, which to a greater extent also depends on the performance of the two materials match or not. Tungsten carbide consists of refractory metal carbide as the matrix and binder metal fabricated by powder metallurgy, which has many differences in mechanical properties with common steel (cast iron, cast steel, carbon steel, etc.).

tungsten carbide roller

 

Tiger Tungsten Gold Plated Bar

Zodiac is a household name in China. Tiger tungsten gold plated bar will be launched by the major banks when it comes to the Tiger lunar New Year, which is strongly welcomed by local people. Also as it shows an ancient Chinese local culture, nowadays more and more are popular for Chinese aboard. It is easily to see the status of Zodiac in people's mind. 
 
In Tiger lunar year, Tiger tungsten gold plated bar could be send as the gift for friends, relatives who was born in the year of Tiger; also it could be used as the collection or commemoration for families. Tiger is a symbol of prestige and high spirits, which could encourage people a lot for their life and hope, so Tiger tungsten gold plated bar will a wonderful present for everywhere needs encouragement. Because Tiger tungsten gold plated is crafted from tungsten alloy, so it can also be called Tiger tungsten alloy gold-plated bar. Firstly to produce the Tiger tungsten alloy blank, later to carve out a variety of different styles of zodiac tiger patterns needed on its surface, and finally plated with a beautiful gold layer on the surface. Tiger tungsten gold plated bar is just to engrave such spirits for commemorating and collecting by people. It is as exquisite as real gold bar, but is not easy to wear and tear, and it feels just like real gold bar but its price is not expensive. Its superior characteristics of non-toxic and environmentally friendly are more in line with the current concept of people's lives and therefore popular. Tiger tungsten gold plated bar could usually be gold plated in gold type of 18K, 24K, also it could be engraved as per customized design. Its surface plating can not only be gold, but other rare metals, such as platinum, silver, rose gold and so on. Such kinds of Tiger tungsten gold plated bars are having more stylish and fresh elements, the more popular among young people. The Tiger tungsten gold plated bar plated with nothing has maintained a unique metallic appearance of tungsten alloy, which also is elegant.
 
Tiger tungsten gold plated bar
 

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