Tungsten Heater for Vacuum Coating

tungsten heaterA vacuum is a kind of gas state whose pressure is less than atmospheric pressure. Natural vacuum is a kind of vacuum that the air pressure decreases with the increasing of altitude and present in the astrospace. Man-made vacuum is to use of a vacuum pump to draw out the gas from vacuum vessel so that the pressure of container can be lower than atmospheric pressure. Generally, vacuum coating is operating by physical vapor deposition and chemical vapor deposition methods. Normally, it can be divided into vapor deposition, sputtering and ion plating. Vacuum coating often adopts tungsten heater to evaporate aluminum. The life time of the heater is also restricted by many factors, such as the degree of vacuum, current, voltage, temperature, and the amount of aluminum and evaporation time.

It is proved that the amount of insertion of the aluminum mandrel has a decisive role on its life time. On the premise of ensuring the plating thickness and unchanging other conditions, the amount of insertion of the aluminum mandrel should be minimized, the greater the amount of aluminum is inserted, the heater's life will be shorter. Because that there are some residuary aluminum on the tungsten heater after the completion of vapor deposition, and aluminum will react with tungsten, leading to corrosion of tungsten. As a result, with a long-term cumulative, it will greatly shorten the life of the tungsten heater.

In aluminum case of residual aluminum, the life time of tungsten heater is one-third less than those heaters which have no residual aluminum. Therefore, according to statistical data, the amount of the insertion of aluminum should be controlled within 5%~8% of the weight of the heater. Under the premise of ensuring the quality of coating, the fewer amounts of aluminum, the higher the rate of evaporation, and the degree of corrosion of the heater is also lower, therefore, life time of tungsten heater will be longer.

Tungsten Alloy Shielding For Ionization Chamber

Tungsten Alloy Shielding For Ionization ChamberIonization chamber, also known as ion chamber, is the simplest of all gas-filled radiation detectors, and is widely used to detect and measure some kinds of ionizing radiation (including X-rays, gamma rays and beta particles). It consists of different electrodes which have different potential and the dielectric between them. When the ionization chamber is under the irradiation, the rays will interact with gas molecules, and produce ion pair in the dielectric. Then these ion pairs free spread to the surrounding area to form the ionization current under the action of electric field. Since the electric current is proportional to the intensity of ionizing radiation, the intensity of ionizing radiation can be obtained by measuring the electric current. The classification of ionization chamber is extremely complex, it can be divided into treatment α ionization chamber, β ionization chamber or α and β ionization chamber, γ ionization chamber, neutron ionization chamber, electron beam ionization chamber, Bragg peak ionization chamber according to the measuring object; and can be divided into shell ionization chamber, parallel-plate ionization chamber, ionization chamber ventilation according to the shape of the ionization chamber .

Radiation including α-rays, β-rays, neutrons, X-rays and γ-rays can cause the ionization of matter. α-ray, also known as " alpha ray ", refers to the α particle flow released from the radioactive material. Although its penetrate power is weaker than β-ray, its ionization effect is stronger that can greatly damage the human body tissues; the ionization effect of β ray is much weaker than the α-ray, but it can also damage human tissues due to its strong penetrate power; X-rays and γ-rays both have strong penetrate power and can cause harm to humans. When the body is irradiated with the radiation, radiation can restrain, damage or even kill human cells, different degrees of change in human physiology, pathology and biochemical aspects. Ionizing radiation can also cause skin damage, hematopoietic disorders, fertility damage, leukopenia, cancer, fetal death, fetal malformations and other diseases.

Tungsten alloy shielding can be used to shield radiation when using the ionization chamber to detect ionizing radiation. According to the research, the ray absorbing ability of shielding material is closely related to its density, the higher density means better shielding capability. Compared with other traditional materials (such as lead), tungsten alloy has higher density, therefore has better ray absorption capacity and shielding ability. And tungsten alloy shielding will not release toxic substances, will not endanger human health or pollute the environment. 

 

Tungsten Trioxide Photocatalyst Coating

Photocatalytic reaction is actually a reverse process of photosynthesis, which is the photolysis process that is the photocatalyst decomposes organic pollutants (formaldehyde, acetaldehyde, etc.) into carbon dioxide and water under the light. Photocatalyst coating is the product which capable play the fully effective photocatalytic effect, with air purification, anti-bacterial, sterilization, anti-mildew, deodorizing, anti-fouling, self-cleaning and so on.
 
photocatalyst coatingTungsten trioxide, the yellow tungsten oxide which has a lower band gap (2.4~2.8eV), can effectively use the visible light to produce photocatalysis, rather than only rely on the ultraviolet light. Because of its small adverse effects and cheap, tungsten trioxide can serve as a good photocatalyst used in building materials, etc., to play an excellent catalytic effect. Tungsten oxide has the relatively stable property in the air at room temperature; however, the provided products in the market have quite a large particle size, which result in the must milling dispersion treatment. However, after dispersion treatment, the photocatalytic activity will be reduced and the high activity of coating can not be obtained.
 
Metal tungsten by using a certain technique to burn or sublimate, thus to synthesize tungsten trioxide particles with a crystal structure, and then collected by using the ESP method (Electrical Dust Collection), then the tungsten oxide particles is dissolved in an alkaline aqueous solution to form a smaller particles, finally, we obtain a tungsten trioxide photocatalyst coating by adding a binder. In addition, after the combustion of particulates heat treatment, the high and stable photocatalyst can be obtained. It is worth mentioning that the amount of binder will also affect the activity of photocatalyst coating, when it is less than 1%, as the film, its strength is obviously not enough; while, when the amount exceeds 10%, the photocatalytic activity will be reduced.
 
Uniformly coat the tungsten trioxide photocatalyst coating on a plate glass or other places, to sufficiently evaporate the solvent component then the transparent and excellent strength of the photocatalytic film will be formed, to play a role of air purifier, the self-cleaning ect..

 

Cesium Tungsten Bronze Ultrafine Powder Preparation

Tungsten trioxide has many applications in everyday life. It is often used in industrial X-ray screen phosphors and fireproof fabric manufacturing tungstate. Because of its rich yellow elements, tungsten oxide is also used as the pigment in ceramics and paints. Tungsten trioxide has been applied in the production of electricity electrochromic windows, smart windows. These windows are glass with the electric switch, and its transmittance and the applied voltage can be changed. A part of the tungsten oxide is used in the production of chemical products, such as paints and coatings, catalysts of the petroleum industry. However, tungsten oxide is an intermediate product. A large amount of tungsten oxide is used in the metal tungsten powder and tungsten carbide powder, and then used in the production of tungsten metal products production, and widely used in the production of tungsten alloy products, such as tungsten copper, tungsten nickel, tungsten nickel-iron, tungsten silver, tungsten rhenium, tungsten thorium, etc., and the tungsten carbide products with the basic material of tungsten has the most widely application in the contemporary industry field. Tungsten trioxide has excellent performance in electrochromic, catalysis, gas sensing and other aspects, its composite oxides, tungsten bronze, generally refers to the metal oxide with deep metallic luster color, and usually metal conductors or metal-semiconductors, the formula of tungsten bronze is AxWO3, but with different types of cations and the number of moles ( different A, x value), the structure and color shades of the compounds will vary. Currently potassium cesium tungsten bronze and tungsten bronzes cesium are relatively common, cesium tungsten bronze is widely used in the preparation of the conductive thin film and insulating agent in glass transparent insulation paint because of its low resistance and excellent transmittance of visible and near-infrared shielding properties.
 
A preparation method of cesium tungsten bronze ultra-fine powder, the steps are as following. (1) Cesium salt and tungsten salt are weighed as the Cs / W molar ratio of 1: (1.5 to 2.8), and introduce chelating agent and alcohol reagent, react at 170 °C for 3h; (2) The mixed solution obtained was put into the pressure bomb and react at 260 ~ 270 °C for 5 ~ 8h; (3) The reaction materials obtained should be washed and centrifuged. the complete crystals cesium tungsten bronze powder will be obtained after being dried in the vacuum at 80 °C.

CsxWO3

 

Design of Tungsten Heater for Vacuum Coating

tungsten heaterThe main raw material of tungsten heater is tungsten filament. Due to its high melting point and strong corrosion resistance, it is widely used in vacuum gilding, aluminum and other decorative items. Vacuum coating is a kind of technology for making film by physical methods. The technology was developed in the 1930s, once it has been introduced, it enjoyed a great popular. This technology was first used in the production of optical lenses, such as telescope disk for sailing. Later it extended to other functional film, music aluminum, decorative coating and surface modification, such as machine tool coating, change processing hardness. Tungsten heater can be twisted into a single strand or multi-strand shape in according with different applications.

Firstly, before designing the appearance of tungsten heater, hank knotting and the heater surface should keep clean, bright without any cracks and visible contamination of impurities, such as oxides and filament drawing lubricants. If there exist impurities on its surface, it will affect the quality of vacuum and influence on the free evaporation rate of the metal, which will reduce the effect of vacuum coating. For the superficial area of tungsten, under the premise of constant power, it should be as large as possible. Size of superficial area is in direct proportion to rate of evaporation, the larger the area, the faster the evaporation. What’s more, it has a direct impact on the quality of vapor deposition and the infiltration flow performance of aluminum.

If it is a single strand tungsten filament, people should choose a relatively thin one whose appearance diameter should be between 0.5 ~ 0.8mm. In the design of the inner diameter of the spiral time, people need to consider whether aluminum can be put in it for many times. On the other hand, it should be ensure that the heat can be effectively concentrated. The pitch of screw thread should be designed for concentrating the heat and the appearance tension of molten aluminum in order to avoid droplet phenomenon.

 

 

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