Tungsten Powder and Acoustic Sensor

The use of acoustic (e.g., ultrasonic) measurement systems in prior art downhole applications, such as logging while drilling (LWD), measurement while drilling (MWD), and wireline logging applications is well known. In known systems an acoustic sensor, typically with a substantially homogenous piezo-ceramic structure on board, operates in a pulse-echo mode in which it is utilized to both send and receive a pressure pulse in the drilling fluid (also referred to herein as drilling mud). In use, an electrical drive voltage (e.g., a square wave pulse) is applied to the transducer, which vibrates the surface thereof and launches a pressure pulse into the drilling fluid. A portion of the ultrasonic energy is typically reflected at the drilling fluid/borehole wall interface back to the transducer, which induces an electrical response therein. Various characteristics of the borehole, such as borehole diameter and measurement eccentricity and drilling fluid properties, may be inferred utilizing such ultrasonic measurements. 
 
While prior art acoustic sensors have been used in various downhole applications (as described in the previously cited U.S. Patents), their use, particularly in logging while drilling (LWD) and measurement while drilling (MWD) applications, tends to be limited by various factors. As used in the art, there is not always a clear distinction between the terms LWD and MWD, however, MWD typically refers to measurements taken for the purpose of drilling the well (e.g., navigation) whereas LWD typically refers to measurement taken for the purpose of analysis of the formation and surrounding borehole conditions. Nevertheless, these terms are hereafter used synonymously and interchangeably.
 
sensors
 
The present invention addresses one or more of the above-described drawbacks of prior art acoustic sensors used in downhole applications. Referring briefly to the accompanying figures, aspects of this invention include a downhole tool including at least one acoustic sensor having a piezo-composite transducer. The piezo-composite transducer may be configured, for example, to withstand demanding downhole environmental conditions. Various exemplary embodiments of the acoustic sensor further include a matching layer assembly for substantially matching the acoustic impedance of the piezo-composite transducer with that of the drilling fluid and for providing mechanical protection for the transducer and/or a backing layer for substantially attenuating ultrasonic energy reflected back into the acoustic sensor. Exemplary embodiments of the downhole tool of this invention include three acoustic sensors disposed substantially equidistantly around the periphery of the tool.
 
Exemplary embodiments of the present invention advantageously provide several technical advantages. Various embodiments of the acoustic sensor of this invention may withstand the extreme temperatures, pressures, and mechanical shocks frequent in downhole environments. Tools embodying this invention may thus display improved reliability as a result of the improved robustness to the downhole environment. Exemplary embodiments of this invention may further advantageously improve the signal to noise ratio of downhole acoustic measurements and thereby improve the sensitivity and utility of such measurements.
 
In one aspect the present invention includes a downhole measurement tool. The downhole measurement tool includes a substantially cylindrical tool body having a cylindrical axis. The tool further includes at least one acoustic sensor deployed on the tool body, the acoustic sensor including a piezo-composite transducer element with anterior and posterior faces. The piezo-composite transducer is in electrical communication with an electronic control module via conductive electrodes disposed on each of the faces. The piezo-composite transducer element includes regions of piezoelectric material deployed in a matrix of a substantially non piezoelectric material, the regions extending through a thickness of the transducer element in at least one dimension. In exemplary variations of this aspect, the acoustic sensor includes a laminate having a composite backing layer, at least one matching layer, and a barrier layer deployed at an outermost surface of the acoustic sensor.
 
In another aspect, this invention includes an acoustic sensor having a piezo-composite transducer element. Further aspects of this invention include a method for fabricating a downhole measurement tool and a method for fabricating an acoustic sensor.
 
The foregoing has outlined rather broadly the features and technical advantages of the present invention in order that the detailed description of the invention that follows may be better understood. Additional features and advantages of the invention will be described hereinafter which form the subject of the claims of the invention. It should be appreciated by those skilled in the art that the conception and the specific embodiment disclosed may be readily utilized as a basis for modifying or designing other structures for carrying out the same purposes of the present invention. It should be also be realized by those skilled in the art that such equivalent constructions do not depart from the spirit and scope of the invention as set forth in the appended claims.
 
Exemplary backing layers may also include substantially any suitable powder material, such as tungsten powers, tantalum powders, and/or various ceramic powders. In one useful embodiment, tungsten powders having a bimodal particle size distribution may be utilized. For example, one exemplary backing layer includes a mixture of C-8 and C-60 tungsten powders. The particle size of C8 is in the range from about 2 to about 4 microns while the particle size of C60 is in the range from about 10 to about 18 microns. 
 
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Tungsten Trioxide Photocatalyst for Ocean Oil Pollution Treatment

In recent years, frequent oil spills at sea and nuclear incidents have caused serious pollution on the human environment; furthermore, these pollutants are difficult to remove in a short time. An offshore drilling platform of British Petroleum (BP) in the Gulf of Mexico exploded in 2010, causing 11 deaths of the workers, resulting in a large number of oil spilt to the sea; According to media reports at the time, the oil leak in the Gulf of Mexico last for a few months, resulting in the death of wild animals, beach being contaminated, and accompanied by secondary effects of the oil spill. The viscosity of the oil determines once it leaking out from tankers and offshore drilling rig, the removal from marine plants and animals is very difficult. Therefore, to find a way to quickly remove and degrade oil leakage is essential for the protection of the marine environment, and marine oil pollution control has become one of the world’s common concern.

tungsten trioxide and ocean oil pollution
 
For taking full advantage of solar energy, scientists coupled the titanium dioxide particles to the hollow glass microspheres which the density is much smaller than that of water by coupling agent of Silane, to form the titanium dioxide photocatalyst which can float on the surface water; also, they studied its photocatalytic decomposition of organic pollutants film on the water and obtained satisfactory results. Although, there has no yet the reports for the study of the tungsten trioxide in the oil pollution control, but I believe  that if will be in the future, because the tungsten trioxide is a photocatalyst which has the better photocatalytic effect of titanium dioxide; and moreover, ultrafine tungsten trioxide powder has a very broad application in catalysis prospects.
 
Tungsten trioxide (WO3), yellow tungsten oxide powder, not only has the properties of photochromic, gas sensing, but also has good catalytic function, and being an important radiation shielding material at the same time. Band gap of tungsten trioxide is 2.4eV ~ 2.8eV, which means that it can take full advantage of sunlight; in addition, WO3 itself has no toxicity, as a photocatalyst, if the technical support was supported, it will degrade the ocean oil pollution and make an important contribution to the marine environmental government, if with appropriate.

 

Tungsten Carbide Button Used for DTH Drill

DTH drill uses compressed air as a power source to drive DTH hammer piston, and high frequency impact DTH drill by large impact energy. At the same time, the axial pressure and rotary torque effect from drilling bars rotate and break the rocks. The debris they produce high-pressure air is carried back to the earth surface. This kind of DTH drill has many advantages, such as high drilling efficiency, high quality of drilling, long service life of drill bits, not easily to be blocked and low cost, which as a kind of efficient drilling process and has been widely used in Mine blast, geological exploration, hydrology well drilling and other drilling purposes, especially effective in medium hard and hard formation. However, tungsten carbide buttons used for DTH drill directly affects DTH drill performance. Since in the process of drilling, the button under the action of high-speed impact of high frequency impact energy to hit the rocks, resulting in a larger volume breaking, DTH drill has higher efficiency. In addition, tungsten carbide buttons crush rock is a dynamic, non-linear failure process, which can be divided into 3 steps:

1. The moment of button and rock contacting, the load is small and rock has elastically deformed, and it appears a hemispherical elastic region under the button;
2. The buttons move down continuously, the load and the elastic region increases, the stress wave uses the point of button and rock contact as the center of the sphere, concentric spherical shape continuously to spread inside the rock. Meanwhile, it appears a high-stress area under the contact point of button and rocks. When the stress reached the limits of zone status, rocks were fractured;
3. The buttons intrude the rocks further, pressure on the surrounding rock to the side and gradually increased, eventually collapse from the surrounding rocks, forms a large volume of crushing, crushing cavity is formed.

In general, DTH drill uses 9 buttons, the bottom surface 3 by a clockwise spiral arrangement, other 6 edge evenly distributed. The bottom sets 3 buttons to ensure that each button can endure the largest impact energy, and the closest to the center uses inlay welding process, which is beneficial for coring. The other 6 edge buttons play a role in holding aperture and breaking the rocks surrounded.

Tungsten Carbide Button Used for DTH Drill

 

Tungsten Carbide Hob Description

Tungsten carbide hob is composed of the hard phase WC and the binder phase Co, its edges helically arranged along cylinder or cone to manufacture cutting tools, which has been widely used in cylindrical gears, worm and other toothed cylindrical workpieces fabricating. According to different applications, tungsten carbide hob can be specifically divided into gear hobs, worm hobs, fixed mounted hobs, non-involute hobs and so on. Compared with common high-speed steel hobs, tungsten carbide hobs have better performance in cutting rate and button efficiency. Solid tungsten carbide hob has been widely used in watches and some of the precision instrument manufacturing industry, such as processing a variety of small module gear; medium modulus solid carbide hob and panels have been used for machining cast iron and bakelite gear; modulus < 3 tungsten carbide hob is also used in steel gear manufacturing; in addition, tungsten carbide hob is also can be used for fabricating hardened wheel (HRC50-62).

Tungsten carbide worm hob is a kind of special tool for worm manufacturing. Its main transmission type and basic parameters of the worm (including module, pressure angle, helix angle, pitch diameter, number of thread, etc.) should work with the same worm. When the worm is large in outer diameter, shaft-mounted hob can be made; when the worm is small in outer diameter, the hob can be made integral with the mandrel shank-type structure. Tungsten carbide fixed mounted hob has different profiles, which only the last one button is the precise button. Gullet button and forming a workpiece identical to alveolar milling method of cutting a workpiece, the rest of the button are for rough cutting and the movements is as same as the gear hob. In addition, forming hob can effectively avoid the exhibition to the transition curve tooling generated the root, especially the ratchet hob. The mechanism of non-involute hob is similar to the gear hob, such as spline hob can be used for processing rectangular teeth, involute or triangular tooth spline shaft, which has better machining precision and efficiency than forming cutters. And it also can be used for arc gears, cycloid gears and sprockets manufacturing. 

tungsten carbide hob

 

Tungsten Cobalt Alloy Production Using Tungsten Powder Coating

During production of tungsten cobalt alloy, to prevent sticking, aluminum oxide with ethanol is brushed to the boat. However, aluminum oxide will penetrate into alloy under high temperature will results in the uneven of bottom to enlarge the finish machining cost. At the same time, the service life of vacuum pump is shorter with absorption of aluminum oxide particle. This article introduces a tungsten cobalt alloy production using tungsten powder preparing method, it will realize the completely separation of tungsten cobalt alloy and graphite boat and will not affect quality of alloy.

Tungsten Powder

Tungsten cobalt alloy production using tungsten powder coating manufacturing method:
A.Submicron tungsten powder preparation:
1.Disolve tungstic acid in distilled water, adding ammonium solution and heating, ammonium tungstate solution is obtained.
2. Quick freeze ammonium tungstate solution under 45~-50°C.
3. Transit ammonium tungstate into ultra freezing drying machine. After freezing out its appearance is like white cellular piece.
4. Smash the piece obtained from step 3.
5. Tungsten powder is obtained under 250~500°C by hydrogen reduction for 4~6 hours.

B. Preparing materials below:
PEG6000 10~20 parts.
Tween 80 5~10 parts.
Graphite glue 10~20 parts.
Anti-brasive carbon black 10~20 parts.
Submicron tungsten powder from step A 5~10 parts.
Water 30~50 parts.

C. Mixing tungsten powder and PEG6000.
D. Dissolve material in step C with distilled water.
E. Adding the rest material into solution of step D and stirring it evenly.

Advantages: This kind of tungsten cobalt alloy production using tungsten powder coating manufacturing method, use freezing tungsten powder to replace metal oxide powder, it has high purity, small grain size. Besides that, submicron tungsten powder produced by vacuum freezing drying method can absorbing other components when blended with coating due to its porosity inside. 

 

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