1. Selection of raw materials of tungsten copper contacts (Cu80W / Cu)
(1) Selection of tungsten powder. Select tungsten powder with the grade of FW-1 standard, tungsten powder particle size range is: 6-8μm. If the tungsten powder is oxidized, then the reduction of the oxidized tungsten powder is needed at the condition of hydrogen protection, and at a temperature of about 860 ℃, and holding 1h.
(2) Selection of copper powder. Adopting electrolytic copper method to obtain copper, which should be restored firstly, its reducing atmosphere is hydrogen atmosphere, temperature is about 300 ℃, holding time of 1h.

2. Preparation of contact 
Preparation of contact of tungsten copper contacts (Cu80W / Cu) adopts sintering and infiltration process of powder metallurgy.
Process:
Mixing powder (tungsten powder and copper powder, in accordance with an appropriate proportion) → pressing to its shape → sintering and infiltration (tungsten copper blanks) → machining and squeezing.
Sintering and infiltration conditions: the need for introducing hydrogen (hydrogen flow: 1m³ / h), the temperature is about 1500 ℃, sintering time is 2h.
Machining and squeezing: machining the tungsten copper blanks after sintering and infiltration, and then, coating its surface with oil evenly, then squeezing by using four-column hydraulic press machine.



 

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Tungsten primary machine to achieve automatic sorting system is the key technology of tungsten ore image featureextraction,identification and sorting algorithm.SUSAN operator to improved fast algorithm as the core of tungsten ores and primary algorithm is a targeted optimum algorithm.A primary algorithm of tungsten ore based on SUSAN operator is designed and realized.The algorithm adopts the improved SUSAN edge extraction operator with morphological opening operation to estimate background and global gray image taking the original geometry of complex operations to weaken the background noise on the image texture and the influence.In order to improve the effect of edge detection,the algorithm is combined with the similarity SUSAN comparison based on image gray edge detection algorithm.The algorithm,which does not require gradient calculations,is simple,accurate in positioning and antinoise.The effect of edge detection is enhanced.

 

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Microvave digestion method was applied in the determination of tungsten in tungsten ore by thiocyanate spectrophotometry.The digestion solvent was 40 mL of NaOH solution(25 g/L).The microwave power was medium-high level.The digestion time was 30 min.The dosages of all reagents were investigated.The detection limit of this method was 0.5 μg/mL.The tungsten ore was analyzed by the proposed method and the determination results were consistent with those obtained by the traditional sample preparation methods.The relative standard deviation(RSD) was less than 2.3 %.

 

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The new type centrifugal separator was used to discarding the large number of tailings of tungsten ore from slims,and the next is that the gravity separation concentrate was put into the process of flotation.Of these mine samples,the degree of slimings is high and the particle size is very low,therefore the separation is very difficult.The experiment test through a flotation flowsheet of centrifugal-flotation was performed.The tungsten concentrate with the grade of 34.74 %WO₃,and the total recovery of 75.21% can be obtained.

 

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Potassium tungstate is white or colorless crystalline powder and is a monoclinic structure. Its physical properties are as follows: chemical formula: K2O4W, molecular weight: 326.0342, density: 3.12g/ml, melting point: 921 ℃, Solubility: soluble in water, insoluble in alcohol. K2O4W should be sealed in the storage vessel, and it is placed in a cool, dry place. Besides avoids contact with tungsten oxide, moisture or humidity. In addition, it is harm for the water, if there is no relevant government departments permission shouldn’t released to the surrounding.
Potassium tungstate is mainly used in analytical reagents, alkaloids precipitant, but also for the fine tungsten and bronze manufacture.
Potassium tungstate producing processes are as follows:
1.Mixed potassium dichromate (K2Cr2O7) with tungsten powder, after reaction to obtain potassium tungstate and chromium oxide.
2.W react with KOH to produce potassium tungstate.
W reacts with KOH solution, if no oxygen participate there is a slight reaction. But the reaction has oxidizing agent (such as KNO3, KNO2, KClO3, PbO2, etc.) will cause violet reaction.

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1. Tungsten alloy multi-blade grating with the thickness of 2.0 to 3.8mm and the plate flatness of 0.05mm.
2. Tungsten alloy protective tank for medical radiation shielding walls, shielded syringe for the shielding of medical radioactive liquor, and tungsten alloy memory for containers such as pots and tanks used for storing radioactive substances
3. Collimator for medical linear accelerators and cyclotrons
4. Shielding device for the shielding of rays of 60Co therapy apparatus.

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The tungsten alloy counterweight is formed by adding elements such as Fe, Ni, Cu, Co, Mo and Cr into tungsten serving as the matrix (the content of W is 85 to 99 percent). Tungsten alloy called high density alloy because its density is up to 16.5 to 19.0g/cm3. It also has the characteristics of high specific gravity, high strength, strong ray absorption capability, high thermal conductivity, small thermal expansion coefficient, good electrical conductivity, and good weldability and machinability, wherein the specific gravity is usually 16.5 to 18.75g/cm3; the tensile strength is 700 to 1,000Mpa; the ray absorption capability is 30 to 40 percent higher than that of lead; the thermal conductivity is 5 times that of mould steel; and the thermal expansion coefficient is only one second to one third of that of Fe or steel. In view of its excellent functions, the high density alloy is widely applied to the industries of aerospace, aviation, war, oil drilling, electrical appliances and meters, medicine and so on.

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According to USGS, world tungsten mine production was estimated to be 71,000 tonnes in 2013. China was the largest producer in 2013, followed by Russia and Canada. The top three countries accounted for 91% of the total production in 2013. Other major producing countries include Bolivia, Austria and Portugal.

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The content of tungsten in the Earth's crust is 0.007%. According to the data released by USGS in 2014, global tungsten reserves are around 3.5 million tonnes. About two-thirds of the world's tungsten resources are in the form of scheelite, and one-third are in wolframite-group minerals. The tungsten ore resources country distribution in the world is as follows:

According to the data released by USGS in 2014, world tungsten reserves are round 3.5 million tonnes. Tungsten resources are concentrated in China (1,900,000 metric tonnes), Canada (290,000 metric tonnes), Russia (250,000 metric tonnes), United States (140,000 metric tonnes), Bolivia (53,000 tonnes), Austria (10,000 metric tonnes) and Portugal (4,200 metric tonnes).

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